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41. 发明公开

EP1201650A3 Composés ioniques dérivés du malonitrile, et leurs utilisations 失效
标题翻译： IonischeMalonsäuredinitrilDerivate und deren Verwendung
公开(公告)号：EP1201650A3
公开(公告)日：2004-01-02
申请号：EP01129670.4
申请日：1997-12-30
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) , Hydro-Quebec
发明人： Armand, Michel , Gauthier, Michel , Choquette, Yves , Michot, Christophe
IPC分类号： C07C317/44 , C07C255/17 , C07C255/65 , C07C255/27 , C07C255/05 , C07C255/35 , C08F220/44 , C07C255/31 , C08G65/48 , C08G73/06 , C08G77/44 , C08G73/02 , C07F17/02 , C07F7/18 , C07C311/02 , C09K3/00 , H01M6/16 , H01M10/40 , C07B41/00 , C08F4/00 , C08J3/24
CPC分类号： B01J31/0224 , B01J31/0215 , B01J31/0222 , B01J31/0225 , B01J31/0227 , B01J31/0235 , B01J31/0239 , B01J31/0247 , B01J31/0251 , B01J31/0252 , B01J31/0267 , B01J31/0271 , B01J31/0281 , B01J31/0288 , B01J31/0289 , B01J31/04 , B01J31/06 , B01J31/068 , B01J31/124 , B01J31/1815 , B01J31/2208 , B01J2231/122 , B01J2231/14 , B01J2231/326 , B01J2231/341 , B01J2231/348 , B01J2231/4205 , B01J2231/543 , B01J2531/35 , B01J2531/824 , C07B37/02 , C07B37/12 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/10 , C07C255/17 , C07C255/27 , C07C255/46 , C07C255/65 , C07C257/14 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07C2601/10 , C07C2602/42 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/90 , C07D239/60 , C07D241/42 , C07D249/04 , C07D249/10 , C07D249/12 , C07D251/70 , C07D277/64 , C07D277/82 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/24 , C07D405/06 , C07D409/12 , C07D417/10 , C07D417/14 , C07F17/02 , C08F4/04 , C08G65/3344 , C09B69/00 , C09B69/02 , C09B69/10 , G02F1/1525 , G02F2001/151 , H01B1/122 , H01B1/128 , H01G9/022 , H01G9/038 , H01G11/02 , H01G11/62 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/382 , H01M4/405 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M4/60 , H01M4/625 , H01M4/661 , H01M6/00 , H01M6/04 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M6/183 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , Y02E60/13 , Y10S430/127 , Y10T29/49108 , Y10T428/2918 , C07C49/84 , C07C49/553
摘要： L'invention a pour objet des composés ioniques dérivés du malononitrile dans lesquels la charge anionique est délocalisée. Un composé ionique de l'invention comprend une partie anionique associée à au moins une partie cationique M m+ en nombre suffisant pour assurer la neutralité électronique de l'ensemble I1 est caractérisé en ce que M est un hydroxonium, un nitrosonium NO + , un ammonium -NH 4 + , un cation métallique ayant la valence m, un cation organique ayant la valence m ou un cation organométallique ayant la valence m, et que la partie anionique répond à l'une des formules R D -Y-C(C≡N) 2 - ou Z-C(C≡N) 2 - dans lesquelles Z est un groupe électroattracteur, R D est un radical organique et Y est un carbonyle, un thiocarbonyle, un sulfonyle, un sulfinyle ou un phosphonyle. Les composés sont utiles notamment pour les matériaux à conduction ionique, les matériaux à conduction électronique, les colorants et la catalyse de diverses réactions chimiques.
摘要翻译：电池具有包含溶剂的电解质和包含氢氧化物，亚硝鎓，铵，金属，有机或有机金属阳离子和5元（杂）环阴离子的盐（I）。电池具有包含溶剂的电解质和包含氢氧化物，亚硝鎓，铵，金属，有机或有机金属阳离子的盐（I）和具有下式的5元（杂）环阴离子：[图像] X1-X5-N =（ - ） - ， - （ - ） - （ - ） - （ - ） - （ - ） - =，条件是不超过四个包括N，不超过两个包括S（不相邻），不超过一个包含P; Q'，Q：1-8C全卤代烷基，全卤代烯基或任选取代的6-12C芳基或芳烷基，各自任选含有O，S或N杂原子; 任选被卤素和/或醚取代的烷基，烯基，芳基，芳烷基，烷基芳基，烯基芳基，脂环族或杂环基，硫醚，胺，亚胺，酰胺，羧基，羰基，异氰酸酯，异硫氰酸酯和羟基; 具有含有杂原子的环和/或取代基的芳族基团; 聚合物组; 或具有一个或多个阳离子和/或阴离子离子基团的基团; Y：H，F，Cl，Br，CN，SCN，NCS，NCO，NO2，全氟烷基，全氟烷氧基，全氟烷基甲基，四氟乙氧基，SCF3，全氟烷硫基，四氟乙硫基，三氟乙氧基，三氟乙硫基，SO2F，SO2Q，COOQ，QN-SO2- ）或COQ; CN，CO 2，SCN，N 3，三氟乙烯基氧基，（1-12C全氟烷基）甲基，氟代烷氧基，氟烷基硫代，烷基，烯基，氧杂烷基，氧杂链烯基，氮杂烷基，氮杂链烯基，硫杂烷基，硫杂链烯基，聚合基团和具有一个或多个阳离子和/或阴离子离子基团的基团; 或者，Y，Q，Q'和Q中的两个可以形成4-至8-元环，或者Y和Q中的一个是连接到第二个5元（杂）环阴离子上的多价基团，或Y中的一个 Q是聚合物的重复单元; 条件是至少一个Y或Q包含离解偶极子。

