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    • 60. 发明公开
    • ACRYLIC RESIN COMPOSITION
    • ACRYLHARZZUSAMMENSETZUNG
    • EP2781535A1
    • 2014-09-24
    • EP12850003.0
    • 2012-10-30
    • Three Bond Fine Chemical Co., Ltd.
    • NOGAMI, YasutoshiWACHI, Takanori
    • C08G75/04C09J4/02C09J167/06C09J175/14
    • C08L33/10C08F290/061C08F290/064C08F290/067C08G2170/40C08L33/08C09D175/16C09J175/16C08G18/672C08G18/42C08G18/48C08F222/1006
    • [PROBLEM]
      The present invention provides an acrylic resin composition, which has low viscosity and can be cured even by an LED irradiation device with low illuminance, and which provides a cured product with adequate peel strength without addition of an additive for forced peeling, wherein the cured product has both toughness and bendability.
      [SOLUTION]
      An acrylic resin composition, which contains components (A) to (D) as essential components, and contains 1000 to 2000 parts by mass of the component (B), 30 to 250 parts by mass of the component (C), and 10 to 100 parts by mass of the component (D), per 100 parts by mass of the component (A):
      Component (A): an acrylic oligomer,
      Component (B): an acrylic monomer, which contains components (b-1) to (b-3), wherein the components (b-1) to (b-3) each are contained in an amount of at least 20 mass% in the component (B),
      Component (b-1) : an ether-based acrylic monomer and/or an ester-based acrylic monomer,
      Component (b-2): a cyclic hydrocarbon-based acrylic monomer,
      Component (b-3): an aromatic acrylic monomer,
      Component (C): a thiol compound, and
      Component (D): a photoinitiator.
    • 本发明提供一种丙烯酸树脂组合物,其具有低粘度,并且即使通过具有低照度的LED照射装置也能够固化,并且在没有添加强制剥离添加剂的情况下提供具有足够剥离强度的固化产物,其中 固化物具有韧性和弯曲性。 [A]〜(D)成分为丙烯酸树脂组合物,成分(B)为1000〜2000质量份,(C)成分为30〜250质量份, 成分(A):丙烯酸系低聚物,成分(B):丙烯酸类单体,其含有成分(b- (b-1)〜(b-3)中,成分(b-1):成分(b-1):成分(b-1) 醚类丙烯酸类单体和/或酯类丙烯酸类单体成分(b-2):环状烃类丙烯酸类单体成分(b-3):芳香族丙烯酸类单体成分(C):硫醇化合物 ,和组分(D):光引发剂。