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51. 发明公开

EP1162225A4 HARDENER FOR EPOXY RESIN AND EPOXY RESIN COMPOSITION 有权
标题翻译： HÄRTUNGSMITTELFÜREPOXYDHARZE UND EPOXYDHARZZUSAMMENSETZUNG
公开(公告)号：EP1162225A4
公开(公告)日：2003-03-05
申请号：EP00969847
申请日：2000-10-18
申请人： OTSUKA KAGAKU KK
发明人： KITAJIMA TAKASHI , NABESHIMA AKIHIRO
IPC分类号： C08G59/50 , C08G59/40 , C08G59/56 , C08K3/18 , C08K5/17 , C08K5/3415 , C08K13/02 , C08L63/00 , C09D163/00
CPC分类号： C08G59/56 , C08G59/4035
摘要： A hardener for epoxy resins which comprises as the active ingredients a compound represented by formula (1): NH2N(R )(R ); or salt thereof and an amine compound or salt thereof, characterized in that at least either of the compound represented by formula (1) and the amine compound is a thiocyanate; and an epoxy resin composition containing the hardener. (In the formula, R and R are the same or different and each represents C1-8 alkyl, aryl, or a nitrogenous heterocyclic group or R and R are bonded together to form C2-11 alkylene or a group represented by R -R -R -, wherein R and R are the same or different and each represents C1-8 alkylene and R represents oxygen, sulfur, or a group represented by =NR or =NNH2, provided that R represents hydrogen or C1-8 alkyl.)
摘要翻译：一种环氧树脂用固化剂，其含有式（1）所示的化合物作为有效成分：NH 2 N（R 1）（R 2）或其盐和胺化合物或其盐，其特征在于由式（1）表示的化合物和胺化合物中的至少一种是硫氰酸盐; 和含有该硬化剂的环氧树脂组合物。（式中，R 1和R 2相同或不同，表示碳原子数1〜8的烷基，芳基或含氮杂环基，或者R 1和R 2键合而形成C 2 -11亚烷基或由R 3 -R 4 -R 5 - 表示的基团，其中R 3和R 5相同或不同并且各自表示C 1-8亚烷基和R 4 表示氧，硫或由= NR 6或= NNH 2表示的基团，条件是R 6表示氢或C 1-8烷基。）

52. 发明公开

EP1200502A1 AMINHÄRTER FÜR EPOXIDHARZE 有权
标题翻译： AMIN硬化剂的环氧树脂
公开(公告)号：EP1200502A1
公开(公告)日：2002-05-02
申请号：EP00944045.4
申请日：2000-07-20
申请人： Vantico AG
发明人： FISCHER, Walter , GABUTTI, Claudio, Alexander , FRISCHINGER, Isabelle , WIESENDANGER, Rolf
IPC分类号： C08G59/66 , C08G59/56 , C07C323/25
CPC分类号： C07C323/25 , C08G59/56 , C08G59/66
摘要： The invention relates to compounds of formula (Ia) or (Ib). In said formulas, A represents an aliphatic, cycloaliphatic, araliphatic or aromatic radical of the value (n + 1) and n is a whole number from 0 to 5, E represents an aliphatic, cycloaliphatic, araliphatic or aromatic radical of the value (m + 1) and m is a whole number from 0 to 3, X stands for -O-, -COO-, or -CHR4-, whereby R4 and R3 together form an ethylene group, R1 and R2 independently of one another represent hydrogen or methyl, R3 represents hydrogen or R3 and R4 together form an ethylene group, and R5 represents a monovalent aliphatic, cycloaliphatic, araliphatic or aromatic radical. The inventive compounds are highly reactive hardening agents for epoxy resins and produce hardened products with improved chemical resistance.

