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51. 发明授权

EP0773240B1 Solid catalyst component for polymerizing olefins and catalyst for polymerization of olefins 失效
标题翻译：用于烯烃聚合和Olefinpolymersation的固体催化剂组分
公开(公告)号：EP0773240B1
公开(公告)日：2001-08-22
申请号：EP97101378.4
申请日：1995-01-31
申请人： TOHO TITANIUM CO., LTD.
发明人： Hosaka, Motoki , Goto, Kenji , Matsuo, Masahiko , Kataoka, Takuo , Masuyama, Takahiro
IPC分类号： C08F10/00 , C08F4/651 , C08F4/654
CPC分类号： C07F7/006 , C07F7/184 , C08F10/00 , C08F110/06 , C08F4/6465 , C08F4/6567 , C08F4/651 , C08F4/6555 , C08F4/6548 , C08F2500/12 , C08F2500/18

52. 发明授权

EP0660847B1 HIGH TENSILE STRENGTH AMORPHOUS 1-BUTENE/PROPYLENE COPOLYMERS 失效
标题翻译： WITH大的应变强度无定形1-丁烯/丙烯共聚物
公开(公告)号：EP0660847B1
公开(公告)日：2001-05-30
申请号：EP93922144.6
申请日：1993-09-08
申请人： Huntsman Polymers Corporation
发明人： SUSTIC, Andres , ALLEN, George, C.
IPC分类号： C08F210/06 , C08F210/08 , C08F4/654
CPC分类号： C08F210/08 , C08F210/06 , C08F4/6555 , C08F4/6465 , C08F210/16 , C08F2500/17 , C08F2500/20 , C08F2500/16
摘要： A process for the production of propylene/1-butene copolymers comprising: reacting propylene and 1-butene monomers in the presence of a catalyst system comprising: (a) a solid supported catalyst component is prepared by the method comprising: (i) co-comminuting magnesium halide support base and aluminum trihalide in a molar ratio from about 8:0.5 to about 8:3 in the absence of added electron donor; and (ii) then co-comminuting the product of step (i) in the absence of added electron donor with sufficient titanium tetrahalide to provide a molar ratio of magnesium halide to titanium tetrahalide from about 8:0.1 to about 8:10; (b) a trialkylaluminum co-catalyst, having from 1 to 9 carbon atoms in each alkyl group in an amount such that the Al/Ti ratio is between about 50:1 and about 500:1; (c) an alkoxy silane component of the formula RnSi(OR')4-n where n = 1-3, R = aryl or alkyl and R' = C1-3 alkyl in a sufficient quantity such that the molar ratio of organoaluminum co-catalyst to alkoxy silane is in the range from about20:1 to about 45:1. Said copolymer being characterized by a propylene content of 25 to 50 wt %, a 1-butene content of 50 to 75 wt % and a tensile strength of at least 300 psig.

53. 发明公开

EP1088005A1 CATALYST AND PROCESS FOR ITS PREPARATION 有权
标题翻译：催化剂及其制造方法
公开(公告)号：EP1088005A1
公开(公告)日：2001-04-04
申请号：EP99920744.2
申请日：1999-04-22
申请人： FINA RESEARCH S.A.
发明人： VEREECKE, Dominique
IPC分类号： C08F4/658 , C08F10/00
CPC分类号： C08F10/02 , C08F4/6555
摘要： A process for preparing a Ziegler-Natta catalyst, which process comprises: (i) mixing in a hydrocarbon solvent a dialkyl magnesium compound of general formula MgR1R2 with a chlorinating agent soluble in the hydrocarbon solvent under conditions to precipitate controlledly a magnesium dichloride derivative, wherein R?1 and R2¿ are each independently a C¿1? to C10 alkyl group, and the chlorinating agent is obtainable from the reaction between an alcohol of general formula R?3¿OH and an alkyl aluminium chloride of general formula R4nAlCl3-n, in which R3OH is a cyclic or branched C¿3? to C20 alcohol, each R?4¿ is independently a C¿2? to C8 alkyl and n is 1 or 2; (ii) removing unwanted reducing species by washing or reaction; and (iii) titanating the magnesium dichloride derivative with a chlorinated titanium compound to produce the Ziegler-Natta catalyst.

