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62. 发明公开

EP2448670A2 PROCEDE DE PREPARATION D'UN CATALYSEUR MULTI-MÉTALLIQUE PRÉSENTANT UNE PROXIMITÉ DE SITES OPTIMISÉE 有权
标题翻译：用于生产多金属催化剂具有最佳组布置
公开(公告)号：EP2448670A2
公开(公告)日：2012-05-09
申请号：EP10734170.3
申请日：2010-06-15
申请人： IFP Energies nouvelles
发明人： AVENIER, Priscilla , LACOMBE, Sylvie , CAUFFRIEZ, Hervé
IPC分类号： B01J23/62 , B01J23/644 , B01J35/00 , C10G35/09 , C07C5/41 , B01J27/185 , B01J27/186 , B01J37/02 , B01J37/24 , B01J23/64
CPC分类号： B01J23/626 , B01J23/644 , B01J23/6445 , B01J27/1856 , B01J27/186 , B01J35/002 , B01J37/0205 , B01J37/0207 , B01J37/24 , B01J37/28 , C10G35/09 , C10G2300/70
摘要： The invention relates to a method for preparing a catalyst including at least one metal M of the platinum group, tin, a phosphorus promoter, a halide compound, a porous substrate, and at least one promoter X1 selected from the group comprising gallium, indium, thallium, arsenic, antimony and bismuth. The X1 promoter(s) and the phosphorus are added during one or more sub-steps a1) or a2), the sub-step a1) corresponding to the synthesis of the precursor of the dominant oxide and the sub-step a2) corresponding to the shaping of the substrate. The tin is added during one at least of the sub-steps a1) and a2). The product is dried and calcinated before depositing at least one metal M of the platinum group. The assembly is then dried under a neutral gas flow or an oxygen-containing gas flow and further calcinated. The invention also relates to the use of the catalyst obtained by said method in catalytic-reforming or aromatic production reactions.

63. 发明公开

EP2432590A1 MONOLITH CATALYST AND USE THEREOF 审中-公开
标题翻译：整体式催化剂及其用途
公开(公告)号：EP2432590A1
公开(公告)日：2012-03-28
申请号：EP10722048.5
申请日：2010-05-18
申请人： BASF SE
发明人： MABANDE, Godwin Tafara Peter , CHIN, Soo Yin , SCHINDLER, Götz-Peter , KOERMER, Gerald , HARMS, Dieter , RABE, Burkhard , FURBECK, Howard , SEEL, Oliver
IPC分类号： B01J23/42 , B01J23/62 , B01J23/656 , B01J23/58 , B01J23/63 , B01J21/06 , B01J35/04 , B01J35/00 , B01J35/10 , B01J21/10 , C07C5/32 , C07C5/333 , C07C5/41 , C07C5/42 , C07C5/48
CPC分类号： F23C13/08 , B01J19/2485 , B01J21/04 , B01J21/06 , B01J21/066 , B01J23/40 , B01J23/42 , B01J23/58 , B01J23/624 , B01J23/63 , B01J23/6567 , B01J23/96 , B01J35/002 , B01J35/0026 , B01J35/023 , B01J35/04 , B01J37/0036 , B01J37/0045 , B01J37/0205 , B01J37/0228 , B01J37/0242 , B01J37/0248 , B01J38/10 , B01J38/12 , C07C5/3337 , C07C5/393 , C07C2523/42 , C07C2523/62 , F23C2900/9901 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C11/08 , C07C15/08
摘要： The invention relates to a catalyst comprising a monolith composed of a catalytically inert material with low BET surface area and a catalyst layer which has been applied to the monolith and comprises, on an oxidic support material, at least one noble metal selected from the group consisting of the noble metals of group VIII of the Periodic Table of the Elements, optionally tin and/or rhenium, and optionally further metals, wherein the thickness of the catalyst layer is 5 to 500 micrometers.