53. 发明公开

EP1156085A1 Binders for use in cathodic electrodeposition coatings, process for their preparation and cathodic electrodeposition coating compositions containing same 有权
标题翻译：作为阴极电沉积粘合剂可用的，它们的制备方法和含有这些阴极电沉积涂料组合物
公开(公告)号：EP1156085A1
公开(公告)日：2001-11-21
申请号：EP01303990.4
申请日：2001-05-01
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Hoenig, Helmut , Gmoser, Johann , Feola, Roland , Thausz, Robert
IPC分类号： C09D5/44 , C09D163/00 , C08G59/56
CPC分类号： C08G59/56 , C09D5/4434 , C09D163/00
摘要： Novel alkaline polymeric binders, preferably amino epoxy binders, for use in cathodic electrodeposition coatings have a number average molecular mass of 1000 to 3000, an amine value of 150 to 250 mg KOH/g binder and 50 to 230 milliequivalents/100 g binder of beta-hydroxyalkyl urethane groups of the formula HOC n H 2n OC(O)NH- where n = 2 to 3, as well as processes for making such binders; aqueous compositions, particularly cathodic electrodeposition compositions containing such binders (which provide improved throwing power); and process of using such compositions, particularly on automotive bodies and parts thereof, are disclosed.
摘要翻译：新型碱性聚合物粘合剂，优选氨基环氧树脂粘合剂，在阴极电沉积涂料具有许多千均分子量3000至150至250毫克KOH /克的粘合剂和50至230毫当量/测试100克粘合剂的胺值羟烷基的式HOCnH2nOC的氨基甲酸酯基团（O）NH-，其中n = 2〜3，以及用于使搜索粘合剂过程; 水性组合物，特别是阴极电沉积的组合物含检测粘合剂（提供改善泳透力）; 并且使用搜索的组合物，特别是对汽车车身，其部分的过程中，是游离缺失盘。

54. 发明公开

EP1111013A1 Cationic coating composition 有权
标题翻译： Kationische Beschichtungszusammensetzung
公开(公告)号：EP1111013A1
公开(公告)日：2001-06-27
申请号：EP00127290.5
申请日：2000-12-19
申请人： KANSAI PAINT CO., LTD.
发明人： Nishiguchi, Shigeo , Kamikado, Koji , Hiraki, Tadayoshi , Tominaga, Akira
IPC分类号： C09D5/44 , C08G59/56 , C08G59/62
CPC分类号： C09D5/4434 , C08G59/56 , C08G59/626 , Y10T428/31511 , Y10T428/31515 , Y10T428/31518 , Y10T428/31522 , Y10T428/31525 , Y10T428/31529
摘要： The present invention provides a cationic coating composition capable of forming a coating film which is excellent in a corrosion resistance and an adhesive property and an electrodepositably coating property toward a rust preventive steel plate (zinc-plated steel plate). The cationic coating composition described above comprises as a vehicle component, a polyol-modified, amino group-containing epoxy resin prepared by reacting an epoxy resin (A) having an epoxy equivalent of 180 to 2500 with a polyol compound (B) obtained by adding caprolactone to a compound having plural active hydrogen groups and an amino group-containing compound (C).
摘要翻译：本发明提供一种阳离子涂料组合物，其能够形成对防锈钢板（镀锌钢板）的耐腐蚀性，粘合性和电沉积涂布性优异的涂膜。上述阳离子涂料组合物包含通过环氧当量为180〜2500的环氧树脂（A）与多元醇化合物（B）反应制备的多元醇改性的含氨基的环氧树脂作为载体成分，己内酯与具有多个活性氢基团和含氨基化合物（C）的化合物反应。

