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31. 发明公开

EP1577278A1 Dielectric ceramic composition, multilayer ceramic capcitor and method for manufacturing the same 审中-公开
标题翻译：的介电陶瓷组合物，叠层电容器和制造过程
公开(公告)号：EP1577278A1
公开(公告)日：2005-09-21
申请号：EP05005596.1
申请日：2005-03-15
申请人： TDK Corporation
发明人： Iguchi, Toshihiro , Hara, Haruya , Ito, Kazushige , Sato, Akira , Sato, Shigeki , Kojima, Takashi
IPC分类号： C04B35/468 , H01G4/12 , H01G4/30
CPC分类号： C04B35/4682 , C04B35/62665 , C04B35/6303 , C04B35/64 , C04B2235/3205 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3239 , C04B2235/3241 , C04B2235/3249 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3436 , C04B2235/3454 , C04B2235/6565 , C04B2235/6582 , C04B2235/6584 , C04B2235/6588 , C04B2235/662 , H01G4/1227 , H01G4/30
摘要： A dielectric ceramic composition contains components, with respective numbers of moles relative to 100 moles of barium titanate, including barium titanate, a first sub-component containing at least one oxide selected from a Mg oxide, a Ca oxide, a Ba oxide, and Sr oxide, a second sub-component containing an oxide containing 1 mol of Si atoms per mol, a third sub-component containing at least one oxide selected from a V oxide, a Mo oxide, and a W oxide, a fourth sub-component containing at least one R 1 oxide (wherein R 1 is at least one selected from Sc, Er, Tm, Yb, and Lu), a fifth sub-component containing at least one R 2 oxide (wherein R 2 is at least one selected from Y, Dy, Ho, Tb, Gd, and Eu), a sixth sub-component containing at least one selected from a Mn oxide and a Cr oxide, and a seventh sub-component containing at least one selected from calcium zirconate and a mixture of a Ca oxide and Zr oxide. The ratio (A/B) of the number of moles A of the second sub-component to the total number of moles B of the fourth and fifth sub-components is 0.7 or more. Alternatively, the ratio (C/D) of the number of moles C of Si atoms in the second sub-component to the total number of moles of the atoms in the first to seventh sub-components excluding the Si atoms and oxygen atoms being 0.2 or more, and the total number of moles of the fourth and fifth sub-components being 3 or more.

32. 发明授权

EP1786005B1 Dielectric ceramic composition, electronic device, and multilayer ceramic capacitor 有权
标题翻译：介电陶瓷组合物，电子组件和多层陶瓷电容器
公开(公告)号：EP1786005B1
公开(公告)日：2011-04-06
申请号：EP06023375.6
申请日：2006-11-09
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira , Yoshii, Akitoshi , Okabe, Masayuki , Takeda, Atsushi , Shinkawa, Takai
IPC分类号： H01G4/12
CPC分类号： H01G4/1209 , H01G4/1227 , H01G4/30 , Y10T428/252 , Y10T428/256 , Y10T428/258 , Y10T428/2991

35. 发明授权

EP1630831B1 Electronic device and the production method 有权
标题翻译：一种电子装置及其制造方法
公开(公告)号：EP1630831B1
公开(公告)日：2009-02-18
申请号：EP05018884.6
申请日：2005-08-31
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira
IPC分类号： H01G4/08
CPC分类号： H01G4/08 , Y10T29/417 , Y10T29/43 , Y10T29/435 , Y10T29/49163 , Y10T29/49206

36. 发明公开

EP1710818A3 Electronic device, dielectric ceramic composition and the production method 有权
标题翻译：一种电子装置，用于制备介电陶瓷组合物和方法
公开(公告)号：EP1710818A3
公开(公告)日：2007-11-21
申请号：EP06006910.1
申请日：2006-03-31
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira
IPC分类号： H01G4/12 , C04B35/46
CPC分类号： H01G4/1227 , B32B2311/22 , C04B35/4682 , C04B35/62685 , C04B35/628 , C04B35/62813 , C04B35/6303 , C04B35/64 , C04B2235/3203 , C04B2235/3205 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3249 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3409 , C04B2235/3418 , C04B2235/3436 , C04B2235/3454 , C04B2235/6582 , C04B2235/6584 , C04B2235/6588 , C04B2235/663 , C04B2237/346 , C04B2237/405 , H01G4/30 , Y10T428/2993
摘要： A dielectric ceramic composition comprising a main component including barium titanate and an oxide of A1, wherein the dielectric ceramic composition includes a plurality of dielectric particles, concentration of A1 in each of the dielectric particles becomes lower from a particle surface to inside thereof, and each of the dielectric particles has an Al non-dispersed region substantially not including Al at least at a center portion of the particle.