54. 发明公开

EP1084162A1 HIGH DENSITY POLYETHYLENE COMPOSITIONS, A PROCESS FOR THE PRODUCTION THEREOF AND FILMS PREPARED THEREOF 有权
标题翻译：聚乙烯组合物密度高，方法为生产薄膜由其MADE
公开(公告)号：EP1084162A1
公开(公告)日：2001-03-21
申请号：EP99913351.5
申请日：1999-04-06
申请人： Borealis Technology Oy
发明人： NUMMILA-PAKARINEN, Auli , MYHRE, Ole, Jan , LINDROOS, Jarmo , JOHANSSON, Solveig
IPC分类号： C08F10/02
CPC分类号： C08F10/00 , C08L23/04 , C08L23/06 , C08L2205/02 , C08L2314/02 , Y10T428/13 , Y10T428/1334 , Y10T428/1345 , Y10T428/1352 , Y10T428/1397 , C08F4/6555 , C08L2666/04
摘要： The present invention concerns a bimodal film-making HDPE composition, a process for the preparation thereof, a film prepared thereof and a film-making process. The composition comprises at least one polyethylene component having a relatively low molecular weight and another polyethylene component having a relatively high molecular weight. The composition has a shear thinning index defined by the relationship: SHI5/300≤0.00014 θ5kPa + 78 wherein θ5kPa is the complex viscosity at G*=5Pa and SHI5/300 is the ratio of complex viscosity at G*=5kPa to the complex viscosity at G*=300kPa. By means of the invention it is possible to produce material for making HDPE blown films with good mechanical properties in a process where the whole range of PE products from LLD to HD can be produced.

55. 发明授权

EP0778289B1 Bimodal ethylene polymers produced in tandem reactors 无效
标题翻译：一种用于在串联的反应器制备双峰聚乙烯的过程
公开(公告)号：EP0778289B1
公开(公告)日：2000-04-12
申请号：EP96113388.1
申请日：1992-02-24
申请人： MOBIL OIL CORPORATION
发明人： Ali, Ahmed Hussein , Hagerty, Robert Olds , Ong, Shihmay Christine
IPC分类号： C08F2/34 , C08F10/02 , C08F4/64 , C08F297/08 , C08L23/06
CPC分类号： C08F10/02 , B01J8/26 , B01J2219/0004 , C08F210/16 , C08F297/083 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08F2/001 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/26 , C08F2500/01 , C08F2500/18 , C08F2500/02 , C08F4/6555 , C08F4/6546 , C08F4/6583

56. 发明公开

EP0949274A2 Polymeric product produced with a catalyst comprising an ion pair 审中-公开
标题翻译： Mit eeem Ionenpaar enthaltenden Katalysator hergestelltes Polymerprodukt
公开(公告)号：EP0949274A2
公开(公告)日：1999-10-13
申请号：EP99660058.1
申请日：1999-04-01
申请人： BOREALIS POLYMERS OY
发明人： Lindroos, Jarmo , Johansson, Solveig , Waldvogel, Päivi
IPC分类号： C08F4/658 , C08F10/02 , C08L23/04 , C08K3/04
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08L23/04 , C08L2205/02 , C08L2314/02 , C08F4/025 , C08F4/6555 , C08L2666/04 , C08F2500/12 , C08F2500/17
摘要： A catalyst having high activity independent of the hydrogen concentration and low gel productivity in the polymerization of ethylene has been prepared. The preparation comprises the steps of reacting:

a support comprising a magnesium halide compound having the formula (1):

RO 2-n MgX n (1)

wherein R is a C 1 -C 20 alkyl, a C 7 -C 26 aralkyl, a C 1 -C 20 alkoxy or a C 7 -C 26 aralkoxy, each same or different X is a halogen, and n is an integer 1 or 2,
an alkyl metal halide compound having the formula (2):

R 1 n 1 M m 1 X 1 (3m 1 -n 1 ) (2)

wherein M is B or Al, each same or different R 1 is a C 1 -C 10 alkyl, each same or different X 1 is a halogen, m 1 is 1 or 2, n 1 is 1 or 2 when m 1 is 1 and n 1 is an integer from 1 to 5 when m 1 is 2,
a magnesium composition containing magnesium bonded to a hydrocarbyl and magnesium bonded to a hydrocarbyl oxide, said magnesium composition having the empirical formula (3):