55. 发明公开

EP0949286A4 CURATIVES FOR EPOXY RESIN, CURING ACCELERATOR, AND EPOXY RESIN COMPOSITION 失效
标题翻译： EPOXIDHARZHÄRTER，HÄRTUNGSBESCHLEUNIGERUND EPOXIDHARZZUSAMMENSETZUNG
公开(公告)号：EP0949286A4
公开(公告)日：2000-12-20
申请号：EP97950428
申请日：1997-12-26
申请人： NIPPON SODA CO
发明人： SUZUKI HIROSHI , AOKI IZUO , ABE SATORU
IPC分类号： C08G59/18 , C08G59/50 , C08G59/56 , C08G59/62 , C08G59/68 , C08L63/00
CPC分类号： C08G59/68 , C08G59/18 , C08G59/5093 , C08G59/56 , C08G59/621
摘要： Curatives for epoxy resins and curing accelerators for epoxy resins which both have improved subliming and decomposing properties and which, when mixed with an epoxy resin, enable the mixture to be greatly improved in thermal stability that is extremely important for the control of a curing reaction and to have a prolonged pot life (stability as a one-pack mixture comprising the epoxy resin, curative, etc.) and improved curability at low temperatures. The curative is characterized by being a clathrate comprising a tetrakisphenol compound represented by general formula (I) and a compound which reacts with the epoxy group of an epoxy resin to cure the resin, wherein X represents (CH2)n, where n is 0, 1, 2, or 3; and R to R each represents hydrogen, lower alkyl, optionally substituted phenyl, halogeno, or lower alkoxy; and the other curative is characterized by being a clathrate comprising a tetrakisphenol compound represented by general formula (I) and a compound accelerating the curing of a compound which reacts with the epoxy group of an epoxy resin to cure the resin.
摘要翻译：本发明的目的是提供用于环氧树脂的固化剂和用于环氧树脂的固化促进剂，它们都具有改进的升华和分解性能，并且当与环氧树脂混合时，能够使混合物的热稳定性大大提高对于固化反应的控制是重要的，并且具有延长的适用期（作为包含环氧树脂的单组分混合物的稳定性，固化剂等）和在低温下提高的固化性。固化剂的特征在于包含由通式[1]表示的四苯酚化合物的包合物; 其中X表示（CH 2）n，其中n为0,1,2或3，R 1至R 8各自表示氢，低级烷基，任选取代的苯基，卤代或低级烷氧基，固化促进剂为其特征在于包含由上述通式[I]表示的四苯酚化合物和加速与环氧树脂的环氧基反应的化合物的固化以固化树脂的化合物的包合物。

56. 发明公开

EP1040150A1 NOVOLAKS AS WATER-UNAFFECTED ACCELERATORS FOR EPOXY RESIN HARDENERS 有权
标题翻译：酚醛清漆比水RESISTANTS加速硬化剂
公开(公告)号：EP1040150A1
公开(公告)日：2000-10-04
申请号：EP98965197.1
申请日：1998-11-28
申请人： Vantico GmbH & Co. KG
发明人： SCHERZER, Wolfgang , VOLLE, Jörg
IPC分类号： C08G59/56 , C08K5/13 , C08L63/00
CPC分类号： C08K5/0008 , C08G59/50 , C08G59/68 , C08L63/00 , C08L61/04
摘要： Curable mixtures based on epoxy resins and amine hardeners, if required additionally using solvents, water, plasticisers, UV stabilisers, colourants, pigments, fillers, which mixtures contain as accelerator at least one compound of general formula (I), wherein R?1, R2, R3, R4¿ are each independently of one another H or an unbranched or branched alkyl radical containing 1 to 15 carbon atoms, and n is 0 to 10.

57. 发明授权

EP0059434B2 Multi-layer printed circuit board and process for production thereof 失效
标题翻译：多层印刷电路板和过程及其制备
公开(公告)号：EP0059434B2
公开(公告)日：1999-08-25
申请号：EP82101447.9
申请日：1982-02-25
申请人： Hitachi, Ltd.
发明人： Takahashi, Akio , Shimazaki, Takeshi , Wajima, Motoyo , Morishita, Hirosada
IPC分类号： C08L79/08 , C08L63/00 , C08G59/40 , C08G59/56 , B32B27/04 , H05K1/02
CPC分类号： B32B27/08 , B32B27/04 , B32B2260/046 , B32B2305/076 , B32B2457/08 , C08G59/4042 , C08G59/56 , C08G73/0644 , C08J5/24 , C08L79/08 , C08L79/085 , H01B3/30 , H05K1/0346 , H05K3/4623 , H05K3/4688 , H05K2201/0154 , H05K2201/09536 , H05K2203/061 , H05K2203/1105 , Y10S428/901 , Y10T428/31511 , Y10T428/31721

58. 发明授权

EP0723982B1 Härtbares Epoxidharzgemisch 失效
标题翻译：可固化的环氧树脂混合物
公开(公告)号：EP0723982B1
公开(公告)日：1999-06-16
申请号：EP96810039.6
申请日：1996-01-17
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： Beisele, Christian
IPC分类号： C08G59/56 , C08L63/00
CPC分类号： C08G59/56 , C08G59/226 , C08G59/38 , C08L63/00 , C08L2666/22

