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    • 66. 发明公开
    • Microporous materials incorporating a nucleating agent and methods for making same
    • Nukleierungsmittel enthaltende mikroporeuse Materialien und Verfahren zur Herstellung derselben。
    • EP0273582A1
    • 1988-07-06
    • EP87310371.7
    • 1987-11-25
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • Mrozinski, James S. c/o Minnesota Mining and
    • C08J5/18C08J9/28
    • B29C55/005B29C47/0004B29C47/0021B29K2105/045Y10T428/249978Y10T428/249986Y10T428/24999
    • The present invention relates to microporous materials incorporating a nucleating agent and methods for making the same. The method comprises the steps of melt blending a crystallizable thermoplastic polymer with a nucleating agent which is capable of inducing subsequent crystallization of the thermoplastic polymer and with a compound which is miscible with the thermoplastic polymer at the melting temperature of the polymer but phase separates on cooling at or below the crystallization temperature of the polymer, forming a shaped article of the melt blend, cooling the shaped article to a temperature at which the nucleating agent induces the thermoplastic polymer to crystallize so as to cause phase separation to occur between the thermoplastic polymer and the compound, thereby providing an article comprising an aggregate of a first phase comprising particles of crystallized thermoplastic polymer in a second phase of the compound, and stretching the article in at least one direction to provide a network of interconnected micropores throughout. Preferably, the compound is removed either before or after stretching. The use of a nucleating agent in accordance with the present invention provides for the manufacture of a wide variety of microporous materials heretofore not possible having a wide range of porosity and other physical characteristics.
    • 本发明涉及结合成核剂的微孔材料及其制造方法。 该方法包括以下步骤:将可结晶的热塑性聚合物与成核剂熔融共混,所述成核剂能够诱导热塑性聚合物的随后的结晶,以及在聚合物的熔融温度下可与热塑性聚合物混溶的化合物,但在冷却时相分离 在聚合物的结晶温度或低于聚合物的结晶温度下,形成熔融共混物的成型制品,将成形制品冷却至成核剂诱导热塑性聚合物结晶的温度,以便在热塑性聚合物和 化合物,从而提供包含在化合物的第二阶段中包含结晶的热塑性聚合物颗粒的第一相的聚集体的制品,并且在至少一个方向上拉伸制品以提供整个相互连接的微孔的网络。 优选地,在拉伸之前或之后除去化合物。 根据本发明的成核剂的使用提供了迄今不可能具有宽范围的孔隙率和其它物理特性的各种微孔材料的制造。
    • 67. 发明公开
    • Microporous sheet material, method of making and articles made therewith
    • Mikroporösesblattförmiges材料,Verfahren zur Herstellung und damit hergestellteGegenstände。
    • EP0105629A2
    • 1984-04-18
    • EP83305161.8
    • 1983-09-06
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • Shipman, Gene H. c/o Minnesota Mining and
    • B29C67/20C08J9/08C08J5/18B32B5/18C08J9/22
    • H01M2/14B01D67/0027B01D2323/12B29C55/005C08J5/18C08J9/228C08J9/28C08J2201/0543C08J2201/0546
    • A method of making a microporous sheet is provided which comprises the steps of melt blending crystallizable thermoplastic polymer with a compound which is miscible with the thermoplastic polymer at the polymer melting temperature but immiscible on cooling below the polymer melting temperature, forming a sheet of the melt blend, cooling the sheet to a temperature at which the compound becomes immiscible with the polymer to cause phase separation to occur between the thermoplastic polymer and the compound to provide a sheet comprising a first phase comprising particles of thermoplastic polymer in a second phase of said compound, orienting the film in at least one direction to provide a network of interconnected micropores throughout the sheet. The microporous sheet comprises about 30 to 80 parts by weight crystallizable thermoplastic polymer and correspondingly about 70 to 20 pans by weight of the compound. The oriented sheet has a microporous structure characterized by a multiplicity of spaced randomly dispersed, equiaxed, non-uniform shaped, non-porous particles of the thermoplastic polymer which are coated with the compound. Adjacent thermoplastic particles within the sheet are connected to each other by a plurality of fibrils consisting of the thermoplastic polymer. The fibrils radiate in three dimensions from each particle. The compound may be removed from the sheet. e.g., by solvent extraction.
    • 提供一种制备微孔片的方法,其包括以下步骤:将可结晶的热塑性聚合物与在聚合物熔融温度下可与热塑性聚合物混溶但在低于聚合物熔融温度的冷却下不混溶的化合物熔融共混,形成熔体 混合,将片材冷却至化合物与聚合物不混溶的温度,以引起在热塑性聚合物和化合物之间发生相分离,以提供包含第一相的片材,该第一相包含所述化合物的第二相中的热塑性聚合物颗粒 使薄膜沿至少一个方向取向,从而提供整个薄片中相互连接的微孔网络。 该微孔片包含约30至80重量份的可结晶的热塑性聚合物和相应的约70至20重量份的化合物。 定向片材具有微孔结构,其特征在于涂覆有化合物的多个间隔开的无规分散的等轴,不均匀的,不均匀的,无孔的热塑性聚合物颗粒。 片材内相邻的热塑性颗粒通过由热塑性聚合物组成的多个原纤维相互连接。 原纤维从每个颗粒三维辐射。 化合物可以从片材中除去,例如通过溶剂萃取。