42. 发明公开

EP1205499A3 Unsaturated nitrile-conjugated diene rubber composition and production process of the rubber 有权
标题翻译：包括不饱和腈 - 共轭二烯橡胶组合物，用于制备所述橡胶
公开(公告)号：EP1205499A3
公开(公告)日：2003-02-12
申请号：EP01126878.6
申请日：2001-11-12
申请人： JSR Corporation
发明人： Sakata, Katsuhiko , Ishikawa, Osamu
IPC分类号： C08F220/44 , C08F236/04 , C08F293/00 , C08F265/08 , C08L55/02 , C08L33/20 , C08K3/00
CPC分类号： C08L51/04 , C08F220/44 , C08F265/08 , C08F279/04 , C08L55/02 , C08L2666/02 , C08L2666/24
摘要： An objective of the present invention is to provide an unsaturated nitrile-conjugated diene-typed rubber capable of giving a vulcanized rubber which exhibits is well-balanced in terms of the mechanical strength, the oil resistance and the like, as well as a process for the production of the same, and a rubber composition which is containing such rubber and exhibits an excellent processability as well as a process for the production of the same. The unsaturated nitrile-conjugated diene-typed rubber in the invention is produced by polymerizing using certain amounts of an olefinically unsaturated nitrile monomer such as acrylonitrile and a conjugated diene monomer such as butadiene at first, and continuing by supplying a remainder of the monomers at a certain ratio continuously or stepwise to proceed the polymerization. The unsaturated nitrile-conjugated diene-typed rubber is constituted 55 to 80wt% of an olefinically unsaturated nitrile monomer unit as a repeating unit and 20 to 45wt% of a conjugated diene monomer unit as a repeating unit based on 100wt% of total of the monomer units. Glass transition temperature is -15 to 30°C and the extrapolated temperature of the termination of the glass transition is preferably 70°C or less.
摘要翻译：本发明的一个目的是提供一种能够赋予硫化橡胶表现出不饱和腈 - 共轭二烯类型的橡胶是在机械强度，耐油性等方面良好平衡的，以及用于处理生产相同的，与橡胶组合物的所有正谋求含橡胶和表现出优异的可加工性，以及为生产相同的处理。通过在供给一的单体的剩余部分，例如在第一丁二烯，继续：如丙烯腈和共轭单体：在本发明的不饱和腈 - 共轭二烯类型的橡胶是通过使用用于烯属不饱和腈单体的一定量的聚合而制造连续一定的比例或逐步地进行聚合。不饱和腈 - 共轭二烯类型的橡胶构成55作为重复单元的烯属不饱和腈单体单元的至80wt％和20基于总单体的100重量％至45重量的共轭二烯单体单元的％作为重复单元单位。玻璃化转变温度为-15〜30℃，优选为玻璃化转变终止的外推温度为70℃或更低。