37. 发明公开

EP1792880A1 Dielectric ceramic composition, electronic device, and multilayer ceramic cpacitor 有权
标题翻译：介电陶瓷组合物，电子器件和多层陶瓷电容器
公开(公告)号：EP1792880A1
公开(公告)日：2007-06-06
申请号：EP06024720.2
申请日：2006-11-29
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira , Yoshii, Akitoshi , Okabe, Masayuki , Takeda, Atsushi , Shinkawa, Takaki
IPC分类号： C04B35/468 , H01G4/12
CPC分类号： H01G4/1227 , C04B35/468 , C04B35/6262 , C04B35/62675 , C04B35/62685 , C04B35/62805 , C04B35/62807 , C04B35/638 , C04B2235/3203 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3236 , C04B2235/3239 , C04B2235/3248 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3409 , C04B2235/3418 , C04B2235/3436 , C04B2235/3454 , C04B2235/6562 , C04B2235/6567 , C04B2235/6582 , C04B2235/6584 , C04B2235/6588 , C04B2235/663 , C04B2235/78 , C04B2235/785 , H01G4/30
摘要： A dielectric ceramic composition comprised of at least dielectric particles having barium titanate as its main ingredient, wherein the ratio of dielectric particles having a surface diffusion structure comprised of a main ingredient phase comprised of the main ingredient and a diffusion phase present around the main ingredient phase with respect to said dielectric particles is 60% or more and the ratio of dielectric particles having a domain in the main ingredient phase with respect to the dielectric particles having the surface diffusion structure is 20% or less. According to the present invention, a dielectric ceramic composition and electronic device realizing good high temperature accelerated life can be provided.
摘要翻译： 1。一种电介质陶瓷组合物，其特征在于，至少由以钛酸钡为主要成分的电介质粒子构成，具有由主成分构成的主成分相和主成分相周围的扩散相构成的表面扩散结构的电介质粒子的比例相对于所述电介质粒子的比例为60％以上，具有主成分相的畴的电介质粒子相对于具有表面扩散结构的电介质粒子的比例为20％以下。根据本发明，可以提供实现良好的高温加速寿命的介电陶瓷组合物和电子器件。

38. 发明公开

EP1786005A1 Dielectric ceramic composition, electronic device, and multilayer ceramic capacitor 有权
标题翻译： Ker ator ator ung ung ung ung ator ator ator ator ator ator ator ator ator ator ator ator ator ator
公开(公告)号：EP1786005A1
公开(公告)日：2007-05-16
申请号：EP06023375.6
申请日：2006-11-09
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira , Yoshii, Akitoshi , Okabe, Masayuki , Takeda, Atsushi , Shinkawa, Takai
IPC分类号： H01G4/12
CPC分类号： H01G4/1209 , H01G4/1227 , H01G4/30 , Y10T428/252 , Y10T428/256 , Y10T428/258 , Y10T428/2991
摘要： A dielectric ceramic composition including dielectric particles comprising a main ingredient phase having barium titanate as its main ingredient and a diffusion phase present at the periphery of said main ingredient phase, wherein when an average value of the depth where sub ingredient elements present at said diffusion phase diffuses from a surface of said diffusion phase toward a center of said dielectric particle is designated as an average diffusion depth, a dispersion of the average diffusion depth among the dielectric particles is, in terms of CV value, 5 to 30%. According to the present invention, an electronic device excellent in all of the dielectric constant, high temperature accelerated life, TC bias, and IR temperature dependency can be provided. The CV value corresponding to an average diffusion depths in 30 particles. The element which diffuse into the dielectric particle being Yb, Mg and Ca.
摘要翻译： 1.一种电介质陶瓷组合物，其特征在于，包括以主要成分相为主成分相的电介质粒子，所述主成分相以钛酸钡为主要成分，所述主成分相的周围存在扩散相，其中，在所述扩散相中存在次成分元素的深度的平均值从所述扩散相的表面朝向所述介电粒子的中心扩散为平均扩散深度，以CV值计，介电粒子的平均扩散深度的分散度为5〜30％。根据本发明，可以提供所有介电常数，高温加速寿命，TC偏压和IR温度依赖性优异的电子器件。对应于30个颗粒的平均扩散深度的CV值。扩散到电介质颗粒中的元素是Yb，Mg和Ca。

