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41. 发明公开

EP2344206A1 PHOTOCATALYSEURS À BASE DE MOUSSES TRIDIMENSIONNELLES STRUCTURÉES EN CARBONE OU MATÉRIAU CARBONÉ 有权
标题翻译：光反应器含有光催化剂的三维结构碳泡沫由
公开(公告)号：EP2344206A1
公开(公告)日：2011-07-20
申请号：EP09740172.3
申请日：2009-09-14
申请人： Centre National de la Recherche Scientifique , Universite De Strasbourg
发明人： PHAM-HUU, Cuong , KELLER, Nicolas , LEDOUX, Marc-Jacques , KELLER-SPITZER, Valérie , BEGIN, Dominique , BERNHARDT, Pierre , JOSSET, Sébastien , HAJESMAILI, Shabnam , ROMERO, Thierry , WURTZ, Nathanaëlle , DOSS, Nizar
IPC分类号： A61L9/20 , B01D53/85 , B01D53/86 , B01J19/12 , B01J21/18 , B01J27/20 , B01J35/00 , B01J35/04 , C02F1/32 , F24F3/16
CPC分类号： B01J35/004 , A61L9/205 , A61L2209/14 , A61L2209/16 , B01D53/88 , B01D2255/802 , B01J21/063 , B01J21/18 , B01J35/04 , B01J35/1076 , B01J37/0219 , B01J37/0244 , B01J37/084 , C02F1/32 , C02F1/725 , C02F2305/10
摘要： The invention relates to a photocatalyst that comprises a cellular foam selected from carbon foam and the foam of a carbonated material such as a polymer, and a photocatalytically active phase directly deposited on said cellular foam or on an intermediate phase deposited on said cellular foam. The average size of the cells is 2500 μm to 5000 μm. The foam may comprise nanotubes or nanofibres (particularly of TiO
2 ).

42. 发明公开

EP2135671A2 Catalyst and method for producing carboxylic acid and/or carboxylic anhydride in the presence of the catalyst 有权
标题翻译：催化剂和方法在催化剂的存在下制备羧酸和/或羧酸酐的
公开(公告)号：EP2135671A2
公开(公告)日：2009-12-23
申请号：EP09162948.5
申请日：2009-06-17
申请人： Mitsubishi Gas Chemical Company, Inc.
发明人： Okamoto, Atsushi
IPC分类号： B01J23/28 , B01J27/199 , B01J27/20 , C07C37/60 , C07C51/15 , C07D493/04
CPC分类号： C07C51/235 , B01J21/18 , B01J23/20 , B01J23/22 , B01J23/24 , B01J23/28 , B01J27/198 , B01J37/0045 , C07C51/265 , C07C63/313
摘要： An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
摘要翻译：本发明的一个目的是提供一种催化剂具有特别在部分氧化反应的优异性能。另一个目的是提供一种通过有机化合物的气相部分氧化通过在催化剂的存在下使用含氧气的气体有效地生产羧酸或羧酸酐的方法。该催化剂含有（1）金刚石; （2）从第5族过渡元素的氧化物，统称氧化物A中选择的至少一种物质; 和（3）从第4族过渡元素的氧化物中选择的至少一种物质，统称氧化物B.用于制造羧酸或羧酸酐的方法，包括：通过使用经受有机化合物气相部分氧化的含氧在催化剂的存在下，worin有机化合物气体是在分子中具有一个或多个取代其的芳香族化合物，均包括在芳环键合到碳原子上的取代基。

43. 发明授权

EP1380342B1 COMPLEX CATALYST, PROCESS FOR PRODUCING THE COMPLEX CATALYST, AND PROCESS FOR PRODUCING ALCOHOL DERIVATIVE WITH THE COMPLEX CATALYST 有权
标题翻译： “配位化合物催化剂制造方法配合物催化剂和方法用于生产具有复杂CATALYST醇衍生物”
公开(公告)号：EP1380342B1
公开(公告)日：2009-07-01
申请号：EP02720443.7
申请日：2002-04-17
申请人： Sumitomo Chemical Company, Limited
发明人： SASAKI, Kazuaki
IPC分类号： B01J31/22 , C07B53/00 , C07C41/03 , C07C43/23 , C07D213/64 , B01J27/20
CPC分类号： B01J31/2243 , B01J2231/48 , B01J2531/0252 , B01J2531/60 , B01J2531/72 , B01J2531/845 , C07D213/64
摘要： An (asymmetric) complex catalyst comprising a Lewis acid and a metal complex represented by the formula (1): (wherein R?1, R2, R3, R4, R5, R6, R7, and R8¿ are the same or different and each represents hydrogen, halogeno, alkyl, etc.; one of R?9 and R10¿ represents hydrogen and the other represents C¿1-4? alkyl, etc.; Q represents a single bond, C1-4 alkylene, etc.; M represents a metal ion; and A represents a counter ion or ligand for balancing); a process for producing an (optically active) alcohol derivative, characterized by reacting a cyclic ether compound with a phenol derivative in the presence of the complex catalyst; and a process for producing an (optically active) nitrogenous heterocyclic compound which comprises reacting the alcohol derivative with a halogenated nitrogenous heterocyclic compound in the presence of a base.