43. 发明公开

EP1082352A4 POLYACRYLONITRILE PARTICLES BY SURFMER POLYMERIZATION AND SODIUM REMOVAL BY CHEMICAL EXCHANGE 审中-公开
标题翻译： POLYACRYLNITRILTEILCHEN打通化学交换“表面活性剂单体”聚合及次脱钠
公开(公告)号：EP1082352A4
公开(公告)日：2002-07-24
申请号：EP99915083
申请日：1999-03-29
申请人： SOLUTIA INC
发明人： WADE BRUCE E , CAPONE GARY J
IPC分类号： C08F4/06 , C08F4/34 , C08F8/44 , C08F212/14 , C08F220/44 , C08F228/02 , C08F12/30 , C08F22/02 , C08F22/04 , C08F30/04 , C08F220/46
CPC分类号： C08F220/44 , C08F8/44
摘要： The present invention is an acrylic polymer particle which is consistently and substantially spherical in shape and which has a mean diameter that can be predetermined from about 30 microns in diameter to about 5 microns or less. Polyacrylonitrile is synthesized in an aqueous dispersion polymerization with an ionic monomer or 'surfmer' to attain a narrow particle size distribution with a mean diameter as low as approximately 3±1.5 microns which is characteristic of an emulsion polymerization. The polymer comprises the ionic monomer and, optionally, a neutral comonomer. The mean particle size is dependent on the concentration of the ionic monomer present, the particular ionic monomer or monomers selected, and the counterion associated with the ionic monomers, the persulfate initiator, and the bisulfite activator. The counterions, often sodium ions, can be removed from the polymer particles by ion exchange with quarternary ammonium compounds.

44. 发明公开

EP1115750A4 AQUEOUS COMPOSITION 有权
标题翻译：水性组合物
公开(公告)号：EP1115750A4
公开(公告)日：2002-05-22
申请号：EP99935791
申请日：1999-07-20
申请人： ROHM & HAAS
发明人： SOLOMON ROBERT DAVID , GREENBLATT GARY DAVID , EDWARDS STEPHEN SCOTT , HAGEMAN BRADLEY KEITH , LARSON GARY ROBERT , LESKO PATRICIA MARIE , MAURICE ALVIN MICHAEL , PROCOPIO LEO JOSEPH , SCHAEFER MARGO RAATE , SPERRY PETER REEVES , WILLIAMS STEWART ORLYN
IPC分类号： C08F290/04 , C08F2/00 , C08F2/26 , C08F212/06 , C08F214/06 , C08F218/02 , C08F220/04 , C08F220/12 , C08F220/44 , C08F220/56 , C08F265/02 , C08F265/04 , C08F265/06 , C08F290/06 , C08J3/02 , C08L23/00 , C08L25/04 , C08L27/02 , C08L31/02 , C08L33/08 , C08L33/20 , C08L33/26 , C08L101/02 , C09D5/02 , C09D101/00 , C09D123/08 , C09D123/14 , C09D125/00 , C09D127/04 , C09D129/00 , C09D131/00 , C09D133/00 , C09D135/00 , C09D139/06 , C09D143/02 , C09D151/00 , C09D157/00 , C09D163/00 , C08F220/06 , C08F246/00
CPC分类号： C08F290/046 , C01P2004/62 , C08F220/04 , C08F265/02 , C08F265/04 , C08F265/06
摘要： Aqueous dispersions of copolymers formed by the polymerisation of a monomer mixture comprising 0.05 % to less than 4.5 % by weight of certain terminally unsaturated oligomers are useful for improving the scrub resistance, corrosion resistance, opacifying capacity and/or efflorescence resistance of a coating.

45. 发明公开

EP1157049A1 MODACRYLIC COPOLYMER COMPOSITION 审中-公开
标题翻译：变性聚丙烯腈共聚物
公开(公告)号：EP1157049A1
公开(公告)日：2001-11-28
申请号：EP00910051.2
申请日：2000-02-02
申请人： Solutia Inc.
发明人： WADE, Bruce, E.
IPC分类号： C08F220/44 , C08F220/46
CPC分类号： C08F214/10 , C08F220/44 , C08F220/46
摘要： The present invention relates to a modacrylic copolymer composition comprising acrylonitrile, vinylidene chloride, vinyl acetate, and at least one ionic comonomer. In one embodiment, the modacrylic copolymer composition comprises from about 45 to about 60% acrylonitrile, from about 35 to about 50% vinylidene chloride, from about 0.5 to about 5% vinyl acetate, and up to about 2% of a salt of p-sulfophenyl methallyl ether by weight of the total composition. The copolymer composition of the present invention provides acceptable color while having acceptable flame resistance.

