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    • 32. 发明公开
    • Star polymer and method for producing the same
    • Sternpolymere和Herstellungsverfahren
    • EP2311900A1
    • 2011-04-20
    • EP10014901.2
    • 2006-09-07
    • Nippon Soda Co., Ltd.
    • Niitani, Takeshi
    • C08G81/00C08F4/00C08F8/00C08F289/00C08G64/00
    • C08F289/00C08F4/00C08F265/04C08F285/00C08F291/00C08F293/00C08F293/005C08F297/00C08F297/02C08G81/00C08G83/003C08L53/00C08L2666/02
    • The present invention provides a novel narrow distribution dendrimer-like star polymer having a controlled molecular structure, and a method capable of easily producing the star polymer.
      Disclosed is a polymer comprising a core portion and an arm portion, wherein the arm portion includes a first generation composed of a polymer chain and a second generation composed of a polymer chain formed at the outer shell of the first generation, the number of arms of the second generation is larger than the number of arms of the first generation, the first generation composed of the polymer chain is a polymer chain derived from a monomer having a polymerizable double bond, and the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), (Mw/Mn), of the star polymer is within a range from 1.001 to 2.50. A compound containing a functional group capable of reacting with an anion, which serves as a core portion, is reacted with a polymer chain containing two or more functional groups and an anion end which serves as an arm portion.
    • 本发明提供了具有受控分子结构的新型窄分布树枝状大分子星形聚合物和能够容易地制备星形聚合物的方法。 公开了一种包含芯部和臂部的聚合物,其中臂部包括由聚合物链组成的第一代和由形成在第一代的外壳的聚合物链构成的第二代, 第二代大于第一代的臂数,由聚合物链组成的第一代是由具有可聚合双键的单体衍生的聚合物链,并且重均分子量(Mw)与 星形聚合物的数均分子量(Mn)(Mw / Mn)在1.001〜2.50的范围内。 与能够与作为核心部分的阴离子反应的官能团的化合物与含有两个以上官能团的聚合物链和作为臂部的阴离子末端反应。