64. 发明公开

EP2379677A2 VERFAHREN ZUR HERSTELLUNG VON BENZOL 审中-公开
标题翻译：用于生产苯
公开(公告)号：EP2379677A2
公开(公告)日：2011-10-26
申请号：EP09796946.3
申请日：2009-12-04
申请人： Bayer Technology Services GmbH
发明人： SCHELLEN, Ralph , HIZALER HOFFMANN, Evin , MLECZKO, Leslaw , SCHUBERT, Stephan , MARWAHA, Bharat
IPC分类号： C10G35/04 , C07C15/02 , C07C5/32 , C07C5/41
CPC分类号： C07C5/367 , C07C5/417 , C07C2521/04 , C07C2523/36 , C07C2523/42 , C10G35/04 , C10G2400/30 , C07C15/04
摘要： The present invention relates to a process for the endothermic, catalytic gas-phase reaction of naphtha with hydrogen to form benzene, in which the reaction is carried out under adiabatic conditions in from 5 to 12 reaction zones connected in series.

65. 发明公开

EP1897863A1 Method for producing dimethylnaphthalene using a metal catalyst 有权转让
标题翻译： Verfahren zur Herstellung von Dimethylnaphtalen mittels eines Metallkatalysators
公开(公告)号：EP1897863A1
公开(公告)日：2008-03-12
申请号：EP07004949.9
申请日：2007-03-09
申请人： Hyosung Corporation
发明人： Kim, Hyun-Soo , Choi, Young-Gyo , Kwon, Ik-Hyun
IPC分类号： C07C5/41 , B01J21/10 , B01J23/40 , B01J23/58 , B01J23/60
CPC分类号： B01J23/62 , B01J23/626 , B01J37/0205 , B01J37/0207 , C07C5/417 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/04 , C07C2523/06 , C07C2523/62 , C07C2527/138 , C07C2529/04 , C07C15/24
摘要： Disclosed herein is a process of producing high purity and high yield dimethylnaphthalene by dehydrogenating a dimethyltetralin isomer using a metal catalyst for dehydrogenation. The metal catalyst contains a carrier selected from alumina (Al 2 O 3 ), silica (SiO 2 ), a silica-alumina mixture and zeolite. The metal catalyst also contains 0.05 to 2.5 % by weight of platinum (Pt), 0.1 to 3.0 % by weight of tin (Sn) or indium (In), 0.5 to 15.0 % by weight of at least one selected from the group consisting of potassium (K), magnesium (Mg) and cesium (Cs), 0.3 to 3.0 % by weight of chlorine, and 0.01 to 3.0 % by weight of zinc (Zn) or gallium (Ga) as active components based on an element weight of the final catalyst.
摘要翻译：本文公开了通过使用用于脱氢的金属催化剂使二甲基四氢萘异构体脱氢来生产高纯度和高收率的二甲基萘的方法。金属催化剂含有选自氧化铝（Al 2 O 3），二氧化硅（SiO 2），二氧化硅 - 氧化铝混合物和沸石的载体。金属催化剂还含有0.05〜2.5重量％的铂（Pt），0.1〜3.0重量％的锡（Sn）或铟（In），0.5〜15.0重量％的选自以下的至少一种：钾（K），镁（Mg）和铯（Cs），0.3〜3.0重量％的氯和0.01〜3.0重量％的作为活性成分的锌（Zn）或镓（Ga）最终催化剂。