46. 发明公开

EP0831932A4 NOVEL TARGETED COMPOSITIONS FOR DIAGNOSTIC AND THERAPEUTIC USE 失效
标题翻译：新的靶向药物用于诊断和治疗用途
公开(公告)号：EP0831932A4
公开(公告)日：2000-01-12
申请号：EP96921486
申请日：1996-06-06
申请人： IMARX PHARMACEUTICAL CORP
发明人： UNGER EVAN C , SHEN DEKANG , WU GUANLI
IPC分类号： A61K47/48 , A61K45/00 , A61K49/00 , A61K49/22 , C08F220/44 , C08G65/32 , A61B5/055 , A61K49/04
CPC分类号： B82Y5/00 , A61K49/0002 , A61K49/223 , A61K49/227 , A61K49/228

47. 发明公开

EP0891996A1 Process for the preparation of acrylonitrile copolymers with at least one (di)olefin 失效
标题翻译： Verfahren zur Herstellung von Acrylonitril Copolymeren mit mindestens einem（di）Olefin
公开(公告)号：EP0891996A1
公开(公告)日：1999-01-20
申请号：EP98111211.3
申请日：1998-06-18
申请人： Enichem S.p.A.
发明人： Po, Riccardo , Fiocca, Luisa
IPC分类号： C08F220/44 , C08F210/00 , C08F236/04
CPC分类号： C08F210/00 , C08F4/65912 , C08F110/06 , C08F220/44 , C08F236/04 , Y10S526/943 , C08F4/6592 , C08F4/642
摘要： Process for the preparation of acrylonitrile copolymers with at least one (di)olefin which comprises reacting the monomers in the presence of a catalytic system essentially consisting of:

i) a complex of zirconium having the general formula:

ZrA a B b (I)

wherein A represents a cyclopentadienyl, indenyl or fluorenyl group, B represents a hydrogen atom, a halogen or a C 1 -C 8 (iso)alkyl, alkoxyl or carboxyl radical;
ii) an aluminumalkyl halide having the general formula:

AlR n X m (II)

wherein R represents a C 1 -C 4 (iso)alkyl group, X is a halogen.
摘要翻译：用于制备具有至少一种（二）烯烃的丙烯腈共聚物的方法，其包括在催化体系存在下使单体反应，所述催化体系基本上由以下组成：i）具有以下通式的锆的络合物：ZrAaBb其中A表示环戊二烯基，茚基或芴基，B表示氢原子，卤素或C1-C8（iso）烷基，烷氧基或羧基; ii）具有以下通式的铝烷基卤化物：AlRnXm其中R表示C1-C4（iso）烷基，X是卤素。

