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31. 发明公开

EP0183083A1 Process for the preparation of (2,2)-paracyclophane 失效
标题翻译： Verfahren zur Herstellung von（2,2）-Paracyclophan。
公开(公告)号：EP0183083A1
公开(公告)日：1986-06-04
申请号：EP85113918.8
申请日：1985-10-31
申请人： Montedison S.p.A.
发明人： Malacrida, Alessandro , Montanari, Fernando , Bottaccio, Giorgio, Dr. , Campolmi, Stefano, Dr.
IPC分类号： C07C13/70 , C07C1/32 , C07C87/30
CPC分类号： C07C1/323 , C07C2603/92 , C07C13/70
摘要： Process for the preparation of (2,2)-paracyclophane starting from p.methyl-benzyl-trimethyl-ammonium halide, consisting in first preparing the p.methyl-benzyl-trimethyl-ammonium hydroxide and successively subjecting the product thus obtained to the HOFMANN Elimination in the presence of a biphasic system consisting of an inert organic solvent and an alkaline solution having a concentration of at least 20% by weight.
The present invention refers to a process for the preparation of (2,2)-paracyclophane of the general formula:

More particularly, the present invention relates to a process for the preparation of (2,2)-paracyclophane of formula (1), starting from a p.methyl-benzyl-trimethyl-ammonium halide of the formula:
wherein: X is a halide such as chlorine, bromine, etc., by the elimination of HOFMANN.
摘要翻译：从（p）甲基 - 苄基 - 三甲基 - 卤化铵开始制备（2,2） - 对环烷酸的方法，首先制备对甲基 - 苄基 - 三甲基 - 氢氧化铵，并依次将由此获得的产物经受HOFMANN 在存在由惰性有机溶剂和浓度为至少20重量％的碱性溶液组成的双相体系的情况下消除。本发明涉及一种制备通式为（CH 2）的（2,2） - 对环烷烃的方法。更具体地说，本发明涉及一种制备式（2）的（2,2） - 对环烷烃的方法， I），由下式的对甲基 - 苄基 - 三甲基 - 卤化铵开始：其中：X是卤素如氯，溴等，通过消除HOFMANN。

32. 发明授权

EP0037116B1 Composés bicycliques polyinsaturés, leur préparation et leur utilisation à titre de produits de départ pour la préparation de composés bicycliques monoinsaturés 失效
标题翻译：双相和歧管不饱和化合物，其制备及其作为起始材料在双相单体不饱和化合物的制备中的应用
公开(公告)号：EP0037116B1
公开(公告)日：1983-12-14
申请号：EP81102399.3
申请日：1981-03-30
申请人： FIRMENICH SA
发明人： Fehr, Charles
IPC分类号： C07C13/32 , C07C1/253 , C07C1/32 , C07C5/05 , C07C147/02
CPC分类号： C07C317/00 , C07C1/322 , C07C5/05 , C07C13/32 , C07C2523/00 , C07C2602/32

33. 发明公开

EP4186883A1 A PROCESS FOR PREPARING A 3,7-DIMETHYLALKANE COMPOUND 审中-实审
公开(公告)号：EP4186883A1
公开(公告)日：2023-05-31
申请号：EP22209109.2
申请日：2022-11-23
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： MIYAKE, Yuki , WATANABE, Takeru , KINSHO, Takeshi
IPC分类号： C07C1/32 , C07C9/22 , C07C17/263 , C07C19/01 , C07F3/02
摘要： The present invention relates to a process for preparing a 3,7-dimethylalkane compound (3):wherein n is 5 or 6, the process comprising: subjecting a nucleophilic reagent, 2,6-dimethyloctyl compound (1): wherein M 1 represents Li, Mg Z 1 , CuZ 1 , or CuLiZ 1 , wherein Z 1 represents a halogen atom or a 2,6-dimethyloctyl group, to a coupling reaction with an electrophilic alkyl reagent (2): wherein X 1 represents a halogen atom or a p-toluenesulfonate group, and "n" is as defined above, to form the 3,7-dimethylalkane compound (3).

34. 发明公开

EP4169894A1 DIMETHYL SULPHIDE CONVERSION INTO C2-C3 OLEFINS 审中-公开
公开(公告)号：EP4169894A1
公开(公告)日：2023-04-26
申请号：EP21315223.4
申请日：2021-10-21
申请人： TotalEnergies OneTech
发明人： Veryasov, Gleb , Nesterenko, Nikolai
IPC分类号： C07C1/32 , C07C11/04 , C07C11/06 , B01J32/00 , B01J29/70 , B01J29/78
摘要： The disclosure provides for a process for converting dimethyl sulfide into C2-C3 olefins, said process comprising the steps: a) providing a gaseous feed stream comprising dimethyl sulphide and optionnally one or more optional diluents; b) providing a catalyst composition; and c) contacting the gaseous feed stream with the catalyst composition at a temperature ranging from 100°C to 700°C and at a pressure ranging from 0.2 MPa.to 20 MPa, to convert at least part of the dimethyl sulphide into C2-C3 olefins; and d) recovering said C2-C3 olefins and the unconverted dimethyl sulphide if any wherein the catalyst composition comprises one or more zeolites with a plurality of pores with a shape of an 8-member ring.

