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    • 54. 发明公开
    • PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    • 用于控制无节幼虫的吡唑类化合物
    • EP2346335A2
    • 2011-07-27
    • EP09783323.0
    • 2009-09-23
    • BASF SE
    • GROß, SteffenKÖRBER, KarstenVON DEYN, WolfgangKAISER, FlorianLE VEZOUET, RonanSÖRGEL, SebastianPOHLMAN, MatthiasDESHMUKH, PrashantDICKHAUT, JoachimANSPAUGH, Douglas D.CULBERTSON, Deborah L.OLOUMI-SADEGHI, Hassan
    • A01N43/90A01P5/00A01P7/02A01P7/04
    • A01N43/90C07D471/04C07D487/04C07D498/04
    • The present invention relates to a method for controlling invertebrate pests which method comprises treating the pests, their food supply, their habitat or their breeding ground or a plant, seed, soil, area, material or environment in which the pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from pest attack or infestation with a pesticidally effective amount of a pyrazole compound of formulae I or II or a salt or an N-oxide thereof, wherein A is a pyrazole radical of the formulae A1 or A2, wherein # denotes the binding; D is a 5- or 6-membered heterocyclic radical fused to the pyrazole moiety; Rp1, Rp2 and Rpx are H, halogen, CN, NO2, C1-C10-alkyl, C2-C10-alkenyl, C2-C10-alkynyl, etc.; n is 0 to 4; or two radicals Rpx bound to the same ring-member may form an oxo substituent, or two radicals Rpx bound to adjacent ring-members may form a 3- to 7-membered fused cyclic radical; B is N or CR4, wherein R4 is H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; X1 is S, O or NR1a, wherein R1a is H, C1-C10-alkyl, etc.; X2 is O2a, NR2bR2c or S(O)mR2d, wherein m is 0, 1 or 2; R2a is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2b, R2c are H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R1 is H, CN, C1-C10-alkyl, C1-C10-haloalkyl, C3-C10-cycloalkyl, etc.; R2, R3 and R5 are H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc., to a method for protecting plant propagation material and/or the plants which grow threfrom, to plant propagation material comprising at least one compound of formulae I or II, to a method for treating or protecting an animal from infestation or infection by parasites, to novel pyrazole compounds of formulae I or II and agricultural composition containing those compounds.
    • 本发明涉及一种防治无脊椎害虫的方法,所述方法包括处理害虫,其食物供应,其栖息地或其繁殖地或害虫正在生长或可能生长的植物,种子,土壤,区域,材料或环境 ,或用杀虫有效量的式I或II的吡唑化合物或其盐或其N-氧化物防护害虫或侵染的材料,植物,种子,土壤,表面或空间,其中A是 式A1或A2的吡唑基,其中#表示结合; D是与吡唑部分稠合的5-或6-元杂环基团; R p1,R p2和R px为H,卤素,CN,NO 2,C 1 -C 10烷基,C 2 -C 10烯基,C 2 -C 10炔基等。 n是0至4; 或者与相同环成员键合的两个基团R px可以形成氧代取代基,或者与相邻环成员键合的两个基团R px可以形成3-至7-员稠合的环状基团; B为N或CR 4,其中R 4为H,卤素,CN,NO 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4烷氧基等。 X 1为S,O或NR 1a,其中R 1a为H,C 1 -C 10烷基等; X 2是O 2a,NR 2b R 2c或S(O)mR 2d,其中m是0,1或2; R 2a为C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6环烷基等; R 2b,R 2c为H,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6环烷基等; R 2d为C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6环烷基等; R 1是H,CN,C 1 -C 10烷基,C 1 -C 10卤代烷基,C 3 -C 10环烷基等; R 2,R 3和R 5为H,卤素,CN,NO 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4烷氧基等。 涉及保护植物繁殖材料和/或其生长的植物的方法,包含至少一种式I或II化合物的植物繁殖材料,治疗或保护动物免受寄生虫侵染或感染的方法,新颖的 式I或II的吡唑化合物和含有这些化合物的农业组合物。
    • 56. 发明公开
    • PESTICIDAL MIXTURES
    • 混配农药
    • EP2009989A2
    • 2009-01-07
    • EP07728253.1
    • 2007-04-18
    • BASF SE
    • LANGEWALD, JürgenVAN TUYL COTTER, HenryCULBERTSON, Deborah L.OLOUMI-SADEGHI, Hassan
    • A01N37/34A01N57/14A01N57/12A01N53/00A01N51/00A01N47/40A01N47/38A01N47/34A01N47/30A01N47/22A01N47/06A01N47/02A01N43/90A01N43/88A01N43/56
    • A01N37/34A01N47/02A01N43/22A01N43/88A01N51/00A01N63/00A01N47/30A01N2300/00