48. 发明公开

EP0768300A1 Acrylonitrile solutions of maleimides, method for preparation thereof, and acrylonitrile based copolymers obtained by use of the solutions 失效
标题翻译：马来酰亚胺的丙烯腈溶液，其制备方法，并通过使用溶液的获得基于丙烯腈共聚物
公开(公告)号：EP0768300A1
公开(公告)日：1997-04-16
申请号：EP96306260.9
申请日：1996-08-29
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Kishino, Kazuo , Nakayama, Kinichi , Shimoyama, Fumioki , Kita, Yuichi
IPC分类号： C07D207/448 , C07C255/08 , C08F220/44
CPC分类号： C07D207/448 , C07C253/32 , C07C255/08
摘要： An acrylonitrile solution of maleimide manifesting transparency, precluding coloration and opacification during the course of handling, and excelling in stability, a method for the preparation of the acrylonitrile solution, and an acrylonitrile based copolymer obtained by using the acrylonitrile solution are provided.
The acrylonitrile solution of maleimide is such that, when it is subjected to a forced coloration test, the differences Δ L, Δa, and Δb values (invariably as absolute values) each between L, a, and b values before and after the test are respectively not more than 5, not more than 5, and not more than 10. The acrylonitrile solution of maleimide is prepared by lowering the water content in the acrylonitrile solution to a level of not more than 0.1% by weight, or causing the acrylonitrile solution to permit coexistence therein of at least one member selected from the group consisting of alkyl-substituted hydroxybenzenes and hindered phenols and at least one member selected from the group consisting of phosphorous esters, phosphoric esters, phosphine, and phosphoric acid amides, or lowering the water content in the acrylonitrile solution to a level of not more than 0.3% by weight and causing the acrylonitrile solution to permit coexistence therein of at least one member selected from the group consisting of alkyl-substituted hydroxybenzenes, hindered phenols, phosphorous esters, phosphoric esters, phosphine, and phosphoric acid amides.
摘要翻译：提供通过使用丙烯腈溶液得到马来酰亚胺表现透明度，处理过程中排除着色和混浊，并且在稳定性的丙烯腈溶液的制备优异，一种方法，以及基于丙烯腈的共聚物的丙烯腈溶液。马来酰亚胺的丙烯腈溶液正在寻求的是，当它经受强制着色测试，差异DELTA L，DELTA一个，和DELTA B值（不变地作为绝对值）每个L之间，a和b值之前和之后的测试分别不超过5，不超过五个，并且不大于10的马来酰亚胺的丙烯腈溶液是通过按重量计在丙烯腈溶液中的水含量降低到不超过0.1％的水平，或使制备丙烯腈溶液以允许共存于其中选自烷基substituiertem羟基苯类选择的至少一种构件和受阻酚和选自亚磷酸酯，磷酸酯，膦的选择的至少一个部件，和磷酸酰胺，或降低在丙烯腈溶液中的水含量，以不大于0.3％的水平按重量计和使丙烯腈溶液，以允许共存于其中的至少一个成员选择素泰德选自烷基substituiertem羟基苯类，受阻酚，亚磷酸酯，磷酸酯，膦，和磷酸酰胺。

49. 发明公开

EP0565086A2 Method for producing a spherical acrylonitrile crosslinked copolymer 有权转让
标题翻译： Verfahren zur Herstellung vonkugelförmigenvernetzten Acrylnitril-Copolymerisaten。
公开(公告)号：EP0565086A2
公开(公告)日：1993-10-13
申请号：EP93105774.9
申请日：1993-04-07
申请人： Mitsubishi Chemical Corporation
发明人： Ito, Tsuyoshi , Watanabe, Junya , Sawada, Shintaro
IPC分类号： C08F220/44 , C08F8/12
CPC分类号： C08F220/44 , C08F8/12 , C08F2800/20 , C08F2810/20 , C08F220/14 , C08F236/20 , C08F212/36 , C08F212/14
摘要： A method for producing an acrylonitrile crosslinked copolymer, which comprises copolymerizing, as polymerizable monomers, acrylonitrile, an alkyl ester of acrylic acid or methacrylic acid, an aliphatic or alicyclic crosslinkable unsaturated monomer having at least two allyl groups, and an aromatic crosslinkable polyunsaturated monomer, in the presence of from 10 to 45% by weight, based on the total amount of the polymerizable monomers, of an inert organic solvent having a specific gravity of at least 1.0.
摘要翻译：一种制备丙烯腈交联共聚物的方法，其包括将丙烯腈，丙烯酸或甲基丙烯酸的烷基酯，具有至少两个烯丙基的脂肪族或脂环族交联性不饱和单体和芳香族交联性多不饱和单体作为聚合性单体共聚，在10至45重量％的存在下，基于可聚合单体的总量，比重为至少1.0的惰性有机溶剂。

50. 发明授权

EP0276718B1 Thermostabile Polymerisate 失效转让
标题翻译：热稳定聚合物
公开(公告)号：EP0276718B1
公开(公告)日：1992-09-02
申请号：EP88100624.1
申请日：1988-01-18
申请人： SKW Trostberg Aktiengesellschaft
发明人： Aignesberger, Alois, Dr. , Weichmann, Josef, Dr. , Plank, Johann, Dr. , Bichler, Manfred
IPC分类号： C08F226/10 , C08F220/44 , C08F220/54 , C09K7/02
CPC分类号： C09K8/24 , C08F8/44 , C08F220/44 , C08F220/54 , C08F226/10 , C08F2810/50 , C08F220/56 , C08F8/12 , C08F216/08

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