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31. 发明公开

EP2147934A1 Process to make a composition comprising a monovinylaromatic polymer and a polymer made from renewable resources 审中-公开
标题翻译：一种用于制备单乙烯基芳族聚合物的组合物和由可再生资源制成的聚合物的方法
公开(公告)号：EP2147934A1
公开(公告)日：2010-01-27
申请号：EP08161165.9
申请日：2008-07-25
申请人： Total Petrochemicals France
发明人： Duc, Michel , Lodefier, Philippe
IPC分类号： C08F2/00 , C08F2/44 , C08L25/00 , C08L67/00 , C08F283/02 , C08L51/08 , C08F295/00
CPC分类号： C08L25/02 , C08F279/02 , C08F287/00 , C08L9/00 , C08L51/006 , C08L51/04 , C08L51/08 , C08L53/025 , C08L67/04 , C08L2666/02
摘要： The present invention is a process to make a composition comprising at least a monovinylaromatic polymer and at least a dispersed phase of one or more polymers made from renewable resources comprising :
a) forming a polymerizable mixture comprising :
at least a monomer or a dimer (a1) selected among an hydroxy carboxylic acid, a precursor of said hydroxy carboxylic acid, a cyclic component polymerizable by ring-opening polymerization (ROP) and a mixture of an epoxide and carbon dioxide,
dispersed in at least (a2) one monovinylaromatic monomer,
optionally a rubber dissolved in (a2) the monovinylaromatic monomer,

b) contacting an appropriate catalyst with the polymerizable solution at conditions effective to produce a polymer A1 comprising the repeating units (a1) dispersed in the (a2) monovinylaromatic monomer,
c) polymerizing through a radical pathway the solution obtained at step b) optionally in the presence of a free radical initiator, optionally in the presence of chain transfer agents,
d) degassing the product of step c) to separate the optional unpolymerized monomers and comonomers and recovering a composition comprising at least a (A2) monovinylaromatic polymer and at least (A1) wherein, the weight proportion A1/(A2+A1) is up to 50%.
In a second embodiment steps b) and c) are made in one step. The polymerizable mixture is contacted with an appropriate catalyst at conditions effective to essentially simultaneously produce a polymer A1 and a monovinylaromatic polymer.
(a1) is advantageously a lactide. The monovinylaromatic monomer is advantageously styrene.
摘要翻译：本发明是一种方法，使一组合物，其包含至少一个单乙烯基芳族聚合物和由可再生资源包括由一种或多种聚合物的至少一个分散相：a）形成聚合混合物，包括：至少一个单体或二聚物（A1 （）在羟基羧酸中选择的所述的羟基羧酸，通过开环聚合ROP的环状组分聚合）和环氧化物和二氧化碳的混合物的前体，分散在至少（a2）的一种单乙烯基芳香族单体，任选在（a2）中的单乙烯基芳族单体中溶解橡胶，b）在有效产生聚合物A1包含分散在（a2）中单乙烯基芳族单体的重复单元（a1）条件下，使与所述可聚合溶液适当的催化剂，c）通过一个聚合自由基途径在步骤b中得到的溶液）任选地在自由基引发剂的存在下，任选地在链转移Ag的存在已废除，D）对步骤c）的产物，以可选的未聚合的单体和共聚单体中分离和回收包含至少一个（A2的组合物）单乙烯基芳族聚合物和至少（A1）worin，重量比例A1 /（A2 + A1）高达50％。在第二个实施例的步骤b）和c）在一个步骤中制成。可聚合的混合物用在适当的催化剂接触，在有效地产生聚合物基本上同时A1和单乙烯基芳族聚合物的条件。（A1）有利地为丙交酯。所述单乙烯基芳族单体是苯乙烯有利。

32. 发明公开

EP2000450A1 Regeneration and stabilization of dehydrogenation catalyst 审中-公开
标题翻译： Regenerierung und Stabilisierung eines Dehydrierungskatalysators
公开(公告)号：EP2000450A1
公开(公告)日：2008-12-10
申请号：EP07290697.7
申请日：2007-06-05
申请人： Total Petrochemicals France
发明人： Leroux, Patrice
IPC分类号： C07C5/333 , C07C15/44 , C07C15/46
CPC分类号： C07C5/3332 , C07C2523/04 , C07C2523/745 , C07C2523/78 , C07C15/44 , C07C15/46
摘要： The present invention relates to a process for catalytically converting an alkylaromatic hydrocarbon into a vinylaromatic hydrocarbon by directing said alkylaromatic hydrocarbon and steam into a reactor containing dehydrogenation catalyst, said process comprising the steps of:
(a) forming a mixed reactant stream consisting essentially of said alkylaromatic hydrocarbon and steam;
(b) bringing said mixed reactant stream into contact with a dehydrogenation catalyst consisting essentially of iron oxide catalyst promoted with alkali metal and at conditions effective to convert at least a portion of the alkylaromatic hydrocarbon to vinylaromatic hydrocarbon;

