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    • 31. 发明公开
    • EXTRUSION BLOW MOLDED ARTICLES
    • 通过挤出生产的条
    • EP1590160A1
    • 2005-11-02
    • EP04706980.2
    • 2004-01-30
    • EASTMAN CHEMICAL COMPANY
    • PECORINI, Thomas, JosephTURNER, Sam, RichardCONNELL, Gary, Wayne
    • B29C49/00C08G63/60
    • B29C49/0005B29C49/04B29K2067/00B29L2031/7126C08G63/199Y10T428/1352
    • Disclosed is a process for the manufacture of shaped articles by extrusion blow molding comprising the steps of (1) extruding a copolyester through a die to form a tube of molten copolyester; (2) positioning a mold having the desired finished shape around the tube of molten copolyester; and (3) introducing a gas into the tube of molten copolyester, causing the extrudate to stretch and expand to fill the mold; wherein the copolyester is a linear, copolyester having an inherent viscosity (IV) of at least 0.7 dL/g measured at a temperature of 25°C at 0.25 g/dl concentration in a solvent mixture of symmetric tetrachloroethane and phenol having a weight ratio of symmetric tetrachloroethane to phenol of 2:3 and comprising: (1) a diacid component consisting essentially of 90 to 100 mole percent terephthalic acid residues and 0 to 10 mole percent isophthalic acid residues, naphthalenedicarboxylic acid residues, biphenyldicarboxylic acid residues or a combination of 2 or more of isophthalic, naphthalenedicarboxylic or bipheyldicarboxylic acid residues; and (2) a diol component consisting essentially of 70 to 90 mole percent 1,4-cyclohexanedimethanol residues and 30 to 10 mole percent neopentyl glycol residues; wherein the copolyester comprises 100 mole percent diacid component and 100 mole percent diol component. The process is particularly useful for the manufacture of bottles or carboys having and interior volume of 2 to 50 liters.
    • 34. 发明公开
    • POLYESTER COMPOSITIONS WHICH COMPRISE SPIRO-GLYCOL, CYCLOHEXANEDIMETHANOL, AND TEREPHTHALIC ACID
    • POLYESTERZUSAMMENSETZUNGEN,DIE SPIROGLYKOL,CYCLOHEXANDIMETHANOL UNDTEREPHTHALSÄUREENTHALTEN
    • EP2358786A1
    • 2011-08-24
    • EP09795586.8
    • 2009-12-17
    • Eastman Chemical Company
    • CRAWFORD, Emmett, DudleyCONNELL, Gary, Wayne
    • C08G63/66C08G63/672
    • C08G63/199
    • The inventions relate to polyester compositions comprising at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 80 to about 10O mole % of terephthalic acid residues; (ii) about 0 to about 20 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a glycol component comprising: (i) about 1 to about 49 mole % spiro-glycol residues; and (ii) about 51 to about 99 mole % at least one glycol chosen from at least one of 1,4-cyclohexanedimethanol residues and 2,2,4,4-tetramethyl-i,3-cyclobutanediol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.
    • 描述为本发明的一个方面是包含至少一种聚酯的聚酯组合物,其包含:(a)二羧酸组分,其包含:(i)约80至约100摩尔%的对苯二甲酸残基; (ii)约0至约20摩尔%的具有至多20个碳原子的芳族和/或脂族二羧酸残基; 和(b)二醇组分,其包含:(i)约1至约49摩尔%的螺二醇残基; 和(ii)约51至约99摩尔%的至少一种选自1,4-环己烷二甲醇残基和2,2,4,4-四甲基-1,3-环丁二醇残基中的至少一种的二醇; 其中二羧酸组分的总摩尔%为100摩尔%,其中二醇组分的总摩尔%为100摩尔%。