44. 发明公开

EP2003718A1 ELECTROCONDUCTIVE CARBON CARRIER FOR FUEL BATTERY, ELECTRODE CATALYST FOR FUEL BATTERY, AND SOLID POLYMER ELECTROLYTE FUEL BATTERY COMPRISING THE SAME 无效
标题翻译： ELEKTRODENKATALYSATORFÜRBRENNSTOFFBATTERIE SOWIE FESTPOLYMERELEKTROLYT-BRENNSTOFFBATTERIE
公开(公告)号：EP2003718A1
公开(公告)日：2008-12-17
申请号：EP07741064.5
申请日：2007-03-29
申请人： Cataler Corporation , Toyota Jidosha Kabushiki Kaisha
发明人： TABATA, Toshiharu , TERADA, Tomoaki , NAGATA, Takahiro , ENOMOTO, Susumu , HORIUCHI, Yosuke , TAKAHASHI, Hiroaki , KAWAMURA, Tetsuo , KAWAI, Hideyasu
IPC分类号： H01M4/96 , B01J27/20 , H01M4/92 , H01M8/10
CPC分类号： H01M4/92 , H01M4/921 , H01M4/926 , H01M2008/1095
摘要： A conductive carbon carrier for a fuel cell having at least a surface layer graphitized, characterized in that the dimension (La) in a six-membered ring face (carbon plane) direction of a crystallite measured by X-ray diffraction is 4.5 nm or more. This carbon carrier improves the durability in a fuel cell and enables operation for a long period of time.
摘要翻译：一种用于至少具有石墨化表面层的燃料电池用导电性碳载体，其特征在于，通过X射线衍射测定的微晶的六元环面（碳平面）方向的尺寸（La）为4.5nm以上。该碳载体提高了燃料电池的耐久性，能够长时间运转。

45. 发明公开

EP0092909A2 Process for producing aminophenyl-beta-hydroxyethylsulfone 失效
标题翻译：一种用于生产氨基苯基-β-hydroxyethylsulfone过程。
公开(公告)号：EP0092909A2
公开(公告)日：1983-11-02
申请号：EP83301683.5
申请日：1983-03-25
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Kotera, Norio , Tada, Kazuhiro , Masaki, Shinzaburo , Goto, Kunihisa , Kaneoya, Tatsuo
IPC分类号： C07C147/12 , B01J27/20 , B01J25/02 , B01J23/74
CPC分类号： C07C323/00 , C07C317/00
摘要： A process for producing aminophenyl-β-hydroxyethylsulfone of the formula (I),
which comprises steps:

(1) condensing nitrohalobenzene with mercaptoethanol in the presence of an alkali hydroxide and at least one reaction medium selected from N-alkyl-substituted amides and sulfoxides to produce mono-nitrophenyl-β-hydroxyethylsulfide of the formula (II):

(2) oxidizing the mononitrophenyl-β-hydroxyethylsulfide (II) to produce mononitrophenyl-β-hydroxyethylsulfone of the formula (III):
and (3) reducing the mononitrophenyl-β-hydroxyethylsulfone to produce the aminophenyl-β-hydroxyethylsulfone of the formula (I). This compound is useful as an intermediate for aminophenyl-β-sulfatoethylsulfone represented by the following formula:
which is an important intermeidate for vinyl sulfone type reactive dyes largely used for dyeing cellulose fiber materials.