59. 发明公开

EP0921142A1 Improved curing catalysts for curing epoxy resins 失效
标题翻译： VerbesserteHärtungskatalysatorengeeignetfürdieHärtungvon Epoxidharzen
公开(公告)号：EP0921142A1
公开(公告)日：1999-06-09
申请号：EP97309841.1
申请日：1997-12-05
申请人： The Dow Chemical Company
发明人： Gan, Joseph , Hoffmann, Klaus E. , Badini, Gabriele
IPC分类号： C08G59/50 , C08G59/56
CPC分类号： C08G59/5073 , C08G59/182 , C08G59/56
摘要： A formulation which contains:

(1)the nucleophilic addition adduct of an imidazole and an unsaturated compound, which contains more than one imidazole moiety per molecule; and
(2) an epoxy resin,
is characterized in that fewer than 50 equivalent percent of the imidazole moieties in the adduct are neutralized with acid. The adduct may serve as a curing catalyst in high or low-temperature curing. The formulation is made and applied as a powder coating for coatings or as a matrix resin in laminates. It may be used in solvent-borne or liquid systems.
摘要翻译：一种制剂，其包含：（1）咪唑和不饱和化合物的亲核加成加合物，其每分子含有多于一个咪唑部分; 和（2）环氧树脂，其特征在于加合物中少于50当量的咪唑部分用酸中和。该加合物可用作高温或低温固化中的固化催化剂。该制剂被制成并用作涂层的粉末涂料或作为层压材料中的基质树脂。它可用于溶剂型或液体系统。

60. 发明公开

EP0736556A2 Wollastonit enthaltendes, härtbares Epoxidharzgemisch 无效
标题翻译： Wollastonit enthaltendes，härtbaresEpoxidharzgemisch
公开(公告)号：EP0736556A2
公开(公告)日：1996-10-09
申请号：EP96810187.3
申请日：1996-03-26
申请人： CIBA-GEIGY AG
发明人： Beisele, Christian
IPC分类号： C08G59/50 , C08G59/56 , C08G59/60 , C08K3/34 , C08L63/02
CPC分类号： C08K3/34 , C08G59/56 , C08L63/00 , C08L2666/22
摘要： Ein härtbares Epoxidharzgemisch, bestehend aus

a) 90 bis 100 Gew.-% einer aromatischen Glycidyletherverbindung mit mehr als einer Glycidylethergruppe im Molekül und 0 bis 10 Gew-% eines von aromatischen Polyglycidylethern verschiedenes Epoxidharz, wobei die Summe der Epoxidharze 100 Gew.% beträgt,
b) 60 bis 100 Gew.-% eines Polyoxyalkylendi- oder -triamins und 0 bis 40 Gew.-% eines von Polyoxyalkylenaminen verschiedenen Härtungsmittels, wobei die Summe der Härtungsmittel 100 Gew.% beträgt,
c) Wollastonit oder einem anorganischen Füllstoff, der mehr als 50 Gew-% Wollastonit enthält, bezogen auf die gesamte Menge des anorganischen Füllstoffes, und gegebenenfalls
d) einem Härtungsbeschleuniger und
e) Glasfasern oder üblichen Zusatzmitteln für Giessharze auf Basis von Epoxidharzen, eignet sich vorzugsweise als Giessharzmasse zum Umhüllen oder Eingiessen von elektrischen oder eloktronischen Bauteilen.
摘要翻译：可硬化环氧树脂混合物。含有（a）90-100重量％的芳族缩水甘油醚cpd。与多于一个缩水甘油醚gp。和10-0％的不同于芳族聚缩水甘油醚的环氧树脂，（b）60-100％的聚氧化烯二 - 或三胺和40-0％的不同硬化剂，（c）硅灰石或无机填料。超过50重量％的硅灰石，w.r.t. 总填料和选择。（d）硬化促进剂，（e）玻璃纤维或其它用于浇铸基于环氧树脂的树脂的添加剂。

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