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31. 发明授权

EP1287064B1 MOLECULAR WEIGHT MODIFICATION OF THERMOPLASTIC POLYMERS 有权
标题翻译：热塑性聚合物的分子量改性
公开(公告)号：EP1287064B1
公开(公告)日：2006-03-22
申请号：EP01981920.0
申请日：2001-05-22
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： ROTH, Michael , PFAENDNER, Rudolf , SIMON, Dirk
IPC分类号： C08K5/3435 , C08K5/32 , C08K5/00 , C08L23/00
CPC分类号： C08K5/32 , C08K5/0025 , C08K5/3435 , C08L2023/44
摘要： The invention relates to a process for the molecular weight increase/crosslinking of non-halogen-containing thermoplastic polymers, in which process a composition comprising a) a non-halogen-containing thermoplastic polymer; b) a functional compound having at least two unsaturated carbon bonds; and c) an alkoxyamine having a structural unit (I), which forms free radicals at the melting temperature/processing temperature of the polymer, is mixed and heated above the melting point of the polymer in the case of crystalline polymers or the softening point in the case of amorphous polymers. The invention relates also to the composition itself, to the use thereof in increasing the molecular weight of polymers and to polymers having increased molecular weight or crosslinked polymers prepared in accordance with that process.

32. 发明公开

EP1601719A1 COATING COMPOSITION COMPRISING HYDROXYLAMINE ESTERS 有权
标题翻译：含羟胺涂料组合物
公开(公告)号：EP1601719A1
公开(公告)日：2005-12-07
申请号：EP04716608.7
申请日：2004-03-03
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： WOLF, Jean-Pierre , MISEV, Ljubomir , NESVADBA, Peter , ZEREN, Sevgi
IPC分类号： C08K5/32 , C08K5/3435 , C09D4/00 , C09D4/06 , C09D5/03
CPC分类号： C09D4/00 , C08K5/3435
摘要： The invention relates to a dual thermal and ultraviolet radiation curable coating composition, comprising a) at least an ethylenically unsaturated compound; b) a hydroxylamine ester effective to enable IR-curing or NIR-curing of the ethylenically unsaturated compound; c) a photoinitiator effective to enable UV-curing of the ethylenically unsaturated compound; wherein the thermal initiator is a hydroxylamine ester which has a structural element of formula (1) or formula (1) or a polymeric hydroxylamine ester which has a repetitive structural unit of formula (11) or (I[') of formula (11) Furthermore, the invention relates to a process for curing a thermal curable coating composition compOsing hydroxylamine esters as thermal initiators using NIR-curing.

33. 发明公开

EP1564254A1 Unsaturated polyester resing or vinyl ester resin compositions 审中-公开
标题翻译：涤纶涤纶涤纶
公开(公告)号：EP1564254A1
公开(公告)日：2005-08-17
申请号：EP04075488.9
申请日：2004-02-17
申请人： DSM IP Assets B.V.
发明人： Jansen, Johan Franz Gradus Antonius , Kraeger, Ivo Ronald
IPC分类号： C08L67/06 , C08L31/04 , C08K5/32 , C08K5/18
CPC分类号： C08K5/18 , C08L67/06
摘要： The present invention relates to a method of providing unsaturated polyester resin or vinyl ester resin compositions containing a phenolic inhibitor and showing a reduced gel-time drift tendency, wherein first a primary resin composition containing a phenolic inhibitor is produced with the phenolic inhibitor being selected from the group of phenolic compounds of which the O-H bond dissociation enthalpy is in the range of from about 325 to 380 kJ/mol, and wherein in a further step an aromatic amine compound for which the calculated oxidation potential (CE ox ) is equal to or lower than 659 kJ/mol is added to said primary unsaturated polyester resin or vinyl ester resin composition. In a preferred embodiment of the invention, in addition to the aromatic amine compound having a CE ox equal to or lower than 659 kJ/mol, also an amount of an N-oxyl compound is being added.
The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing. Such cured resin compositions can suitably be used in the field of chemical anchoring, construction, roofing, flooring, windmill blades, containers, tanks, pipes, automotive parts, boats, etc.
摘要翻译：本发明涉及一种提供含有酚类抑制剂的不饱和聚酯树脂或乙烯基酯树脂组合物的方法，其显示出降低的凝胶时间漂移趋势，其中首先制备含有酚类抑制剂的主要树脂组合物，酚类抑制剂选自 OH键解离焓在约325〜380kJ / mol的范围内的酚类化合物组，其中在另外的步骤中计算出的氧化电位（CEox）等于或低于其的芳族胺化合物对所述一次不饱和聚酯树脂或乙烯基酯树脂组合物加入659kJ / mol以上。在本发明的优选实施方案中，除了具有等于或低于659kJ / mol的CEox的芳族胺化合物之外，还加入了一定量的N-氧基化合物。本发明还涉及通过固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。这种固化的树脂组合物可以适用于化学锚固，建筑，屋顶，地板，风车叶片，容器，罐，管道，汽车零件，船等领域。