39. 发明公开

EP1710817A2 Electronic device, dielectric ceramic composition, and method of production of the same 有权
标题翻译：一种电子装置，用于制备介电陶瓷组合物和方法
公开(公告)号：EP1710817A2
公开(公告)日：2006-10-11
申请号：EP06006909.3
申请日：2006-03-31
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira
IPC分类号： H01G4/12 , C04B35/46
CPC分类号： H01G4/1227 , B32B2311/22 , C04B35/4682 , C04B35/6303 , C04B35/64 , C04B2235/3203 , C04B2235/3205 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3224 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3249 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3409 , C04B2235/3418 , C04B2235/3436 , C04B2235/3454 , C04B2235/6582 , C04B2235/6584 , C04B2235/6588 , C04B2235/663 , C04B2235/72 , C04B2235/79 , C04B2237/346 , C04B2237/405 , H01G4/30
摘要： A dielectric ceramic composition having at least a main component including barium titanate, a first subcomponent including at least one type of compound selected from MgO, CaO, BaO, and SrO, a second subcomponent including at least one type of compound selected from Al 2 O 3 , Li 2 O, and B 2 O 3 , a third subcomponent including at least one type of compound selected from V 2 O 5 , MoO 3 , and WO 3 , a fourth subcomponent including an oxide of R1 (where R1 is at least one type of element selected from Sc, Er, Tm, Yb, and Lu), and a fifth subcomponent including CaZrO 3 or CaO+ZrO 2 .
摘要翻译：具有的介电陶瓷组合物，至少一个主部件，包括钛酸钡，第一副成分，包含由MgO，CaO的，BaO和的SrO，第二副成分，包含选自Al 2 O中选择的至少一种类型的化合物中选择的至少一种类型的化合物 3，Li 2 O的，和B 2 O 3，第三副成分，包含选自V 2 O 5，的MoO 3中的至少一种类型的化合物，和WO 3，第四副成分，包含于R1（的氧化物，其中R 1是至少一种元素选自Sc，铒，铥，Yb和Lu中选择），和第五副成分，包含CaZrO.sub.3或CaO + ZrO 2的。

40. 发明公开

EP1648002A1 Ceramic electronic device and production method thereof 有权
标题翻译： Elektronische keramische Vorrichtung und Verfahren zur Herstellung
公开(公告)号：EP1648002A1
公开(公告)日：2006-04-19
申请号：EP05022292.6
申请日：2005-10-12
申请人： TDK Corporation
发明人： Ito, Kazushige , Sato, Akira
IPC分类号： H01G4/10
CPC分类号： H01G4/1218
摘要： A highly reliable ceramic electronic device having an excellent temperature characteristic of a capacitance and a low IR temperature dependency, comprising a dielectric layer: wherein the dielectric layer includes a main component expressed by a composition formula of Ba m TiO 2+m , wherein "m" satisfies 0.995 ≤ m ≤ 1.010 and a ratio of Ba and Ti satisfies 0.995 ≤ Ba/Ti ≤ 1.010, and, as subcomponents, an oxide of Al and an oxide of Si or an oxide of R, R is at least one kind selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and includes a secondary phase composed of at least a part of the oxide of Al and at least a part of the oxide of Si or the oxide of R and being different from a main phase mainly composed of the main component; and the production method are provided.
The first pre preliminarly fired powder contains as main component material (BaTiO 3 ) and subcomponent MgO, V 2 O 5 , MnCO 3 and CaZrO 3 .
摘要翻译：一种具有优异的电容温度特性和低IR温度依赖性的高可靠性陶瓷电子器件，包括电介质层：其中介电层包括由组成式Ba m TiO 2 + m表示的主要成分，其中“m “满足0.995‰‰‰1.010，Ba和Ti的比例满足0.995‰¤Ba / Ti‰¤1.010，作为次要成分，Al的氧化物和Si的氧化物或R，R的氧化物处于选自Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Lu中的至少一种; 并且包括由Al的氧化物和Si的氧化物的至少一部分或R的氧化物的至少一部分构成的二次相，并且与主要由主要成分构成的主相不同; 并提供制造方法。第一次预先焙烧的粉末包含主要成分（BaTiO 3）和次要组分MgO，V 2 O 5，MnCO 3和CaZrO 3。

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