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    • 75. 发明公开
    • Preparation of mixed ultrafine particles form PFPE microemulsion
    • Präparationvon gemischten ultrafeinen Partikeln aus einer PFPE Mikroemulsion
    • EP0686447A2
    • 1995-12-13
    • EP95108723.8
    • 1995-06-07
    • AUSIMONT S.p.A.
    • Chittofrati, AlbaBoselli, Viviana
    • B22F9/24
    • B82Y30/00C01B13/328C01G49/0018C01P2004/52C01P2004/64H01F1/44Y10S516/922Y10S516/927
    • Process for preparing dispersions containing mixed oxides having particle size lower than or equal to 50 nm and having narrow size distribution, comprising the following steps:

      P1) preparing a microemulsion of water in oil, the oil being a perfluoropolyether, said microemulsion being obtained using a perfluoropolyether surfactant, the aqueous phase consisting of a solution of an inorganic salt of a M1 metal;
      P2) preparing a M2 metal salt of an anionic perfluoropolyether surfactant, such salt being soluble in the perfluoropolyether oil used in P1, the amount by moles of surfactant being such as to fully bind to the cation and so as not to be in excess;
      P3) adding P2 to P1 for obtaining the reaction system containing the two metals M1 and M2; M1 in aqueous phase and M2 in perfluoropolyether oil phase;
      P4) adding alkali solution to P3 with contemporaneous or subsequent heating, if P3 has not yet been heated, at the temperature necessary to form the desired oxide; then cooling and separating the aqueous supernatant;
      M1 and M2 belong to the metals capable of giving oxides; when the two metals M1 and M2 have different valence, then M1 is the metal ion with lower valence, different from Fe(II), optionally in admixture with Fe(II), M2 is the metal ion with higher valence.
    • 制备含有粒度小于或等于50nm并具有窄尺寸分布的混合氧化物的分散体的方法,包括以下步骤:P1)制备油中的水微乳液,所述油为全氟聚醚,所述微乳液使用 全氟聚醚表面活性剂,由M1金属的无机盐的溶液组成的水相; P2)制备阴离子全氟聚醚表面活性剂的M2金属盐,这种盐可溶于P1中使用的全氟聚醚油,表面活性剂的摩尔数与阳离子完全结合并且不会过量; P3)将P2加入到P1中以获得含有两种金属M1和M2的反应体系; M1在水相中,M2在全氟聚醚油相中; P4)在同时或随后加热的情况下,如果P3尚未加热,则在形成所需氧化物所需的温度下加入碱溶液; 然后冷却并分离含水上清液; M1和M2属于能够产生氧化物的金属; 当两种金属M1和M2具有不同的价态时,M1是与Fe(II)不同的低价金属离子,任选与Fe(II)混合,M2是具有较高价态的金属离子。
    • 79. 发明公开
    • A self-metabolic functional material
    • 自我代谢功能材料
    • EP0546342A3
    • 1993-09-08
    • EP92119453.6
    • 1992-11-13
    • MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
    • Kishimoto, Yoshio
    • B01J8/42B03C1/00B01D15/00B01J47/00B01D15/02B01J19/08B01J47/06B01J47/08
    • H01F1/112B01D15/00B01J19/087B01J19/22B01J47/018B01J2219/0852B01J2219/0854H01F1/44
    • The present invention provides a self-metabolic functional material comprising a functional ferromagnetic particles dispersed in a fluid, each of the particles comprising a functional component and a chemically reactive ferromagnetic component with a characteristic of losing a ferromagnetism thereof by a chemical reaction proceeding with time, the functional ferromagnetic particles losing the ferromagnetism by the chemical reaction of the ferromagnetic component with time. The self-metabolic functional material has a desired function and gradually loses its function by being used. The degradation or loss of the function of the material can be detected by degradation or loss of ferromagnetism. By using such a material in the self-metabolic functional apparatus comprising a carrying means and a supply means, the self-metabolic functional material is self-metabolized as follows: The function of the self-metabolic functional material is degraded or lost, and at the same time the ferromagnetism is degraded or lost; and then the self-metabolic functional particles can not be carried on the carrying means. Fresh self-metabolic functional material comprising self-metabolic functional particles by either ferromagnetism and functionality, is carried on the carrying means by the supply means.
    • 本发明提供一种包含分散在流体中的功能性铁磁颗粒的自代谢功能材料,每个颗粒包含功能组分和化学反应性铁磁组分,其特征在于通过随时间的化学反应失去其铁磁性, 功能性铁磁性颗粒通过铁磁性部件随时间的化学反应而失去铁磁性。 自身代谢功能材料具有所需的功能,并通过使用而逐渐失去功能。 材料的功能的降解或损失可以通过铁磁性的降解或损失来检测。 通过在包含携带装置和供给装置的自代谢功能装置中使用这种材料,自身代谢功能材料如下自身代谢:自身代谢功能材料的功能降解或丧失,并且在 铁磁同时退化或失落; 然后自代谢功能性颗粒不能携带在携带装置上。 通过铁磁性和功能性的包含自身代谢功能性颗粒的新鲜的自代谢功能材料由供给装置承载在承载装置上。