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    • 47. 发明公开
    • PROCESS FOR THE PRODUCTION OF BUTADIENE
    • VERFAHREN ZUR HERSTELLUNG VON BUTADIEN
    • EP2467352A1
    • 2012-06-27
    • EP10745029.8
    • 2010-08-05
    • Lummus Technology Inc.
    • ARNOLD, Stephen CraigGAFFNEY, Anne MaeKARAS, Lawrence JohnANGEVINE, Philip JayYEH, Chuen YuanSONG, Ruozhi
    • C07C5/25C07C11/167
    • C07C5/327C07C5/2506C07C11/167Y02P20/127C07C11/08
    • Processes are provided for the production of butadiene from C
      4 containing feed stocks that contain isobutene and/or isobutane in addition to n-butcne(s) and/or n-butane. The processes of the present invention generally comprise feeding the feed stock to a combination butenes isomerization reaction and distillation tower for conversion of I -butene to 2-butenes and separation from isobutene and isobutane, followed by an oxydchydrogenation unit to convert n-butenes to butadiene. The processes may also include additional isomerization and/or dehydrogenation steps for the tower overhead and bottoms streams to create additional isobutene and/or n-bulenes for valued uses, which may include additional production of butadiene. The feed to the system may comprise any mixture or separate feeding of C
      4 olefins and C
      4 paraffins, at least one of which contains isobutene and/or isobutane.
    • 提供用于从包含异丁烯和/或异丁烷以及正丁烷和/或正丁烷的含C4原料的原料生产丁二烯的方法。 本发明的方法通常包括将原料进料到组合丁烯异构化反应和用于将1-丁烯转化为2-丁烯的蒸馏塔,并从异丁烯和异丁烷中分离出来,随后用氧化脱氢单元将正丁烯转化为丁二烯 。 该方法还可以包括用于塔塔顶馏出物和塔底物流的另外的异构化和/或脱氢步骤以产生用于重要用途的额外的异丁烯和/或正丁烯,其可以包括额外生产丁二烯。 系统的进料可以包括C4烯烃和C4链烷烃的任何混合物或单独进料,其中至少一种含有异丁烯和/或异丁烷。
    • 49. 发明公开
    • PROCESS AND SYSTEM FOR THE PRODUCTION OF ISOPRENE
    • VERFAHREN UND SYSTEM ZUR HERSTELLUNG VON ISOPREN
    • EP2462095A2
    • 2012-06-13
    • EP10745027.2
    • 2010-07-29
    • Lummus Technology Inc.
    • GARTSIDE, Robert, J.KLEINDIENST, Shane, R.
    • C07C4/04C07C11/10
    • C07C11/18C07C4/04
    • Disclosed herein is a process for producing isoprene that includes reacting a mixed C4 metathesis feed stream comprising isobutylene and at least one of 1-butene and 2-pentene in a first metathesis reactor in the presence of a first metathesis catalyst under conditions sufficient to produce an intermediate product stream comprising at least 30 wt. % 2-methyl-2-pentene based upon the olefin content of fresh feed in the mixed C4 feed stream, and at least one of ethylene and propylene, separating the 2-methyl-2-pentene, subjecting the separated 2-methyl-2-pentene to pyrolysis to produce a reaction product stream comprising isoprene, and separating the isoprene into an isoprene product stream using fractionation. A system used in producing isoprene is also disclosed.
    • 本文公开了一种生产异戊二烯的方法,其包括在第一复分解反应器存在下,使第一复分解催化剂中包含异丁烯和1-丁烯和2-戊烯中的至少一种的混合C4复分解进料流在足以产生 中间产物流包含至少30重量% 基于混合C 4进料流中的新鲜进料的烯烃含量和乙烯和丙烯中的至少一种的2-甲基-2-戊烯,分离2-甲基-2-戊烯,使分离的2-甲基-2-戊烯 戊烯进行热解以产生包含异戊二烯的反应产物流,并使用分馏将异戊二烯分离成异戊二烯产物流。 还公开了用于生产异戊二烯的体系。