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51. 发明公开

EP3135695A1 PROCESS FOR CONTINUOUS POLYMERIZATION OF OLEFIN MONOMERS IN A REACTOR 审中-公开
标题翻译： EEREM REAKTOR VERFAHREN ZUR KONTINUIERLICHEN POLYMERISATION VON OLEFINMONOMEREN
公开(公告)号：EP3135695A1
公开(公告)日：2017-03-01
申请号：EP15182740.9
申请日：2015-08-27
申请人： SABIC Global Technologies B.V.
发明人： BANAT, Yahya , WAJEEH, Moughrabiah
IPC分类号： C08F2/01 , B01J8/08 , B01J8/18 , B01J8/24 , C08F2/34
CPC分类号： C08F2/01 , B01J8/08 , B01J8/18 , B01J8/24 , C08F2/34 , C08F210/16 , C08F210/06 , C08F2/00
摘要： The invention relates to a process and system for the continuous polymerization of one or more α-olefin monomers comprising the steps of:
(a) withdrawing fluids from a reactor
(b) cooling fluids comprising the withdrawn fluids with a cooling unit
(c) introducing the cooled fluids to a separator to separate at least part of the liquid from these fluids to form a liquid phase and a gas/liquid phase
(d) introducing the gas/liquid phase below to the reactor below a distribution plate
(e) introducing the liquid phase to a settling tank to separate liquid from fines that settle down in the settling tank
(f) introducing liquid from the settling tank upstream of the cooling unit.
摘要翻译：本发明涉及一种或多种α-烯烃单体的连续聚合的方法和系统，包括以下步骤：（a）从反应器中取出流体（b）用冷却单元冷却包含排出的流体的流体（c）引入将冷却的流体输送到分离器以将至少部分液体与这些流体分离以形成液相和气/液相（d）将下面的气/液相引入到分配板下方的反应器（e）液相到沉淀池，以将液体与沉降在沉淀池中的细粉分离（f）将来自沉淀槽的液体从冷却单元的上游引入。

52. 发明公开

EP3121199A1 HIGH-PRESSURE POLYMERIZATION PROCESS OF ETHYLENICALLY UNSATURATED MONOMERS IN A TUBULAR REACTOR 有权
标题翻译：在管状反应器的烯属不饱和单体的HOCHDRUCKPOLYMERISIERUNGSVERFAHREN
公开(公告)号：EP3121199A1
公开(公告)日：2017-01-25
申请号：EP15178042.6
申请日：2015-07-23
申请人： Basell Polyolefine GmbH
发明人： Littmann, Dieter , Mohrbutter, Jürgen , Mei, Giulia , Finette, Andre-Armand , Wolfram, Sven , Deuerling, Michael , Khayrullin, Danir , Groos, Georg , Wolf, Christoph
IPC分类号： C08F2/01 , C08F2/34
CPC分类号： C08F110/02 , B01J19/2415 , C08F2/01 , C08F2/34 , C08J5/18 , C08J2323/06 , C08F2/00 , C08F2500/12 , C08F2500/26
摘要： A process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100°C to 350°C and pressures in the range from 180 MPa to 340 MPa with a specific reactor surface area A sp of 2 m 2 /(t/h) to 5.5 m 2 /(t/h) and the tubular reactor has a specific ratio RD sp of from 0.0050 MPa -1 to 0.0069 MPa -1 and an inner surface which has a surface roughness Ra of 2 µm or less.
摘要翻译：到一种聚合或自由基聚合引发剂的存在下共聚合烯属不饱和单体，worin聚合在一个连续操作的管式反应器在温度100℃下从180兆帕进行，以350℃和压力范围为过程为340MPa与特定表面区域SP为2m 2 /（T / H）的〜5.5米2 /（吨/小时）和管式反应器的反应器具有从0.0050 MPa至0.0069兆帕-1的特定比例RD SP - 1和帧内表面具有表面粗糙度Ra为2微米或更小。

