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    • 31. 发明公开
    • Method of recovering valuable metals from waste materials, particularly from spent petroleum cracking catalysts
    • 一种用于从废催化剂从废物中回收高品质的金属,特别是重油的催化裂化方法。
    • EP0150438A2
    • 1985-08-07
    • EP84115725.8
    • 1984-12-18
    • STAUFFER CHEMICAL COMPANY
    • Carron, Mark Stuart
    • C22B7/00C22B34/22C22B23/02
    • C22B23/02C22B7/009C22B34/22Y02P10/214
    • The invention is directed to a process of treating waste materials, particularly petroleum cracking catalyst waste containing contaminating and/or valuable metals to decontaminate the waste and/or recover the metals therefrom which process comprises the reduction of the metals contained in the waste in the presence of a slag former such as a silica-alumina composite, a flux such as a Group IA or IIA oxide and a phosphate containing compound. The metals are recovered as metals or metal phosphides in a distinct ferrophos layer. The accumulated metals can be further processed to recover the metal content thereof. The process parallels the electrothermal process for producing phosphorus which is desirably utilized as disclosed herein to recover valuable Group VB to Group VIII metals.
    • 本发明涉及治疗废物材料,特别是石油裂化催化剂废物含污染和/或有价金属以净化废物和/或从该过程回收金属存在的方法包括在存在包含在废物中的金属的还原 渣前的:如二氧化硅 - 氧化铝复合物,通量:如IA族或IIA族氧化物和含有磷酸盐化合物。 金属被回收作为在不同层Ferrophos金属或金属磷化物。 累积的金属可被进一步处理以回收其金属含量。 过程平行的制造磷所有这一切都理想地用作在游离缺失回收有价值VB族至VIII族金属盘电热过程。
    • 34. 发明公开
    • Process for removing metal values from oxidic materials
    • Verfahren zum Aufbereiten oxidischer Materialien。
    • EP0034434A1
    • 1981-08-26
    • EP81300441.3
    • 1981-02-03
    • Laporte Industries Limited
    • Robinson, MichaelWilson, Harry Brian
    • C22B1/08C22B21/00C22B23/02C22B34/12C22C35/00C01G49/10
    • C22B21/0007C01G49/06C01P2006/80C22B1/08C22B23/02C22B34/1222Y02P10/216Y02P10/23
    • Low grade oxidic ores, such as, for example, chromite, tantalite, wolframite, ilmenite or bauxite may be beneficiated by chlorinating the ore in a fluidised bed in the presence of carbon to produce a gaseous effluent containing ferrous chloride, partially oxidising the ferrous chloride to a mixture of ferric oxide and iron chloride, condensing and then revolatilising the iron chloride, oxidising the revolatilised iron chloride to release chlorine and recycling the chlorine to the ore chlorination. The process lends itselfto efficiency of operation. The ore may be preheated by the combustion of carbon utilising also the combustion of volatiles from the calcining of the carbon. Preferably, sufficient carbon is present during the ore preheating to supply also the needs of the chlorination. Preferably solid iron chloride is volatilised in the gaseous effluent from the chlorination. Iron oxide recovered may be used as a coolant in steel making. The residual beneficiated ores may be used in the production of special steels or for other uses.
      In a modification of the process values of metals other than iron such as, for example, values of boron, gallium, zirconium, thorium, titanium or uranium aluminium or silicon, may be removed from ore.
    • 可以通过在碳存在下将流化床中的矿石氯化以产生含有氯化亚铁的气态流出物,部分氧化氯化亚铁,从而选择低等级的氧化矿石,例如铬铁矿,钽铁矿,钨铁矿,钛铁矿或铝土矿 将氧化铁和氯化铁的混合物冷凝,然后使氯化铁旋转,氧化氯化铁,释放氯气,并将氯再循环到矿石中。 该过程适用于操作效率。 矿石可以通过碳的燃烧利用来自煅烧碳的挥发物的燃烧来预热。 优选地,在矿石预热期间存在足够的碳以提供氯化的需要。 优选地,固体氯化铁在氯化气体流出物中挥发。 回收的氧化铁可用作炼钢中的冷却剂。 剩余的精选矿石可用于生产特殊钢或其他用途。 在例如硼,镓,锆,钍,钛或铀铝或硅的值以外的金属的处理值的修改中,可以从矿石中除去。