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    • 54. 发明公开
    • Smoker's article
    • 吸烟者的文章
    • EP0740907A1
    • 1996-11-06
    • EP95810294.9
    • 1995-05-03
    • F. J. Burrus SA
    • Meier, Walter M.Wild, JostScanlan, Francis
    • A24D3/16A24B15/10
    • A24D3/166A24B15/10
    • The smoker's article comprises a filter, a tobacco rod and a wrapper. The filter comprises a sorbent consisting of a hydrophobic member of zeolites or zeolite-like molecular sieves, the zeolite or zeolite-like material being defined by the following formula:

              M m M' n [aAlO 2 · b SiO 2 ·cTO 2 ] q Q

         wherein

      M is a monovalent cation,
      M' is a divalent cation
      a, b, c, n, m, and q are numbers which reflect the stoichiometric proportions,
      c, m, n or q can also be zero,
      Al and Si are tetrahedrally coordinated Al and Si atoms,
      T is a tetrahedrally coordinated metal atom being able to replace Al or Si
      and
      Q is a sorbate molecules corresponding to the pore geometry of zeolite,
         the modulus a/b of the zeolite or the zeolite-like material, enclosed in the filter, has a value >400 and the pore size of the sorbent lays wihin the range of 5 to 7 Å;
      and/or the smoker's article contains a tobacco rod containing a catalyst consisting of a hydrated zeolite or a zeolite-like molecular sieve, the said zeolite or zeolite-like material being defined by the following formula:

              M m' M' n' M'' p [a' AlO 2 · b' SiO 2 ·c' TO 2 ] q' Q

         wherein

      M is a monovalent cation
      M' is a divalent cation
      M'' is a trivalent cation
      a', b', c', n', m', p and q' are numbers which reflect the stoichiometric proportions,
      c', m', n', p' or q' can also be zero,
      Al and Si are tetrahedrally coordinated Al and Si atoms,
      T is a tetrahedrally coordinated metal atom being able to replace Al or Si
      and
      Q is a sorbate capable of passing the pore system of the zeolite,
      or of mixtures thereof, which characterized in that the catalyst consisting of a zeolite or the zeolite-like material, enclosed in the tobacco rod is present at least in part in the H form, the Q is mainly water and that the catalyst comprises a thermally stable structure.
      The zeolite sorbent incorporated in the filter reduces harmful products in the main stream smoke and the zeolite catalyst which is incorporated in the tobacco rod reduces harmful products in the side stream smoke
    • 吸烟者的物品包括过滤器,烟丝条和包装物。 该过滤器包括由沸石或沸石状分子筛的疏水性成分组成的吸附剂,该沸石或沸石状物质由下式定义:Mm M'n [aAlO2·bSiO2·cTO2] qQ其中M是 一价阳离子,M'是二价阳离子a,b,c,n,m和q是反映化学计量比例的数字,c,m,n或q也可以是零,Al和Si是四面体配位的Al和 Si原子,T是能够代替Al或Si的四面体配位的金属原子,Q是对应于沸石的孔隙几何结构的包含在过滤器中的沸石或类沸石材料的模量a / b的山梨酸盐分子 ,具有> 400的值,并且吸附剂的孔径范围为5至7埃; 和/或吸烟者的物品含有含有由水合沸石或沸石状分子筛组成的催化剂的烟草棒,所述沸石或沸石状物质由下式定义:Mm'M'n'M“ 其中M是单价阳离子M'是二价阳离子M“是三价阳离子a',b',c',n',m' ,p和q'是反映化学计量比例的数字,c',m',n',p'或q'也可以为零,Al和Si是四面体配位的Al和Si原子,T是四面体配位的金属原子 能够代替Al或Si,并且Q是能够通过沸石的孔隙体系或其混合物的山梨酸盐,其特征在于包含在烟草棒中的由沸石或沸石状材料组成的催化剂是 至少部分以H形式存在,Q主要是水并且催化剂包含热稳定结构。 掺入过滤器中的沸石吸附剂减少了主流烟气中的有害产物,并且掺入烟丝条中的沸石催化剂减少了侧流烟雾中的有害产物