R 2 n 2 (R 3 O) 2-n 2 Mg (3)

wherein each same or different R 2 is a C 1 -C 20 alkyl, each same or different R 3 is a C 1 -C 20 alkyl, n 2 is between 0.01 and 1.99, and
a titanium halide compound having the formula (4):

(R 4 O) n 3 TiX 2 4-n 3 (4)

wherein each same or different R 4 is a C 1 -C 20 alkyl, each same or different X 2 is a halogen, n 3 is 0 or an integer 1-3, and Ti is quadrivalent titanium.
摘要翻译：已经制备了具有独立于乙烯聚合中的氢浓度和低凝胶生产率的高活性的催化剂。该制备方法包括以下步骤：使包含具有式（1）的卤化镁化合物的载体反应：ƒ€ƒ€ƒ€ƒ€ƒ€ƒƒƒƒƒƒƒƒ€ƒ€ƒ €（1）其中R是C 1 -C 20烷基，C 7 -C 26芳烷基，C 1 -C 20烷氧基或C 7 -C 26芳烷氧基，各自相同或不同，X是卤素，n为整数1或2，具有式（2）的烷基金属卤化物化合物：ƒ€ƒ€ƒ€ƒ€ƒ€ƒR 1€Šn 1 M m 1 X 1€ Š（3m 1 -n 1）€ƒ€ƒ€ƒ€ƒ（2）其中M为B或Al，各自相同或不同，R 1为C 1 -C 10烷基，各自相同或不同X 1为卤素，m 1为1或2，当m 1为1时，n 1为1或2，当m 1为2时，n 1为1至5的整数，镁与镁基结合的烃基和镁所述镁组合物具有经验式（3）：ƒ€ƒ€ƒ€ƒ€ƒ€ƒR 2€Šn 2（R 3 O）2-n 2 Mg€ ƒ ƒ€ƒ€ƒ（3）其中每个相同或不同的R 2是C 1 -C 20烷基，各自相同或不同，R 3为C 1 -C 20烷基，n 2为0.01至1.99，以及具有式（4）的卤化钛化合物：ƒ€ƒ€ƒ€ƒ€ƒ€ƒ（R 4 O）n 3 TiX 2€Š4-n 3€ƒ€ƒ€ƒ€ （4）其中每个相同或不同的R 4是C 1 -C 20烷基，各自相同或不同，X 2为卤素，n 3为0或整数1-3，Ti为四价钛。

57. 发明授权

EP0775163B1 SUPPORTED OLEFIN POLYMERIZATION CATALYST 失效
标题翻译：催化剂载体的烯烃
公开(公告)号：EP0775163B1
公开(公告)日：1998-06-10
申请号：EP95928154.4
申请日：1995-07-28
申请人： THE DOW CHEMICAL COMPANY
发明人： SPENCER, Lee , SPRINGS, Marc, A.
IPC分类号： C08F10/00 , C08F4/02
CPC分类号： C08F10/00 , C08F110/02 , C08F4/025 , C08F4/6555 , C08F2500/18 , C08F2500/12 , C08F2500/24

58. 发明授权

EP0574153B1 Process for preparing ultra-high molecular weight polyethylene 失效
标题翻译：一种制备超高分子量聚乙烯的方法
公开(公告)号：EP0574153B1
公开(公告)日：1997-07-30
申请号：EP93303974.5
申请日：1993-05-21
申请人： NIPPON OIL Co. Ltd.
发明人： Shiraishi, Takeichi , Okamoto, Mitsuo , Matsuura, Kazuo
IPC分类号： C08F10/02 , C08F4/655
CPC分类号： C08F110/02 , C08F4/6555 , C08F2500/01 , C08F2500/18 , C08F2500/24