wherein an effective amount of an alkali metal compound in the form of a powder is injected continuously or intermittently in at least one of the feedstocks sent to the dehydrogenation catalyst; said effective amount of alkali metal compound being sufficient to maintain substantially constant levels of conversion of alkylaromatic hydrocarbon and selectivity of vinylaromatic hydrocarbon.
摘要翻译：本发明涉及通过将所述烷基芳族烃和蒸汽引入含有脱氢催化剂的反应器中将烷基芳族烃催化转化为乙烯基芳族烃的方法，所述方法包括以下步骤：（a）形成基本上由所述烷基芳烃和蒸汽; （b）使所述混合反应物流与基本上由碱金属促进的氧化铁催化剂组成的脱氢催化剂接触，并且在有效将至少一部分烷基芳烃转化为乙烯基芳烃的条件下进行; 其中将有效量的粉末形式的碱金属化合物连续地或间歇地注入到送至脱氢催化剂的至少一种原料中; 所述有效量的碱金属化合物足以保持烷基芳族烃的转化率基本上恒定且乙烯基芳族烃的选择性。

33. 发明公开

EP1975201A1 Monovinylaromatic polymer composition comprising a polymer made from renewable resources as a dispersed phase 审中-公开
标题翻译：包括来自可再生资源作为分散相由聚合物单乙烯基芳族聚合物组合物
公开(公告)号：EP1975201A1
公开(公告)日：2008-10-01
申请号：EP07290396.6
申请日：2007-03-30
申请人： Total Petrochemicals France
发明人： Duc, Michel
IPC分类号： C08L25/00 , C08L67/04 , C08L51/08 , C08F283/02 , C08F2/44
CPC分类号： C08L67/04 , C08F279/02 , C08F283/02 , C08F2438/02 , C08L25/00 , C08L25/06 , C08L51/08 , C08L2205/03 , C08F212/08 , C08L2666/04 , C08L2666/24 , C08L2666/14 , C08L2666/18 , C08L2666/02
摘要： The present invention concerns a monovinylaromatic polymer composition comprising a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase wherein said bio-courced polymer dispersed phase is predominantly made of particles having a size of less than 10 µm.
The present invention also relates to a process (hereunder referred as the first process) to make said monovinylaromatic polymer composition, said process comprising admixing :
a monovinylaromatic monomer,
at least one bio-sourced polymer,
optionally a rubber,
at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer of the bio-sourced polymer and monovinylaromatic polymer.
The present invention also relates to a process (hereunder referred as the second process) to make said monovinylaromatic polymer composition, said process comprising admixing :
a monovinylaromatic monomer,
functionalized bio-sourced polymer-s), or mixtures of bio-sourced polymer (s)and functionalized bio-sourced polymer(s),
optionally a rubber,
at conditions effective to polymerize at least a part of the monovinylaromatic monomer.
The present invention also relates to a process (hereunder referred as the third process) to make said monovinylaromatic polymer composition, said process comprising blending in the molten state functionalized bio-sourced polymer(s) (or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s)) with monovinylaromatic polymer, said monovinylaromatic polymer comprising optionally a rubber.
摘要翻译：本发明涉及单乙烯基芳族聚合物组合物，包含生物来源的聚合物分散相和任选的橡胶分散相worin所述生物courced聚合物分散相主要由具有大小小于10微米的颗粒组成。因此，本发明涉及的处理（由下文中称为第一处理），以使所述单乙烯基芳族聚合物组合物，所述方法包括将单乙烯基芳族单体，至少一种生物来源的聚合物，任选的橡胶，在有效地聚合在至少单乙烯基芳族单体的一部分，并产生所述生物来源的聚合物和单乙烯基芳族聚合物的相容剂。因此，本发明涉及的处理（由下文中称为第二工艺），以使所述单乙烯基芳族聚合物组合物，所述方法包括将单乙烯基芳族单体，官能化的生物来源的聚合物-S），或生物来源的聚合物的混合物（S ）和官能化的生物来源的聚合物（S），任选的橡胶，在有效条件下聚合至少单乙烯基芳族单体的一部分。因此，本发明涉及的处理（由下文中称为第三方法），以使所述单乙烯基芳族聚合物组合物，所述方法包括熔融状态官能化的生物来源的聚合物（S）在混合（或者生物来源的聚合物的混合物（S）和官能化的生物来源的聚合物（S））与单乙烯基芳族聚合物，所述单乙烯基芳族聚合物任选地包含橡胶。