34. 发明公开

EP1564253A1 Unsaturated polyester resins or vinyl ester resin compositions 审中-公开
标题翻译：涤纶涤纶涤纶
公开(公告)号：EP1564253A1
公开(公告)日：2005-08-17
申请号：EP04075482.2
申请日：2004-02-17
申请人： DSM IP Assets B.V.
发明人： Jansen, Johan Franz Gradus Antonius , Kraeger, Ivo Ronald
IPC分类号： C08L67/06 , C08L31/04 , C08K5/3435 , C08K5/32
CPC分类号： C08K5/32 , C08K5/3435 , C08L67/06
摘要： The present invention relates to a method of providing unsaturated polyester resin or vinyl ester resin compositions containing a phenolic inhibitor and showing a reduced gel-time drift tendency, wherein first a primary resin composition containing a phenolic inhibitor is produced with the phenolic inhibitor being selected from the group of phenolic compounds of which the O-H bond dissociation enthalpy is in the range of from 78 to 91 kcal/mol, and wherein in a further step an N-oxyl radical compound is added to said primary unsaturated polyester resin or vinyl ester resin composition. In a preferred embodiment of the invention, in addition to the N-oxyl radical compound, also an amount of an amine compound is being added.
The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions. by curing. These can suitably be used in the field of chemical anchoring, construction, roofing, flooring, windmill blades, containers, tanks, pipes, automotive parts, boats, etc.
摘要翻译：本发明涉及一种提供含有酚类抑制剂的不饱和聚酯树脂或乙烯基酯树脂组合物的方法，其显示出降低的凝胶时间漂移趋势，其中首先制备含有酚类抑制剂的主要树脂组合物，酚类抑制剂选自 OH键解离焓在78〜91kcal / mol的范围内的酚类化合物组，其中在另外的步骤中，将N-氧基自由基化合物加入到所述一次不饱和聚酯树脂或乙烯基酯树脂组合物中。在本发明的优选实施方案中，除了N-氧基自由基化合物之外，还加入一定量的胺化合物。本发明还涉及由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。通过治疗。这些可以适用于化学锚固，建筑，屋面，地板，风车叶片，集装箱，水箱，管道，汽车零件，船只等领域。

35. 发明授权

EP0969038B1 Rubber composition for tyre tread 有权
标题翻译：轮胎胎面用橡胶组合物
公开(公告)号：EP0969038B1
公开(公告)日：2004-03-24
申请号：EP99305207.5
申请日：1999-07-01
申请人： Sumitomo Rubber Industries Ltd.
发明人： Mizuno, Yoichi , Matsuo, Toshiro
IPC分类号： C08K5/32 , C08L21/00 , B60C1/00
CPC分类号： B60C1/0016 , C08K5/32 , Y02T10/862 , Y10S152/905 , Y10T152/10 , C08L21/00

36. 发明授权

EP1263862B1 AMINE OXIDES AS ASPHALT EMULSIFIERS 有权
标题翻译：阿明氧化物THAN沥青乳化剂
公开(公告)号：EP1263862B1
公开(公告)日：2004-02-18
申请号：EP01914116.7
申请日：2001-03-01
申请人： Akzo Nobel N.V.
发明人： WATES, Julia, Mary , THORSTENSSON, Bengt-Arne , JAMES, Alan
IPC分类号： C08K5/32 , C08L95/00 , B01F17/00 , C09K7/00 , E21B43/22 , C07C291/04
CPC分类号： C08L95/005 , B01F17/0042 , B01F17/005 , C07C291/04 , C08K5/32
摘要： A method of emulsifying asphalt using a polyamine polyoxide, preferably a diamine dioxide, as an emulsifier or co-emulsifier and an emulsion of asphalt, water and a polyamine polyoxide, preferably a diamine dioxide. The advantages of using a polyamine polyoxide as an emulsifier or co-emulsifier include its ability to provide superior cationic and anionic emulsions, and slow-setting emulsions at low use levels, and the excellent adhesion of the cured asphalt film.

37. 发明公开

EP1239006A1 Polyester and polyamide compositions of low residual aldehyde content 有权
标题翻译：聚酯和聚酰胺树脂中的维他命
公开(公告)号：EP1239006A1
公开(公告)日：2002-09-11
申请号：EP02405128.6
申请日：2002-02-21
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： Odorisio, Paul Angelo , Andrews, Stephen Mark , Lazzari, Dario , Simon, Dirk , King, Roswell Easton , Stamp, Melissa , Reinicker, Roger , Tinkl, Michael , Berthelon, Natacha , Müller, Daniel , Hirt, Urs
IPC分类号： C08K5/00 , C08K5/16 , C08K5/32 , C08K5/34
CPC分类号： C08K5/32 , C08K5/17 , C08K5/34 , C08L67/02 , C08L77/00
摘要： A mixture of a polyester, such as poly(ethylene terephthalate) PET, or a polyamide, and a suitable stabilizer selected from the group consisting of hydroxylamine stabilizers, substituted hydroxylamine stabilizers, nitrone stabilizers and amine oxide stabilizers, when extrusion compounded exhibits a lower residual acetaldehyde content than does polyester or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.
摘要翻译：当挤出复合时，聚酯（例如聚对苯二甲酸乙二醇酯）PET或聚酰胺和选自羟胺稳定剂，取代羟胺稳定剂，硝酮稳定剂和氧化胺稳定剂的合适稳定剂的混合物表现出较低的残留乙醛含量比同样处理的聚酯或聚酰胺单独使用。本发明涉及用于制造模塑制品，纤维或薄膜的任何聚酯或聚酰胺，例如用于储存消费材料（例如食品，饮料和水）的瓶子或容器。

