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    • 45. 发明公开
    • Exchangeable continous casting nozzle
    • AuswechselbareGiessdüzezum Kontinueierlichen Giessen
    • EP1149649A1
    • 2001-10-31
    • EP00122935.0
    • 2000-10-21
    • Akechi Ceramics Kabushiki KaishaTOKYO YOGYO KABUSHIKI KAISHA
    • Sasajim, YasushiAndo, MitsuruTakahashi, Shigeaki
    • B22D41/50B22D41/52B22D11/10
    • B22D41/50
    • An exchangeable continuous casting nozzle used for a slide nozzle device (100) connected to an upper nozzle (1) disposed on a bottom portion of a container for molten metal, comprises a nozzle including a flange portion (22) made of a refractory material having a through hole for receiving molten metal flowing out of the upper nozzle (1), and a tube body of a refractory material having another through hole following the through hole, and a metal protecting body including a metal casing portion (26A) surrounding the flange portion (22), a metal skirt portion (26B) surrounding an upper portion of the tube body following the flinge portion (22), and metal reinforcing portions disposed on the slide nozzle device (100) in parallel with a direction to detach/attach the nozzle for reinforcing junction between the metal casing portion (26A) and the metal skirt (26B).
    • 用于连接到设置在用于熔融金属的容器的底部的上喷嘴(1)上的滑动喷嘴装置(100)的可交换连续铸造喷嘴包括喷嘴,该喷嘴包括由耐火材料制成的凸缘部分(22) 用于接收从上部喷嘴(1)流出的熔融金属的通孔和具有贯穿通孔的另一通孔的耐火材料的管体,以及金属保护体,其包括围绕凸缘的金属壳体部分(26A) 部分(22),围绕所述悬挂部分(22)的围绕所述管体的上部的金属裙部(26B)以及设置在所述滑动喷嘴装置(100)上的平行于拆卸/附接的方向的金属加强部 用于加强金属壳体部分(26A)和金属裙部(26B)之间的连接处的喷嘴。
    • 47. 发明公开
    • Sensor probe for measuring hydrogen concentration in molten metal and method for measuring hydrogen concentration
    • Verfahren und Vorrichtung zur Wasserstoffkonzentrationsmessung inflüssigenMetallen。
    • EP0544281A1
    • 1993-06-02
    • EP92120184.4
    • 1992-11-26
    • TOKYO YOGYO KABUSHIKI KAISHA
    • Koide, KunihiroYajima, Tamotsu
    • G01N27/406
    • G01N27/4118G01N27/4114
    • On the inner surface of sensor element (1) made of proton conductive solid electrolyte with perovskite structure and enclosed at its lower end, a reference electrode (2) constituted of porous electrode is formed, and a measuring electrode (3) constituted of porous electrode is formed on the outer surface thereof. And, the reference electrode and the measuring electrode are gas-tightly separated by sealing material. The sensor prove is inserted into ceramic sensor holding cup (10) and both are fixed in such a way that a part of the measuring electrode (3) extrude into said holding cup. Then, by dipping the holder into molten metal (19)by facing its opening part downwards, a space contacting with molten metal is enclosed in the holding cup.
      Thereby, reduction of solid electrolyte constituting the sensor element can be prevented, and hydrogen concentration in molten metal can be accurately measured without direct dipping the sensor element into molten metal. Thereby, it is possible to provide a sensor probe and a method for measuring hydrogen concentration in which hydrogen concentration can be continuously measured for long period and an apparatus with smaller size can be made.