35. 发明公开

EP4116282A1 METHOD FOR PRODUCING MONO-CROSS-COUPLED AROMATIC COMPOUND HAVING LEAVING GROUP 审中-实审
公开(公告)号：EP4116282A1
公开(公告)日：2023-01-11
申请号：EP21764165.3
申请日：2021-03-02
申请人： National University Corporation Hokkaido University
发明人： ITO, Hajime , KUBOTA, Koji
IPC分类号： C07C1/32 , C07C15/20 , C07C25/22 , C07C41/30 , C07C43/205 , C07C209/68 , C07C211/45 , C07D333/16 , C07D333/18 , C07D333/56 , C07C17/26 , C07B61/00
摘要： Disclosed is a method for producing a mono-cross-coupled aromatic compound (3-1) having one less leaving group than an aromatic compound (1) having at least two leaving groups, the method comprising: preparing the aromatic compound (1) having at least two leaving groups; preparing a compound (2) capable of undergoing a cross-coupling reaction selected from an aromatic boronic acid (2-1), an aromatic amino compound (2-2), a diboronic acid ester (2-3), an aromatic compound (2-4) having a hydroxyl group and an aromatic compound (2-5) having a thiol group; and performing a cross-coupling reaction of the aromatic compound (1) having at least two leaving groups with the compound (2) in the presence of a palladium catalyst and a base, in the absence of a solvent.

37. 发明公开

EP3802471A1 SYNTHESIS OF E,E-FARNESOL, FARNESYL ACETATE AND SQUALENE FROM FARNESENE VIA FARNESYL CHLORIDE 审中-公开
公开(公告)号：EP3802471A1
公开(公告)日：2021-04-14
申请号：EP19733346.1
申请日：2019-06-07
申请人： Amyris, Inc.
发明人： FISHER, Karl Joseph , WOOLARD, Frank Xavier
IPC分类号： C07C17/093 , C07C29/128 , C07C67/10 , C07C209/60 , C07C1/32 , C07C315/00 , C07C315/04

38. 发明公开

EP3733678A1 METHOD FOR SYNTHESIZING ORGANIC MAGNESIUM COMPOUND, METHOD FOR SYNTHESIZING ORGANIC BORIC ACID COMPOUND, AND COUPLING METHOD 审中-公开
公开(公告)号：EP3733678A1
公开(公告)日：2020-11-04
申请号：EP18897718.5
申请日：2018-12-27
申请人： Kobelco Eco-Solutions Co., Ltd , National University Corporation Okayama University
发明人： MURAKAMI Yoshiaki , FUKUSHIMA Miyuki , TAKAI Kazuhiko , ASAKO Sobi
IPC分类号： C07F3/02 , C07C1/32 , C07C15/27 , C07F5/02 , C07B61/00
摘要： An object is to establish a technology with which an organic magnesium compound can be easily and efficiently synthesized at a low cost with few steps that do not involve a complex chemical method. A method for synthesizing an organic magnesium compound includes, in a reaction solvent, reacting an organic halide represented by General Formula I (R a -X a ) with a dispersion product obtained by dispersing sodium in a dispersion solvent to obtain an organic sodium compound represented by General Formula II (R a -Na), and reacting the obtained organic sodium compound with a magnesium halide represented by General Formula III (Mg-(X b ) 2 ) to obtain an organic magnesium compound represented by General Formula IV (R a -Mg-X b ).

39. 发明授权

EP2898945B1 CATALYST USING PD-RU SOLID-SOLUTION-TYPE ALLOY PARTICLES 有权
公开(公告)号：EP2898945B1
公开(公告)日：2020-09-02
申请号：EP13838282.5
申请日：2013-09-18
申请人： Japan Science and Technology Agency
发明人： KITAGAWA, Hiroshi , KUSADA, Kohei , NAGAOKA, Katsutoshi , SATO, Katsutoshi , KUTUBI, Md. Shahajahan
IPC分类号： B01J23/46 , B01D53/94 , B22F1/00 , B22F9/24 , C07C1/32 , C07C15/14 , C07B61/00 , B01J23/44 , B01J37/16 , B82Y30/00 , B01J35/00 , C07B37/04

40. 发明公开

EP3487619A1 SURFACE-MODIFIED CALCIUM CARBONATE AS CARRIER FOR TRANSITION METAL-BASED CATALYSTS 有权
公开(公告)号：EP3487619A1
公开(公告)日：2019-05-29
申请号：EP17739291.7
申请日：2017-07-17
申请人： Omya International AG
发明人： GANE, Patrick A.C. , RENTSCH, Samuel , WELKER, Matthias
IPC分类号： B01J27/232 , B01J35/10 , B01J37/28 , B01J37/02 , B01J35/00 , B01J31/02 , C07C1/32 , C07B37/04 , C07C29/60 , C07C29/00 , C09C1/02 , B01J37/08 , B01J37/00

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