53. 发明公开

EP3109262A1 HIGH PRESSURE, FREE RADICAL POLYMERIZATIONS TO PRODUCE ETHYLENE-BASED POLYMERS 审中-公开
标题翻译：放射性化学品分子式聚合物UR UR ON ON ON ON EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN
公开(公告)号：EP3109262A1
公开(公告)日：2016-12-28
申请号：EP16382298.4
申请日：2016-06-24
申请人： Dow Global Technologies LLC
发明人： Berbee, Otto J. , Dang, Nhi T. Y. , Hosman, Cornelis J F , Flores, Joaquin
IPC分类号： C08F2/01 , C08F2/34 , B01J12/00 , F25B49/02
CPC分类号： C08F2/34 , A46B11/06 , B01J12/00 , B05C17/00503 , B05C17/00569 , B05C17/00573 , C08F2/00 , C08F2/01 , C08F210/02 , Y02P20/582
摘要： The invention provides a high pressure polymerization process to form an ethylene-based polymer, the process comprising at least the following steps:
polymerizing a reaction mixture comprising ethylene, using a reactor system comprising at least three ethylene-based feed streams and a reactor configuration that comprises at least four reaction zones, and
wherein at least one of the following distributions a) through c), is met:
(a) up to 100 wt% of the ethylene-based feed stream to the first reaction zone comes from a high pressure recycle, and/or up to 100 wt% of the last ethylene-based feed stream to a reaction zone comes from the output from a Primary compressor system; and/or
(b) up to 100 wt% of the ethylene-based feed stream to first reaction zone comes from the output from a Primary compressor system, and/or up to 100 wt% of the last ethylene-based feed stream to a reaction zone comes from a high pressure recycle; and/or
(c) the ethylene-based feed stream to the first reaction zone, and/or the last ethylene-based feed stream to a reaction zone, each comprises a controlled composition;
and wherein each ethylene based feed stream to a reaction zone, independently, receives an output from two or more cylinders of the last compressor stage of a Hyper compressor system;
and wherein the ethylene based feed stream to the first reaction zone is from 20 wt% to 60 wt% of the total ethylene based feed stream to the reactor configuration; and
wherein the sum of the last two ethylene based feed streams to the reactor configuration is from 20 wt% to 80 wt% of the total ethylene based feed streams to the reactor configuration.
摘要翻译：本发明提供了形成乙烯基聚合物的高压聚合方法，该方法包括至少以下步骤：使用包含至少三个基于乙烯的进料流的反应器系统和包含乙烯的反应混合物聚合反应混合物，反应器构型包含至少四个反应区，并且其中满足以下分布a）至c）中的至少一个：（a）至多100重量％的至第一反应区的基于乙烯的进料流来自高压再循环和/或最多100重量％的最后一个基于乙烯的进料流到反应区来自主压缩机系统的输出; 和/或（b）至多100重量％的至第一反应区的基于乙烯的进料流来自主压缩机系统的输出，和/或最多100重量％的最后的乙烯基进料流至反应区来自高压循环; 和/或（c）到第一反应区的乙烯进料流和/或最后的进入反应区的基于乙烯的进料流各自包含受控组合物; 并且其中独立于反应区的每个基于乙烯的进料流接收超级压缩机系统的最后压缩机级的两个或更多个气缸的输出; 并且其中到所述第一反应区的所述基于乙烯的进料流为所述反应器构型的总乙烯基进料流的20重量％至60重量％并且其中到反应器构型的最后两个基于乙烯的进料流的总和为反应器构型的总乙烯基进料流的20重量％至80重量％。