    • 在由具有钙钛矿结构的质子传导性固体电解质制成的传感器元件(1)的内表面上,封装在其下端,形成由多孔电极构成的参比电极(2),由多孔电极构成的测量电极 形成在其外表面上。 并且,参考电极和测量电极由密封材料气密分离。 将传感器证明插入到陶瓷传感器保持杯(10)中,并且两者都固定成使得测量电极(3)的一部分挤出到所述保持杯中。 然后,通过向下面朝向其开口部分将保持器浸入熔融金属(19)中,与熔融金属接触的空间被封闭在保持杯中。 由此,可以防止构成传感器元件的固体电解质的降低,并且可以精确地测量熔融金属中的氢浓度,而无需将传感器元件直接浸入熔融金属中。 因此,可以提供一种传感器探头和用于测量长时间连续测量氢浓度的氢浓度的方法,并且可以制造具有较小尺寸的装置。
    • 48. 发明公开
    • Vacuum-suction degassing method and an apparatus therefor
    • Verfahren und Vorrichtungfürdie Vakuum-Entgasung。
    • EP0462536A1
    • 1991-12-27
    • EP91109887.9
    • 1991-06-17
    • Sano, MasamichiTOKYO YOGYO KABUSHIKI KAISHA
    • Sano, MasamichiMiyagawa, NobuoYamamoto, Kunji
    • C22B9/04B22D18/06B22D27/15
    • C22B9/04C22B9/05
    • A melt (2) is stored in a vessel (5) placed in a decompression vessel (10). On the bottom of the vessel is arranged a bubble generator (9) made of porous bricks, and bubbles of argon gas are introduced into the melt through this bubble generator. Also a lower half section of a degassing member is immersed in the melt. This degassing member (6) has a cylindrical form with the lower end closed and the section immersed in the melt is made of a porous material permeable to gases and impermeable to melts.
      With these features, a surface of molten metal can be put under reduced pressure and high content components of the melt can be removed by means of bubbling, and also solute components in the melt can be removed into bubbles of argon gas. Also, gases in the melt and gases produced by reactions between the melt and the porous material can be sucked through a wall of the degassing member into inside thereof and removed.
    • 将熔体(2)储存在放置在减压容器(10)中的容器(5)中。 在容器的底部布置有由多孔砖制成的气泡发生器(9),并且通过该气泡发生器将氩气气体引入熔体中。 此外,脱气构件的下半部分浸入熔体中。 该脱气构件(6)具有圆柱形形式,其下端封闭,并且浸入熔体中的部分由可渗透气体并且不能熔化的多孔材料制成。 通过这些特征,能够减少熔融金属的表面,通过鼓泡可以除去熔融物的高含量成分,并且可以将熔融物中的溶质中的溶质除去到氩气气泡中。 此外,通过熔体和多孔材料之间的反应产生的熔体中的气体和气体可以通过脱气构件的壁​​被吸入其内部并被去除。
    • 49. 发明公开
    • Vacuum-suction degassing apparatus
    • VAKUUM-Entgasungs-Vorrichtung。
    • EP0462535A1
    • 1991-12-27
    • EP91109886.1
    • 1991-06-17
    • Sano, MasamichiTOKYO YOGYO KABUSHIKI KAISHA
    • Sano, MasamichiMiyagawa, NobuoYamamoto, Kunji
    • C22B9/04
    • C22B9/04
    • A melt (2) is stored in a vessel(5). A lower half of a degassing member (6) is immersed in the melt. The degassing member has a cylindrical form with the lower end closed, and the lower half section is made of a porous material which is permeable to gas and impermeable to melts as molten metal, molten slag, or molten matte. This lower half section is a partitioning member (6a). When an internal space inside the degassing member is sucked to realize vacuum or reduced pressure atmosphere, gas-producing components in the melt pass through the partition member (6a) of the degassing member, and are exhausted to inside the degassing member, thus being separated from the melt. Also, by making the degassing member rotate or move in a horizontal or vertical direction, the melt is stirred. With these features, gas-producing components in the melt can be removed at a high efficiency.
    • 熔体(2)储存在容器(5)中。 将脱气构件(6)的下半部浸入熔体中。 脱气构件具有下端闭合的圆柱形,下半部由多孔材料制成,该多孔材料可渗透气体,并且不可熔化为熔融金属,熔融炉渣或熔融锍。 该下半部分是分隔构件(6a)。 当抽吸脱气构件内的内部空间以实现真空或减压气氛时,熔体中的气体产生部件通过脱气构件的分隔构件(6a),排出到脱气构件内部,从而被分离 从熔化。 此外,通过使脱气构件在水平或垂直方向上旋转或移动,搅拌熔体。 利用这些特征,可以高效地除去熔体中的气体生成成分。