38. 发明公开

EP1170329A1 Polymeric composition, its use for the manufacture of object and object so obtained 审中-公开
标题翻译：聚合物组合物和其用于物体中的用途，因此制造物品
公开(公告)号：EP1170329A1
公开(公告)日：2002-01-09
申请号：EP01202534.2
申请日：2001-07-02
申请人： SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme)
发明人： Spino, Larry , Swanzy, Scott
IPC分类号： C08K5/32 , C08K5/52 , C08K5/53 , C08K5/15 , C08K5/3435 , C08L23/10 , C08K5/00
CPC分类号： C08K5/52 , C08K5/005 , C08K5/32 , C08K5/3435 , C08K5/53 , C08L23/10
摘要： A stabilized polypropylene composition, free or essentially free of any phenolic antioxidant containing:

a) 100 parts by weight of a propylene polymer,
b) from 0.005 to 0.1 part by weight of an amine oxide having the structural formula
wherein R' and R" are groups containing from 1 to 36 carbon atoms, or of a N,N-dialkylhydroxylamine of formula

R 1 R 2 NOH (II)

wherein
R 1 and R 2 are independent groups of 1 to 36 carbon atoms,
c) from 0.1 to 0.5 part by weight of a clarifying agent, and optionally
d) from 0.01 to 0.1 part by weight of a sterically hindered amine.

Manufacture of shaped object by using said composition and manufactured objects so obtained.
摘要翻译：一种稳定化的聚丙烯组合物，不含或基本上不含任何酚类抗氧化剂含有：A）100份（重量）的丙烯聚合物，b）由0.005至0.1重量份具有以下结构式 worin R“和氧化胺的 R“是含有1至36个碳原子的基团，或式R <1> [R <2> NOH worin - [R <1>和R <2>是独立的基团的1至36个碳原子的N，N-二烷基羟胺的 C）为0.1（重量）的澄清剂，和任选的d从0点01分至0.1重量份的空间位阻胺的0.5份）。通过使用所述组合物和制造的对象，例如获得制造造型物。

39. 发明公开

EP0867467A1 Compositions stabilized with tertiary amine oxides 失效
标题翻译：咪唑钠稳定剂Zusammensetzungen
公开(公告)号：EP0867467A1
公开(公告)日：1998-09-30
申请号：EP98302048.8
申请日：1998-03-18
申请人： GENERAL ELECTRIC COMPANY
发明人： Prabhu, Vaikunth S. , Avakian, Roger W.
IPC分类号： C08K5/00 , C08K5/32 , C08L23/02
CPC分类号： C08K5/32 , C08K5/005
摘要： Thermoplastic resin composition are provided that comprise a thermoplastic resin or mixture thereof, a stabilizing amount of a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the 3-arylbenzofuranones, the hindered amine stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids, the hydroxylamines, and the thiosynergists, and a stabilizing amount of a tertiary amine oxide. The compositions have improved stability against discoloration upon exposure to heating or to the combustion products of natural gas by the concomitant presence of an effective amount of a tertiary amine oxide.
摘要翻译：提供了热塑性树脂组合物，其包含热塑性树脂或其混合物，稳定剂量的稳定剂或稳定剂混合物，其选自酚类抗氧化剂，3-芳基苯并呋喃酮，受阻胺稳定剂，紫外光吸收剂，有机磷化合物，脂肪酸的碱金属盐，羟胺和硫代增效剂，以及稳定量的叔胺氧化物。通过伴随有效量的叔胺氧化物的存在，组合物在暴露于加热或天然气的燃烧产物时具有改善的抗变色稳定性。

40. 发明授权

EP0560447B1 Thermoplastic composition based on polyphenylene ether and polyamide 失效
标题翻译：一种热塑性组合物基于聚苯醚和聚酰胺
公开(公告)号：EP0560447B1
公开(公告)日：1998-05-13
申请号：EP93200673.7
申请日：1993-03-09
申请人： ENICHEM S.p.A.
发明人： Ghidoni, Dario , Bencini, Elena
IPC分类号： C08L71/12 , C08L77/00 , C08K5/32 , C08K5/3417
CPC分类号： C08K5/3417 , C08K5/32 , C08L53/00 , C08L71/123 , C08L77/00 , C08L71/12 , C08L71/00

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