54. 发明公开

EP3105257A2 PRODUCING POLYOLEFIN PRODUCTS WITH IMPROVED STIFFNESS, TOUGHNESS, AND PROCESSABILITY 有权
标题翻译： HERSTELLUNG VON POLYOLEFINPRODUKTEN MIT VERBESSERTER STEIFIGKEIT，ZÄHIGKEITUND VERARBEITBARKEIT
公开(公告)号：EP3105257A2
公开(公告)日：2016-12-21
申请号：EP15705878.5
申请日：2015-02-10
申请人： Univation Technologies, LLC
发明人： LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, JR. Daniel P.
IPC分类号： C08F2/34 , C08F210/02 , C08F210/16 , C08F4/6592 , C08J5/18
摘要： Polymers, and systems and methods for making and using the same are described herein. A polymer includes ethylene and at least one alpha olefin having from 4 to 20 carbon atoms. The polymer has a melt index ratio (MIR) greater than about 40. The polymer also has a value for Mw1/Mw2 of at least about 2.0, wherein Mw1/Mw2 is a ratio of a weight average molecular weight (Mw) for a first half of a temperature rising elution (TREF) curve from a cross-fractionation (CFC) analysis to an Mw for a second half of the TREF curve. The polymer also has a value for Tw1−Tw2 of less than about −15° C., wherein Tw1−Tw2 is a difference of a weight average elution temperature (Tw) for the first half of the TREF curve to a Tw for the second half of the TREF curve.
摘要翻译：催化剂系统及其制造和使用方法。聚合烯烃以制备具有多峰组成分布的聚烯烃聚合物的方法包括使乙烯和共聚单体与催化剂体系接触。催化剂体系包括第一催化剂化合物和第二催化剂化合物，其共同负载以形成通常负载的催化剂体系。第一催化剂化合物包括具有通式（C5HaR1b）（C5HcR2d）HfX2的化合物。第二催化剂化合物包括以下通式中的至少一种：在两种催化剂体系中，R基团可以独立地选自任意数量的取代基，包括例如H，烃基，取代的烃基或杂原子基团等。

55. 发明授权

EP2903732B1 SYSTEMS AND PROCESSES FOR STORING RESIN 有权
标题翻译：系统和方法树脂储存
公开(公告)号：EP2903732B1
公开(公告)日：2016-11-23
申请号：EP13776672.1
申请日：2013-10-01
申请人： Univation Technologies, LLC
发明人： WHITE, Simon, J. , HASBARGEN, Alison, H.
IPC分类号： B01J8/18 , C08F10/00 , C08F2/34
CPC分类号： B65G53/16 , B01J8/0015 , B01J8/0025 , B01J8/1809 , B01J2208/00212 , C08F2/34 , C08F10/00 , Y10T137/6579

56. 发明授权

EP2913345B1 Gas phase polymerization process 有权
标题翻译：气相聚合
公开(公告)号：EP2913345B1
公开(公告)日：2016-11-02
申请号：EP14157153.9
申请日：2014-02-28
申请人： Borealis AG
发明人： Kanellopoulos, Vasileios , Krallis, Apostolos , Al-haj Ali, Mohammad , Tupe, Ravindra
IPC分类号： C08F2/01 , C08F2/34
CPC分类号： C08F2/34 , C08F2/01 , C08F110/02

57. 发明公开

EP3074434A1 MULTI-ZONE REACTOR FOR CONTINUOUS POLYMERIZATION OF ALPHA OLEFIN MONOMERS 有权转让
标题翻译： EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN EN
公开(公告)号：EP3074434A1
公开(公告)日：2016-10-05
申请号：EP14803091.9
申请日：2014-11-24
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： BANAT, Yahya , CEVALLOS-CANDAU, Jose Fernando
IPC分类号： C08F10/00 , C08F2/01 , C08F2/34
CPC分类号： C08F10/06 , B01J8/085 , B01J19/2465 , B01J2208/00938 , B01J2219/00033 , B01J2219/185 , C08F2/34 , C08F10/02 , C08F10/00 , C08F2/01 , C08F2/00
摘要： The invention relates to a multi-zone reactor for the continuous fluidized bed polymerization of one or more α-olefin monomers of which at least one is ethylene or propylene, which multi-zone reactor is operable in condensed mode, which multi-zone reactor comprises a first zone, a second zone, a third zone, a fourth zone and a distribution plate, wherein the second zone contains an inner wall, wherein the third zone contains an inner wall, wherein at least part of the inner wall of the third zone is either in the form of a gradually increasing inner diameter or a continuously opening cone, wherein the diameter or the opening increases in the vertical direction towards the top of the multi-zone reactor, wherein the largest diameter of the inner wall of the third zone is larger than the largest diameter of the inner wall of the second zone.
摘要翻译：本发明涉及一种用于一种或多种α-烯烃单体的连续流化床聚合的多区域反应器，其中至少一种是乙烯或丙烯，该多区域反应器可在冷凝模式下操作，该多区反应器包括第一区域，第二区域，第三区域，第四区域和分布板，其中所述第二区域包含内壁，其中所述第三区域包含内壁，其中所述第三区域的至少部分内壁是呈逐渐增加的内径或连续开口的锥体的形式，其中直径或开口朝着多区域反应器的顶部在垂直方向上增加，其中第三区域的内壁的最大直径大于第二区域的内壁的最大直径。