34. 发明授权

EP1326872B1 LIGANDS AVEC AU MOINS UN SUBSTITUANT FLUOROSILICONE UTILISABLES POUR LA PREPARATION DE METALLOCENES 有权
标题翻译：配体与至少一个氟取代基用于生产金属茂
公开(公告)号：EP1326872B1
公开(公告)日：2006-03-01
申请号：EP01963049.0
申请日：2001-08-02
申请人： TOTAL PETROCHEMICALS FRANCE
发明人： CHERON, Virginie , COUTURIER, Jean-Luc , HAGEN, Hendrik , VAN KOTEN, Gerard , DEELMAN, Berth, Jan
IPC分类号： C07F17/00 , C07F7/08 , C08F2/06 , C08F4/642
CPC分类号： C07F17/00 , C07F7/0818 , Y10S526/943
摘要： The invention concerns ligands with at least a fluorosilicone substituent of general formulae (I) and (II); a method for preparing them and their use for producing catalysts useful for olefin polymerisation.

35. 发明授权

EP2125904B1 PROCESS FOR PREPARING HIGH IMPACT MONOVINYLAROMATIC POLYMERS IN THE PRESENCE OF A BORANE COMPLEX 有权
标题翻译：用于生产单乙烯基高耐冲击性芳香族聚合物使用一个复杂BORAN
公开(公告)号：EP2125904B1
公开(公告)日：2011-11-23
申请号：EP08708031.3
申请日：2008-01-21
申请人： Total Petrochemicals France , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
发明人： DUC, Michel , VUILLEMIN, Bruno , BERTIN, Denis , MARQUE, Sylvain , GALINDO, Christophe
IPC分类号： C08F279/02 , C08F4/52
CPC分类号： C08F257/02 , C08F279/02
摘要： The present invention relates to a process for preparing a high impact monovinylaromatic polymer comprising admixing a rubber, at least one monovinylaromatic monomer and optionally one or more comonomer in the presence of at least a borane complex of the L-BH3 type wherein L is a Lewis base and polymerizing the monovinylaromatic monomer. The borane complex initiator, L may be an ether (e.g THF, tetrahydrofurane), a thioether (e.g dimethylthioether) or an amine. A preferred complex is an amine borane such as by way of example triethylamine borane. The present invention also relates to a high impact monovinylaromatic polymer having a weight ratio of grafted monovinylaromatic monomer and optional comonomer to the initial monovinylaromatic monomer and optional comonomer above 0.1 %, advantageously above 2% and preferably in the range 2 to 4 %. The invention is of particular interest to make high impact polystyrene.

36. 发明公开

EP2155635A1 REGENERATION AND STABILIZATION OF DEHYDROGENATION CATALYST 审中-公开
标题翻译：再生与脱水催化剂的稳定化
公开(公告)号：EP2155635A1
公开(公告)日：2010-02-24
申请号：EP08760253.8
申请日：2008-05-30
申请人： Total Petrochemicals France
发明人： LEROUX, Patrice
IPC分类号： C07C5/333 , C07C15/44 , C07C15/46
CPC分类号： C07C5/3332 , C07C2523/04 , C07C2523/745 , C07C2523/78 , C07C15/44 , C07C15/46
摘要： The present invention relates to a process for catalytically converting an alkylaromatic hydrocarbon into a vinylaromatic hydrocarbon by directing said alkylaromatic hydrocarbon and steam into a reactor containing dehydrogenation catalyst, said process comprising the steps of: (a) forming a mixed reactant stream consisting essentially of said alkylaromatic hydrocarbon and steam; (b) bringing said mixed reactant stream into contact with a dehydrogenation catalyst consisting essentially of iron oxide catalyst promoted with alkali metal and at conditions effective to convert at least a portion of the alkylaromatic hydrocarbon to vinylaromatic hydrocarbon; wherein an effective amount of an alkali metal compound in the form of a powder is injected continuously or intermittently in at least one of the feedstocks sent to the dehydrogenation catalyst; said effective amount of alkali metal compound being sufficient to maintain substantially constant levels of conversion of alkylaromatic hydrocarbon and selectivity of vinylaromatic hydrocarbon.