46. 发明公开

EP0065025A1 Preparation of carbamates from aromatic amines and organic carbonates 失效
标题翻译：从芳香胺和有机碳酸酯制备氨基甲酸酯
公开(公告)号：EP0065025A1
公开(公告)日：1982-11-24
申请号：EP81103809.0
申请日：1981-05-18
申请人： THE DOW CHEMICAL COMPANY
发明人： Gurgiolo, Arthur Emilio
IPC分类号： C07C125/06 , B01J23/06 , B01J27/04 , B01J27/20 , B01J31/04 , B01J31/06 , B01J31/08 , B01J31/12 , B01J31/22 , B01J31/26
CPC分类号： C07C271/06
摘要： This invention is directed to a process for preparing carbamates from an organic carbonate and an aromatic amine in the presence of a catalyst. The reaction is conducted at a temperature of at least 200°C and the catalyst is at least one member selected from the group consisting of (1) zinc or divalent tin salts of monocarboxylic acids having a pKa value of less than 2.8 other than such salts of trifluoroacetic acid; (2) divalent cobalt or trivalent cobalt salts of monocarboxylic acids having a pKa value of less that 2.8; (3) zinc or divalent tin or divalent cobalt or trivalent cobalt salts of organic materials having more than one -COOH group per molecule; (4) divalent cobalt or trivalent cobalt salts of a 1,3-diketone having from 5 to 10 carbon atoms; (5) tetravalent alkyl tin compounds or tetravalent alkyl tin oxides represented by formulas I and II:
and
wherein each R is independently a hydrocarbon group having from 1 to 10 carbon atoms, or a carboxylate group having from 2 to 10 carbon atoms, X is a halogen atom, x has an average value of from 1 to 5, and y has a value of from 1 to 4; and (6) an inorganic zinc compound selected from zinc carbonate, zinc sulfide, and zinc oxide.
摘要翻译：本发明涉及在催化剂存在下由有机碳酸酯和芳族胺制备氨基甲酸酯的方法。反应在至少200℃的温度下进行，并且催化剂是选自以下的至少一种：（1）pKa值小于2.8的一元羧酸的锌或二价锡盐，除了这些盐以外的三氟乙酸; （2）pKa值小于2.8的一元羧酸的二价钴或三价钴盐; （3）每分子具有多于一个-COOH基团的锌或二价锡或有机材料的二价钴或三价钴盐; （4）具有5至10个碳原子的1,3-二酮的二价钴或三价钴盐; （5）由式I和II表示的四价烷基锡化合物或四价烷基锡氧化物：并且其中每个R独立地为具有1至10个碳原子的烃基或具有2至10个碳原子的羧酸酯基团，X为卤素原子，x的平均值为1至5，并且y的值为1至4; 和（6）选自碳酸锌，硫化锌和氧化锌的无机锌化合物。

47. 发明公开

EP4117816A1 CATALYST SUPPORT 审中-实审
公开(公告)号：EP4117816A1
公开(公告)日：2023-01-18
申请号：EP21711943.7
申请日：2021-03-12
申请人： Johnson Matthey Hydrogen Technologies Limited
发明人： MCLEOD, Lucy , SHARMAN, Jonathan , SPIKES, Geoffrey , WALTON, Richard
IPC分类号： B01J27/20 , B01J27/22 , B01J27/24 , H01M4/88 , H01M4/90 , H01M4/92 , C01B21/082

49. 发明公开

EP4021637A1 CATALYST COMPRISING COKE AND PROCESS FOR THE PRODUCTION OF DIENES 审中-公开
公开(公告)号：EP4021637A1
公开(公告)日：2022-07-06
申请号：EP20761911.5
申请日：2020-08-25
申请人： Versalis S.p.A. , Alma Mater Studiorum Universita di Bologna
发明人： VELASQUEZ OCHOA, Juliana , CAVANI, Fabrizio , TOSI, Irene , FARCI, Erika , VECCHINI, Nicola
IPC分类号： B01J21/12 , B01J27/20 , B01J21/18 , B01J35/02 , B01J37/03 , B01J37/08 , C07C11/167 , C07C33/025 , B01J23/10

50. 发明公开

EP3129341A4 SYNTHESIS OF R-GLUCOSIDES, SUGAR ALCOHOLS, REDUCED SUGAR ALCOHOLS, AND FURAN DERIVATIVES OF REDUCED SUGAR ALCOHOLS 审中-公开
公开(公告)号：EP3129341A4
公开(公告)日：2017-12-06
申请号：EP14888904
申请日：2014-04-10
申请人： ARCHER-DANIELS-MIDLAND COMPANY
发明人： STENSRUD KENNETH , MA CHI-CHENG , MARTIN KEVIN
IPC分类号： C07C29/60 , B01J23/46 , B01J25/00 , B01J27/053 , B01J27/16 , B01J27/20 , C07C29/132 , C07C31/22 , C07C31/24 , C07C31/26 , C07D307/12
CPC分类号： C07D307/12 , B01J23/462 , B01J23/72 , B01J25/00 , B01J27/053 , B01J27/16 , B01J27/20 , C07C29/132 , C07C29/60 , C07G3/00 , C07C31/26 , C07C31/22 , C07C31/24
摘要： Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.

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