58. 发明公开

EP3071642A2 METHODS FOR CONTROLLING POLYMER PROPERTIES 有权
标题翻译：方法控制聚合物性能
公开(公告)号：EP3071642A2
公开(公告)日：2016-09-28
申请号：EP14784569.7
申请日：2014-09-25
申请人： Univation Technologies, LLC
发明人： GOODE, Mark G. , ALEXANDRE, Francois , CANN, Kevin J. , KOPP, Barbara J. , MATTHEWS, William A. , MOORHOUSE, John H. , MURE, Cliff R.
IPC分类号： C08L23/08 , C08F210/16 , C08F2/34 , C08F4/24
CPC分类号： C08F210/16 , C08L23/08 , C08F210/14 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F2500/13 , C08F4/24 , C08F2/34 , C08F4/025
摘要： Disclosed herein are methods of controlling polymer properties in polymerization processes that use a chromium-based catalyst. An embodiment discloses a method of producing a polyolefin comprising: contacting a reaction mixture and a reduced chromium oxide catalyst in a gas-phase reactor to produce the polyolefin, wherein the reaction mixture comprises a monomer and a co-monomer; and changing a reaction temperature in the gas- phase reactor by about 1° C or more whereby a gas molar ratio of the co-monomer to the monomer is changed by about 2% or more and a co-monomer content of the polyolefin at substantially constant density is changed by about 2% or more. Additional methods and compositions are also provided.