37. 发明公开

EP2067749A1 Process for purification of an aqueous phase containing polyaromatics 审中-公开
标题翻译： Verfahren zur Reinigung einerwässrigenPhase mit Polyaromatika
公开(公告)号：EP2067749A1
公开(公告)日：2009-06-10
申请号：EP07291442.7
申请日：2007-11-29
申请人： Total Petrochemicals France
发明人： Dernoncourt, Renaud
IPC分类号： C02F1/26 , C02F1/20
CPC分类号： C02F1/26 , B01D11/0492 , B01D17/0208 , B01D17/047 , C02F1/20 , C02F2101/327 , C02F2103/36 , C02F2103/38 , C07C5/333 , C07C15/46
摘要： The present invention is a process for purifying a liquid stream comprising an aqueous phase and optionally an organic phase,
said aqueous phase comprising polyaromatics in solution in water,
wherein,
a) said liquid stream is sent to a mixing tank in which is introduced an effective amount of an aromatic component, advantageously ethylbenzene or benzene or toluene or mixture thereof to produce a mixture of an organic phase and of an aqueous phase,
b) then said mixture recovered at step a) is sent to a decanter to recover a clean aqueous phase and an organic phase.
According to a specific embodiment the stream sent to step a) is the whole or a fraction of the aqueous phase recovered by condensation of the effluent gas leaving an ethylbenzene dehydrogenation reactor.
摘要翻译：本发明是一种净化包含水相和任选的有机相的液体流的方法，所述水相包括在水中的溶液中的多芳族化合物，其中a）将所述液体物流送入混合罐中，其中引入有效的芳族组分的量，有利地是乙苯或苯或甲苯或其混合物以产生有机相和水相的混合物，b）然后将在步骤a）回收的所述混合物送入滗析器以回收清洁的水相和有机相。根据具体实施方案，送至步骤a）的流是通过离开乙苯脱氢反应器的流出气体的冷凝回收的全部或一部分水相。

38. 发明公开

EP1954705A2 COMPLEXE METALLOCENE BOROHYDRURE D UN LANTHANIDE, SYSTEME CATALYTIQUE L INCORPORANT, PROCEDE DE POLYMERISATION L UTILISANT ET COPOLYMERE ETHYLENE/BUTADIENE OBTENU PAR CE PROCEDE 有权转让
标题翻译：硼氢化金属茂络合物一镧系元素，催化系统，这个复杂的包括聚合作为此被使用，并且使用这种方法GOT乙烯丁二烯共聚物
公开(公告)号：EP1954705A2
公开(公告)日：2008-08-13
申请号：EP06818328.4
申请日：2006-10-31
申请人： Société de Technologie Michelin , Michelin Recherche et Technique S.A. , Total Petrochemicals France , Centre National de la Recherche Scientifique , Ecole Superieure de Chimie Physique Electronique de Lyon
发明人： THUILLIEZ, Julien , BOISSON, Christophe , SPITZ, Roger
IPC分类号： C07F17/00 , C08F4/52 , C08F210/12
CPC分类号： C08F210/02 , C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/52 , C08F236/06
摘要： The invention relates to a borohydride metallocene complex of a lanthanide, the preparation method thereof, a catalytic system including said borohydride metallocene complex, a method for the copolymerisation of olefins using said catalytic system and an ethylene/butadiene copolymer obtained using said method, having butadiene units with 1,2-cyclohexane or 1,2 and 1,4-cyclohexane chains. The inventive complex has one of the following formulas (A and B), wherein, in formula A, two molecules of ligands Cp1 and Cp2 are linked to the lanthanide Ln, such as Nd, said ligand molecules each consisting of a fluorenyl group, and, in formula B, a ligand molecule is linked to the lanthanide Ln, said ligand molecule consisting of two fluorenyl groups Cp1 and Cp2 which are interlinked by means of a bridge P having formula MR1R2, in which M is an element from column IVA, such as Si, and R1 and R2, which may be identical or different, represent an alkyl group having between 1 and 20 carbon atoms. According to the invention, L represents an alkali metal, such as Li, N represents a molecule of a complexing solvent, such as THF, x is an integer or a non-integer which is greater than 0 and p is an integer which is equal to or greater than 1.

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