66. 发明公开

EP1642641A1 A catalyst and process for producing monocyclic aromatic hydrocarbons 失效
标题翻译： Katalysator和Verfahren zur Herstellung von monozyklischen Aromaten
公开(公告)号：EP1642641A1
公开(公告)日：2006-04-05
申请号：EP05021950.0
申请日：1995-10-05
申请人： Asahi Kasei Kabushiki Kaisha
发明人： Takashi, Tsunoda , Sekiguchi, Mitsuhiro , Tokitaka, Kaneshima
IPC分类号： B01J29/44 , B01J29/068 , C10G35/095 , C07C5/41
CPC分类号： B01J29/44 , B01J29/068 , C07C4/06 , C07C5/415 , C07C2529/40 , C10G11/05 , C10G11/18 , C10G2400/20 , C10G2400/30 , C07C15/02
摘要： The present invention provides a catalyst to produce a monocyclic aromatic hydrocarbon from hydrocarbons, which comprises a zeolite containing substantially no proton and having an intermediate pore diameter, a molar ratio of SiO 2 to Al 2 O 3 of at least 20 and silver, and which further comprises at least one metal belonging to Group IIb, IIIb and Group VIII of the Periodic Table. Further, the present invention provides a method to catalytically convert hydrocarbons by using the above catalyst. By means of the present invention, there can be provided a stable catalyst for conversion of hydrocarbons, which is capable of obtaining monocyclic aromatic hydrocarbons with good balance and a high yield, and which is hardly deteriorated by steam having a high temperature.
摘要翻译：本发明提供一种由烃制造单环芳烃的催化剂，其包含基本上不含质子且中等孔径，SiO 2与Al 2 O 3的摩尔比至少为20的银和银，并且还包含属于周期表IIb族，IIIb族和VIII族的至少一种金属。此外，本发明提供了通过使用上述催化剂催化转化烃的方法。通过本发明，可以提供一种用于转化烃的稳定催化剂，其能够获得具有良好平衡和高产率的单环芳烃，并且几乎不会由于具有高温蒸汽而劣化。

67. 发明授权

EP0951443B1 HYDROCARBON CONVERSION USING LARGE CRYSTAL ZEOLITE CATALYST 失效
标题翻译：油气转换装置BIG沸石催化剂AUFWEISENDEM
公开(公告)号：EP0951443B1
公开(公告)日：2002-09-04
申请号：EP97911819.7
申请日：1997-10-17
申请人： ExxonMobil Chemical Patents Inc.
发明人： SMITH, Robert, S. , VERDUIJN, Johannes, P.
IPC分类号： C01B39/02 , C01B39/04 , C10G35/095 , C07C4/06 , C07C5/27 , C07C6/12 , C07C2/66 , C07C5/41 , C07C1/20
CPC分类号： C10G45/64 , C01B39/02 , C01B39/04 , C07C2/66 , C07C4/06 , C07C5/2708 , C07C5/41 , C07C6/123 , C07C6/126 , C07C2529/18 , C07C2529/50 , C07C2529/65 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/095 , C07C15/00

68. 发明公开

EP0988891A4 HALOGEN-CONTAINING CATALYST AND PROCESS FOR THE PREPARATION THEREOF 失效
标题翻译： HALOGENE含有催化剂和方法及其
公开(公告)号：EP0988891A4
公开(公告)日：2002-04-24
申请号：EP98923145
申请日：1998-06-05
申请人： IDEMITSU KOSAN CO , CHEVRON CHEM CO
发明人： FUKUNAGA TETSUYA , ISHII MITSUE
IPC分类号： B01J27/08 , B01J29/60 , B01J29/62 , B01J37/00 , C07C2/52 , C07C5/41 , C07C15/00
CPC分类号： B01J37/0009 , B01J27/08 , B01J29/62 , B01J2229/42
摘要： A halogen-containing catalyst wherein halogen is uniformly distributed, particularly one exhibiting an alpha ratio of 0.17 or below in the figure obtained in the line analysis of the section of the catalyst for halogen atoms in one direction with an electron probe microanalyzer (EPMA) which shows a curve of intensity (I) of X-rays vs. distance (x) in the sectional widthwise direction (from one surface of the catalyst), with the alpha ratio being defined by the formula: (F-F0)/F (wherein F is an intensity value of X-rays obtained by integrating the above curve I(x) between one of the surfaces of the catalyst and the other thereof anf F0 is one obtained by integrating the tangent line I0(x) of the above curve at the minimum and lowest point thereof between them; and a process for the preparation of a halogen-containing catalyst, characterized by making a carrier such as L-zeolite support a halogen thereon and drying the resulting carrier at an evaporation rate of moisture of 15 wt.%/h or below. The catalyst has a uninform halogen distribution and is therefore lowered in the decomposing activity, thus being suitable for the preparation of aromatic hydrocarbons.

