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    • 79. 发明公开
    • COMPOSITION FOR METAL SURFACE TREATMENT, METAL SURFACE TREATMENT METHOD, AND METAL MATERIAL
    • 金属制品有限公司METALLOBERFLÄCHENBEHANDLUNGUNDMETALLOBERFLÄCHENBEHANDLUNGSVERFAHREN
    • EP1997936A1
    • 2008-12-03
    • EP07737639.0
    • 2007-03-01
    • Chemetall GmbH
    • INBE, ToshioKOLBERG, Thomas
    • C23C22/48B32B15/04C09D183/08C25D9/10
    • C09D183/08C08K3/10C23C18/1216C23C18/122C23C18/1241C23C18/1295C23C22/34C23C2222/20Y10T428/12Y10T428/12729Y10T428/12743Y10T428/12792Y10T428/12951Y10T428/31663
    • Disclosed is a composition for metal surface treatment which enables to form a chemical conversion coating film which achieves sufficient foundation surface concealment, coating adhesion and corrosion resistance. Also disclosed are a metal surface treatment method, and a metal material. Specifically disclosed is a composition for metal surface treatment containing a zirconium compound and/or a titanium compound, and an organosiloxane which is a polycondensation product of an organosilane and has at least two amino groups in a molecule. The polycondensation rate of the organosiloxane represented by the mathematical formula (1) below is not less than 40%. The content of the zirconium compound and/or titanium compound in the metal surface treatment composition and the organosiloxane content in the metal surface treatment composition are at predetermined values, while the mass ratio of the zirconium element and/or titanium element contained in the zirconium compound and/or titanium compound relative to the silicon element contained in the organosiloxane is at a predetermined value. Polycondensation Rate % = Mass of Organosiloxane × 100/(Mass of unreacted Organosilane + Mass of Organosiloxane) (1)
    • 公开了一种用于金属表面处理的组合物,其能够形成实现足够的基础表面隐蔽性,涂层粘附性和耐腐蚀性的化学转化涂膜。 还公开了金属表面处理方法和金属材料。 具体公开了含有锆化合物和/或钛化合物的金属表面处理用组合物和作为分子内具有至少两个氨基的有机硅烷的缩聚物的有机硅氧烷。 由下式数学式(1)表示的有机硅氧烷的缩聚率为40%以上。 金属表面处理组合物中的锆化合物和/或钛化合物的含量和金属表面处理组合物中的有机硅氧烷含量为预定值,而锆化合物中所含的锆元素和/或钛元素的质量比 和/或钛化合物相对于有机硅氧烷中所含的硅元素为预定值。 缩聚率%=有机硅氧烷的质量×100 /(未反应的有机硅烷的质量+有机硅氧烷的质量)(1)
    • 80. 发明公开
    • Dye-sensitized solar cell and method of manufacturing it
    • Farbstoffsensibilisierte Solarzelle und deren Herstellungsverfahren
    • EP1978136A1
    • 2008-10-08
    • EP08005872.0
    • 2008-03-27
    • TDK Corporation
    • Handa, TokuhikoMonden, Atsushi
    • C25D9/08C25D15/02C25B11/03C25B11/04H01G9/042H01G9/20H01L31/0216H01L31/0224H01L31/0236
    • C25D15/02C25D9/08H01G9/2027H01G9/2059Y02E10/542Y02P70/521
    • There are disclosed an electrode having a large amount of a dye to be supported, having an excellent dye replacement property and having a capability of improving a photoelectric conversion efficiency, a manufacturing method of the electrode and a dye-sensitized solar cell including the electrode. An electrode 11 according to the present invention includes a dye-supported layer 14 laminated on a substrate 12 and including zinc oxide and a dye. The dye-supported layer 14 has at least a plurality of bump-like protrusions formed so that zinc oxide protrudes radially from the substrate 12, or satisfies represented by the following formula (1) : 2 ≤ I 002 /I 101 ≤ 12, in which I 002 is a peak intensity attributed to a zinc oxide (002) face in X-ray diffraction measurement of the dye-supported layer 14, and I 101 is a peak intensity attributed to a zinc oxide (101) face in the X-ray diffraction measurement.
    • 公开了具有大量待负载的染料,具有优异的染料替代性能并且具有提高光电转换效率的能力的电极,电极的制造方法和包括该电极的染料敏化太阳能电池。 根据本发明的电极11包括层叠在基板12上并包含氧化锌和染料的染料负载层14。 染料支撑层14具有至少多个凸起状突起,其形成为使得氧化锌从基板12径向突出,或满足下式(1)所示:2‰I 002 / I 101‰12, 其中I 002是染料负载层14的X射线衍射测定中归因于氧化锌(002)面的峰强度,I 101是归因于X射线衍射中的氧化锌(101)面的峰强度, 射线衍射测量。