59. 发明公开

EP2997052A2 MULTISTAGE PROCESS FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：维生素VERFAHREN ZUR POLYMERISIERUNG VON OLEFINEN
公开(公告)号：EP2997052A2
公开(公告)日：2016-03-23
申请号：EP14725670.5
申请日：2014-05-13
申请人： Basell Polyolefine GmbH
发明人： PENZO, Giuseppe , MEI, Gabriele , MEIER, Gerhardus , SCHUELLER, Ulf , CIARROCCHI, Antonio
IPC分类号： C08F210/00 , C08F2/00 , C08F2/34
CPC分类号： C08F110/02 , B01J8/0025 , B01J8/1863 , B01J8/1872 , B01J8/26 , B01J19/245 , B01J2208/00274 , B01J2208/00292 , B01J2208/00557 , B01J2208/00752 , B01J2208/00761 , B01J2208/00769 , B01J2208/00991 , B01J2219/24 , C08F10/00 , C08F2/001 , C08F2/34 , C08F2/01 , C08F2500/12 , C08F2500/07 , C08F2500/24 , C08F2500/18
摘要： A process for polymerizing olefins at temperatures of from 30°C to 140°C and pressures of from 1.0 MPa to 10 MPa in the presence of a polymerization catalyst in a multistage polymerization of olefins in at least two serially connected gas-phase polymerization reactors, the process for transferring polyolefin particles from a first gas-phase polymerization reactor to a second gas-phase polymerization reactor comprising the steps of a) discharging polyolefin particles from the first gas-phase polymerization reactor into a separation chamber in which the polyolefin particles are separated from concomitantly discharged reaction gas, the separation chamber being at a lower pressure than the pressure in the first gas-phase polymerization reactor; b) transferring the polyolefin particles within the separation chamber into a lower part of the separation chamber which contains a bed of polyolefin particles which moves from top to bottom of this part of the separation chamber and into which a fluid is introduced in an amount that an upward stream of the fluid in the bed of polyolefin particles above the fluid introduction point is induced, c) withdrawing polyolefin particles from the lower end of said lower part and transferring them to one of at least two lock hoppers working intermittently in parallel; and d) simultaneously pressurizing another of the at least two lock hoppers working intermittently by means of a gas comprising reaction gas coming from the second gas-phase polymerization reactor, and apparatus for the multistage polymerization of olefins, comprising at least two serially connected gas-phase polymerization reactors and a device for transferring polyolefin particles from an up-stream gas-phase polymerization reactor to a downstream gas-phase polymerization reactor, the transferring device comprising - a gas/solid separation chamber placed downstream of the upstream gas-phase polymerization which gas/solid separation chamber is equipped at a lower part with an inlet for introducing a fluid, and - connected to the gas/solid separation chamber at least two lock hoppers, placed in a parallel arrangement, each connected to the downstream gas-phase polymerization reactor.
摘要翻译：在至少两个串联连接的气相聚合反应器中的烯烃多段聚合中，在聚合催化剂存在下，在30℃至140℃的温度和1.0MPa至10MPa的压力下使烯烃聚合的方法，将聚烯烃颗粒从第一气相聚合反应器转移到第二气相聚合反应器的方法，包括以下步骤：a）将聚烯烃颗粒从第一气相聚合反应器排出到其中分离聚烯烃颗粒的分离室从同时排出的反应气体，分离室的压力低于第一气相聚合反应器中的压力; b）将分离室内的聚烯烃颗粒转移到分离室的下部，该分离室包含聚烯烃颗粒床，该聚烯烃颗粒床从分离室的该部分的顶部向底部移动，并且流体以引起在流体引入点上方的聚烯烃颗粒床中的流体的向上流，c）从所述下部的下端抽出聚烯烃颗粒并将它们转移到平行间歇地工作的至少两个锁定料斗中的一个; 以及d）通过包含来自第二气相聚合反应器的反应气体的气体和用于烯烃的多段聚合的装置同时间歇地加压至少两个锁定料斗中的另一个，包括至少两个串联连接的气 - 将聚合物颗粒从上游气相聚合反应器转移到下游气相聚合反应器的装置，该转移装置包括 - 放置在上游气相聚合下游的气/固分离室，该气/ 固体分离室在下部配备有用于引入流体的入口，并且连接到气/固分离室至少两个并联布置的锁定料斗，每个连接漏斗连接到下游气相聚合反应器。

60. 发明公开

EP2970518A1 PROPYLENE/BUTENE INTERPOLYMER PRODUCTION SYSTEM AND METHOD 有权
标题翻译：系统和方法制备丙烯/丁烯INTERPOLYMER
公开(公告)号：EP2970518A1
公开(公告)日：2016-01-20
申请号：EP14775705.8
申请日：2014-03-13
申请人： W.R. Grace & CO. - CONN.
发明人： PETERSON, Sharon E. , BLOOD, Mark W. , DUNCAN, Theodore
IPC分类号： C08F2/34 , C08F210/04
CPC分类号： C08F210/06 , C08F2/34 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F210/16 , C08F2/001
摘要： The present disclosure provides a process. In an embodiment, the process includes producing a propylene-based polymer in a gas-phase polymerization reactor (10) under polymerization conditions. The polymerization conditions include a combined propylene-plus-propane partial pressure from 290 psia to 450 psia. The process further includes maintaining the combined propylene-plus-propane partial pressure in the range from 290 psia to 450 psia while simultaneously: (i) reducing propylene partial pressure in the gas-phase polymerization reactor; (ii) adding propane to the gas-phase polymerization reactor; (iii) introducing at least one C4-C10 comonomer into the gas-phase polymerization reactor (26); and forming a propylene/C4-C10 interpolymer in the gas-phase polymerization reactor (44).

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