59. 发明公开

EP0778289A1 Process for producing bimodal ethylene polymers in tandem reactors 无效
标题翻译： Verfahren zur Herstellung von bimodalen聚乙烯在Serien-Reaktoren
公开(公告)号：EP0778289A1
公开(公告)日：1997-06-11
申请号：EP96113388.1
申请日：1992-02-24
申请人： MOBIL OIL CORPORATION
发明人： Ali, Ahmed Hussein , Hagerty, Robert Olds , Ong, Shihmay Christine
IPC分类号： C08F2/34 , C08F10/02 , C08F4/64 , C08F297/08 , C08L23/06
CPC分类号： C08F10/02 , B01J8/26 , B01J2219/0004 , C08F210/16 , C08F297/083 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08F2/001 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/26 , C08F2500/01 , C08F2500/18 , C08F2500/02 , C08F4/6555 , C08F4/6546 , C08F4/6583
摘要： A process is provided for producing a bimodal ethylene polymer blend comprising contacting in a first gas phase, fluidized bed reaction zone under polymerization conditions, a gaseous monomeric composition comprising a major proportion of ethylene and, optionally, hydrogen, with a Ziegler-Natta catalyst, the hydrogen/ethylene molar ratio (H 2 /C 2 ratio) being no higher than about 0.3 and the ethylene partial pressure being no higher than about 100 psia, to produce a relatively high molecular weight (HMW) polymer associated with catalyst particles, transferring the HMW polymer associated with catalyst particles to a second gas phase, fluidized bed reaction zone into which is also fed hydrogen and a gaseous monomeric composition comprising a major proportion of ethylene, under polymerization conditions including an H 2 /C 2 ratio of at least about 0.9 and at least about 8.0 times that in the first reaction zone, and an ethylene partial pressure of at least 1.7 times that in said first reaction zone, to produce a low molecular weight (LMW) polymer deposited on and within the voids of the HMW polymer/catalyst particles, the resulting bimodal polymer blend obtained from the second reaction zone having a fraction of HMW polymer of at least about 0.35.
摘要翻译：提供了一种用于生产双峰乙烯聚合物共混物的方法，其包括在第一气相，聚合条件下的流化床反应区，包含主要乙烯和任选的氢的齐格勒 - 纳塔催化剂的气态单体组合物，氢/乙烯摩尔比（H2 / C2比）不高于约0.3，乙烯分压不高于约100psia，以产生与催化剂颗粒相关的相对高分子量（HMW）聚合物，转移HMW 与催化剂颗粒相关的聚合物与第二气相相关的流化床反应区，在其中还供入氢的气态单体组合物和包含主要比例的乙烯的气态单体组合物在包括至少约0.9的H 2 / C 2比和至少约0.9的聚合条件下约为第一反应区的8.0倍，乙烯分压至少为所述第一反应区的1.7倍 n区，以产生沉积在HMW聚合物/催化剂颗粒的空隙上和之内的低分子量（LMW）聚合物，所得双峰聚合物共混物由第二反应区获得，HMW聚合物的分数为至少约0.35。

60. 发明授权

EP0515645B1 PROCEDE DE PREPARATION D'UN CATALYSEUR POUR LA POLYMERISATION DES OLEFINES 失效
标题翻译：制造用于烯烃催化剂
公开(公告)号：EP0515645B1
公开(公告)日：1997-05-21
申请号：EP92901730.9
申请日：1991-12-16
申请人： POLIMERI EUROPA S.r.l.
发明人： BUJADOUX, Karel , LEPREVOST, Benoît , MORTREUX, André , PETIT, Francis
IPC分类号： C08F10/02 , C08F4/655
CPC分类号： C08F10/00 , C08F4/6555 , C08F4/651
摘要： A method for preparing an olefin homopolymerization and copolymerization catalyst by at least partially reducing at least one tetravalent titanium compound, wherein: firstly, at least one α,φ-dihalogenoalkane of general formula X-(CH2)n-X1, wherein X and X1, which are the same or different, are halogen atoms and n is equal to or greater than 2, are contacted with a tetravalent titanium compound and aluminium until said aluminium completely disappears; and secondly, an organomagnesium derivative is added to the solution thereby obtained in an amount sufficient for the molar ratio of Mg/Ti to be of at least 1. The catalyst thereby obtained may be used together with an activator in an olefin polymerization method, and particularly in an ethylene (co)polymerization method.

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