69. 发明公开

EP1010745A1 Dehydrocyclization process with downstream dimethylbutane removal 审中-公开
标题翻译：脱水仙人掌on ender ender。。。。。。。。。。。。。
公开(公告)号：EP1010745A1
公开(公告)日：2000-06-21
申请号：EP98310451.4
申请日：1998-12-18
申请人： Chevron Chemical Company LLC
发明人： Witte, David H.
IPC分类号： C10G61/02 , C07C5/41
CPC分类号： C10G61/02 , C07C5/417 , C07C2529/22 , C07C2529/62 , C07C2529/74
摘要： In the present invention, dimethylbutanes are removed from the raffinate component of the feed to a dehydrocyclization process. Thus, according to a preferred embodiment, a process is provided for producing aromatics by the following steps:

(a) contacting fresh paraffins rich feed hydrocarbons, containing 0.1 to 20.0 wt. % dimethylbutanes with a highly selective dehydrocyclization catalyst in a reaction zone, under dehydrocyclization reaction conditions, to convert paraffins to aromatics and obtain an aromatics rich effluent;
(b) separating aromatics from the effluent to obtain an aromatics lean raffinate;
(c) removing dimethylbutanes from the raffinate to obtain a raffinate of reduced dimethylbutane content; and
(d) recycling the raffinate of reduced dimethylbutane content to the reaction zone.

Preferably, the dehydrocyclization catalyst used is a nonacidic, monofunctional catalyst. Platinum on L zeolite is a particularly preferred highly selective dehydrocyclization catalyst for use in the process.
摘要翻译：在本发明中，将二甲基丁烷从进料的萃余液组分中除去脱氢环化过程。因此，根据优选的实施方案，提供了通过以下步骤生产芳族化合物的方法：（a）使含有0.1至20.0重量％％二甲基丁烷与高选择性脱氢环化催化剂在反应区内，在脱氢环化反应条件下，将烷烃转化为芳族化合物，并获得富含芳烃的流出物; （b）从流出物中分离出芳族化合物以获得芳烃贫残余物; （c）从萃余液中除去二甲基丁烷以获得还原的二甲基丁烷含量的萃余液; 和（d）将还原的二甲基丁烷含量的残液回收到反应区。优选地，所用的脱氢环化催化剂是非酸性单官能催化剂。 L沸石上的铂是用于该方法的特别优选的高选择性脱氢环化催化剂。

70. 发明公开

EP0788838A4 HYDROCARBON CONVERSION CATALYST AND METHOD OF CATALYTIC CONVERSION THEREWITH 失效
标题翻译：催化剂用于烃的FOR与催化剂的催化转化转化和方法
公开(公告)号：EP0788838A4
公开(公告)日：1999-08-11
申请号：EP95933621
申请日：1995-10-05
申请人： ASAHI CHEMICAL IND
发明人： TSUNODA TAKASHI , SEKIGUCHI MITSUHIRO , KANESHIMA TOKITAKA
IPC分类号： B01J29/064 , B01J29/068 , B01J29/44 , B01J29/46 , C07B61/00 , C07C4/06 , C07C5/393 , C07C5/41 , C07C11/02 , C07C15/02 , C10G11/02 , C10G11/05 , C10G35/095 , C10G47/20
CPC分类号： B01J29/44 , B01J29/068 , C07C4/06 , C07C5/415 , C07C2529/40 , C10G11/05 , C10G11/18 , C10G2400/20 , C10G2400/30 , C07C15/02
摘要： A hydrocarbon conversion catalyst comprising an intermediate-pore-size zeolite which has an SiO2 to Al2O3 ratio of at least 20 by mole, contains one or more Group Ib metals and is substantially free of protons. The catalyst permits lower olefins mainly comprising ethylene and monocyclic aromatic hydrocarbons to be produced in high yields at a good balance therebetween, and is stable because of being reduced in the deterioration due to high-temperature steam.

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