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    • 45. 发明公开
    • Novel rare-earth doped fluorides and process for preparing
    • 氟化物和Herstellungsverfahrendafür的Neue seltenerddotierte
    • EP1884553A2
    • 2008-02-06
    • EP07010047.4
    • 2007-05-21
    • E.I. du Pont de Nemours and Company
    • Chi, ChangzaiCrawford, Michael KarlMikeska, Kurt Richard
    • C09K11/77C01F11/22
    • C01F11/22C01F17/0012C01P2002/54C01P2006/90C09K11/7733
    • The invention is directed a composition represented by the chemical formula Eu x A 1-x F 2+x-2y O y wherein A is alkaline earth, 0.002 ≤ x ≤ 0.20, and 0 ≤y ≤x; the composition exhibiting a luminescence spectrum characterized by peaks at 592 ± 2 nm and 627 ± 2 nm, wherein the ratio of the peak intensity at 592 ± 2 nm to that at 627 ± 2 nm is at least 5% larger than the corresponding peak intensity ratio at the same wavelengths of a first corresponding reference composition with the same value of x that has not been exposed to a temperature above 100°C, and wherein said ratio of the peak intensity at 592 ± 2 nm to that at 627 ± 2 nm is at least 5% smaller than the corresponding peak intensity ratio at the same wavelengths of a second corresponding reference composition with the same value of x that has been subject to heating to 900°C for 6 hours.
    • 本发明涉及由化学式Eu x A 1-x F 2 + x-2y O y表示的组合物,其中A为碱土金属,0.002‰×‰0.20和0‰y‰x; 该组合物表现出以592±2nm和627±2nm的峰为特征的发光光谱,其中592±2nm处的峰强度与627±2nm处的峰强度的比例比相应的峰强度至少大5% 在相同波长的相同波长处的相同波长的第一对应参考组合物具有相同的未被暴露于高于100℃的温度的x的值,并且其中在592±2nm处的峰强度与627±2nm处的峰强度比 比第二相对应的参考组合物的相同波长的相应峰强度比小至少5%,其相同的x值已被加热到900℃6小时。