    • Pesticidal mixtures comprising, as active components, 1) a malonodinitrile compound selected from compounds I-1 to I-8 CF2HCF2CF2CF2CH2C(CN)2CH2CH2CF3 (compound I-1; name: 2-(2,2,3,3,4,4,5,5- octafluoro-pentyl)-2-(3,3,3-trifluoro-propyl)-malononitrile); CF3(CH2)2C(CN)2CH2(CF2)5CF2H (compound I-2; name: 2-(2,2,3,3,4,4,5,5,6,6,7,7- dodecafluoro-heptyl)-2-(3,3,3-trifluoro-propyl)-malononitrile); CF3(CH2)2C(CN)2(CH2)2C(CF3)2F (compound I-3; name: 2-(3,4,4,4-tetrafluoro-3- trifluoromethyl-butyl)-2-(3,3,3-trifluoro-propyl)-malononitrile); CF3(CH2)2C(CN)2(CH2)2(CF2)3CF3 (compound I-4; name: 2-(3,3,4,4,5,5,6,6,6- nonafluoro-hexyl)-2-(3,3,3-trifluoro-propyl)-malononitrile); CF2H(CF2)3CH2C(CN)2CH2(CF2)3CF2H (compound I-5; name: 2,2-bis-(2,2,3,3,4,4,5,5- octafluoro-pentyl)-malononitrile); CF3(CH2)2C(CN)2CH2(CF2)3CF3 (compound I-6; name: 2-(2,2,3,3,4,4,5,5,5-nonafluoro- pentyl)-2-(3,3,3-trifluoro-propyl)-malononitrile); CF3(CF2)2CH2C(CN)2CH2(CF2)3CF2H (compound I-7; name: 2-(2,2,3,3,4,4,4- heptafluoro-butyl)-2-(2,2,3,3,4,4,5,5-octafluoro-pentyl)-malononitrile); or CF3CF2CH2C(CN)2CH2(CF2)3CF2H (compound I-8; name: 2-(2,2,3,3,4,4,5,5-octafluoro- pentyl)-2-(2,2,3,3,3-pentafluoro-propyl)-malononitrile); and 2) one or more compounds II selected from group A consisting of organo(thio)- phosphates, carbamates, pyrethroids, growth regulators, nicotinic receptor agonists/antagonists compounds, GABA antagonist compounds, macrocyclic lactone insecticides, METI I acaricides, METI II and III compounds, uncoupler compounds, oxida- tive phosphorylation inhibitor compounds, mixed function oxidase inhibitor compounds, sodium channel blocker compounds and others, all as defined in the description, in synergistically effective amounts, use of these mixture for combating insects, arachnids or nematodes in and on plants and for the protection of seeds, and for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by parasites.
    • 57. 发明公开
    • MALONONITRILE COMPOUNDS
    • 金属氰化物化合物
    • EP1973404A1
    • 2008-10-01
    • EP06830609.1
    • 2006-12-13
    • BASF SE
    • POHLMAN, MatthiasHOFMANN, MichaelBASTIAANS, Henricus Maria MartinusRACK, MichaelCULBERTSON, Deborah L.OLOUMI-SADEGHI, HassanHOKAMA, TakeoPALMER, ChristopherLANGEWALD, Jürgen
    • A01N37/34A01N43/40A01N43/52A01N47/02C07C255/37C07C317/10C07C321/20C07D213/67C07D271/06C07D277/32C07D317/32C07D333/28
    • C07C323/60A01N37/34A01N43/10A01N43/28A01N43/78A01N43/80A01N43/82C07C255/20C07C255/37C07C317/44C07C317/46C07C323/62C07D213/61C07D235/16C07D261/08C07D271/06C07D277/32C07D333/28
    • Compounds of formula I wherein X is O or S(=O)n; n is 0,1 or 2; R1 is optionally substituted alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, cycloalkyl, halocycloalkyl, cycloalkenyl, halocycloalkenyl, phenyl, hetaryl, phenylalkyl, hetaryl alkyl, optionally fused to phenyl, hetaryl or heterocyclyl; A is -NRb2, -C(=G)GRb, -C(=G)NRb2, -C(=NORb)Rb, C(=G)[N=SRb2], -C(=G)NRb-NRb2, C2-C6-alkandiyl, C2-C6-alkenediyl, C1-C3-alkyl-G-C1-C3-alkyl, wherein Rb is as defined in the description, or optionally substituted phenyl, hetaryl, heterocyclyl, optionally fused to phenyl or heterocyclyl; B is an optionally substituted saturated or partially unsaturated hydrocarbon chain with 1 to 3 carbon chain atoms; D is an optionally substituted saturated or partially unsaturated hydrocarbon chain with 1 to 5 carbon chain atoms or C3-C6-cycloalkyl; G is oxygen or sulfur; or the enantiomers or diastereomers or salts or N-oxides thereof, processes for preparing the compounds I, pesticidal compositions and synergistic mixtures comprising compounds I, methods for the control of insects, acarids or nematodes by contacting the pests or their food supply, habitat or breeding grounds with a pesticidally effective amount of compounds formula I, and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites which comprises orally, topically or parenterally administering or applying to the animals a parasiticidally effective amount of compounds of formula I.
    • 其中X是O或S(= O)n的式I化合物; n是0,1或2; R 1是任选地与苯基,杂芳基或杂环基稠合的任选取代的烷基,卤代烷基,烯基,卤代烯基,炔基,卤代炔基,环烷基,卤代环烷基,环烯基,卤代环烯基,苯基,杂芳基,苯基烷基, A是-NRb2,-C(= G)GRb,-C(= G)NRb2,-C(= NORb)Rb,C(= G)[N = SRb2],-C(= G)NRb- C2-C6-亚烷基,C2-C6-链烯二基,C1-C3-烷基-G-C1-C3-烷基,其中Rb如说明书中所定义,或任选取代的苯基,杂芳基,杂环基,任选稠合至苯基或杂环基 ; B是具有1至3个碳原子的任选取代的饱和或部分不饱和烃链; D是具有1至5个碳原子的任选取代的饱和或部分不饱和烃链或C 3 -C 6 - 环烷基; G是氧或硫; 或其对映异构体或非对映异构体或其盐或N-氧化物,制备化合物I的方法,包含化合物I的杀虫组合物和协同混合物,通过接触害虫或其食物供应源,栖息地或 用杀虫有效量的式I化合物繁殖的场所,以及用于治疗,防治,预防或保护动物免受寄生虫侵染或感染的方法,其包括口服,局部或非肠道给药或施用杀寄生物有效量的 公式I.