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    • 21. 发明公开
    • POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
    • 聚合LINK聚合性组合物,聚合物,光学各向异性体及其制造方法的连接可聚合
    • EP2871192A4
    • 2015-12-23
    • EP13816607
    • 2013-05-30
    • ZEON CORP
    • SAKAMOTO KEIKIRIKI SATOSHIOKUYAMA KUMITAIRA KANAKO
    • C07D277/82C07D277/84C07D417/12C07D513/04C08F20/36C08L33/08G02B5/30
    • C07D277/82C07C69/753C07C2601/14C07D277/84C07D417/12C07D513/04C08F20/36C08F20/68C08F22/105C08F22/14C08F22/20C08F22/22C08F22/24C08F22/26C08F26/06C08F28/06C08F2500/26C09K19/0403C09K2019/0414C09K2019/0481G02B5/30G02F2202/40
    • The present invention is a polymerizable compound (I), a polymerizable composition comprising the polymerizable compound and an initiator, a polymer obtained by polymerizing the polymerizable compound or polymerizable composition, an optically anisotropic article comprising the polymer, a carbonyl compound (4), a method for producing a polymerizable compound (I), the method comprising reacting the carbonyl compound (4) with a hydrazine compound, and a method for using the carbonyl compound (4) as a raw material for producing a polymerizable compound (I). According to the present invention, provided is a polymerizable compound or the like that has a practical low melting point, exhibit excellent solubility in a general-purpose solvent, and can produce an optical film that can be produced at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. Also provided is a carbonyl compound or the like that is useful as a raw material for producing the polymerizable compound, a method for producing the polymerizable compound using the carbonyl compound or the like. (In the formula (I), Y 1 to Y 8 represent -C(=O)-O-, or the like, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group or the like, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group that includes at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group or the like, A 1 represents a trivalent aromatic group or the like, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group or the like, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom or the like.)
    • 本发明是一种可聚合化合物(I)中,可聚合组合物包含可聚合化合物,并在引发剂,由包含聚合物聚合光学各向异性体的聚合性化合物或聚合性组合物,羰基化合物而得到的聚合物(4),一 一种产生可聚合化合物(I)的方法,该方法包括使与肼化合物的羰基化合物(4),以及用于使用所述羰基化合物(4)作为原料用于产生可聚合化合物(I)的方法。 。根据本发明,提供了一种可聚合化合物或具有实用熔点低,显示出在通用溶剂的溶解性优异,并且可以在光电影产生并能够以低成本来制造,表现出低的反射亮度等 ,并实现在宽的波长频带的偏振光均匀转换光学各向异性本文,。 所以提供一种羰基化合物或类似物,它们作为制造原料的聚合性化合物,一种使用羰基化合物等的聚合性化合物的方法是有用的。 (在式(I)中,Y 1至Y 8表示-C(= O)-O-,或类似物,G 1和G 2表示二价的C 1-20直链脂肪族基等,Z 1和 Z 2表示C 2-10的链烯基即unsubstituiertem,substituiertem或卤原子,A X darstellt一个C 2-30的有机基团做了包括至少一个芳环的Y darstellt氢原子或C 1-20 烷基或类似物,A 1表示三价芳族基团等,A 2和A 3表示C 3-30二价脂环族烃基或类似物,A 4和A 5表示C 6-30二价芳基 或类似物,和Q 1表示氢原子等。)
    • 22. 发明公开
    • POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
    • 可聚合化合物,可聚合组合物,聚合物,光学各向异性体和生产可聚合化合物的方法
    • EP2871192A1
    • 2015-05-13
    • EP13816607.9
    • 2013-05-30
    • Zeon Corporation
    • SAKAMOTO KeiKIRIKI SatoshiOKUYAMA KumiTAIRA Kanako
    • C08F20/36C07D277/82C07D277/84C07D417/12C07D513/04C08L33/08G02B5/30
    • C07D277/82C07C69/753C07C2601/14C07D277/84C07D417/12C07D513/04C08F20/36C08F20/68C08F22/105C08F22/14C08F22/20C08F22/22C08F22/24C08F22/26C08F26/06C08F28/06C08F2500/26C09K19/0403C09K2019/0414C09K2019/0481G02B5/30G02F2202/40
    • The present invention is a polymerizable compound (I), a polymerizable composition comprising the polymerizable compound and an initiator, a polymer obtained by polymerizing the polymerizable compound or polymerizable composition, an optically anisotropic article comprising the polymer, a carbonyl compound (4), a method for producing a polymerizable compound (I), the method comprising reacting the carbonyl compound (4) with a hydrazine compound, and a method for using the carbonyl compound (4) as a raw material for producing a polymerizable compound (I). According to the present invention, provided is a polymerizable compound or the like that has a practical low melting point, exhibit excellent solubility in a general-purpose solvent, and can produce an optical film that can be produced at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. Also provided is a carbonyl compound or the like that is useful as a raw material for producing the polymerizable compound, a method for producing the polymerizable compound using the carbonyl compound or the like. (In the formula (I), Y 1 to Y 8 represent -C(=O)-O-, or the like, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group or the like, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group that includes at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group or the like, A 1 represents a trivalent aromatic group or the like, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group or the like, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom or the like.)
    • 本发明是可聚合化合物(I),包含可聚合化合物和引发剂的可聚合组合物,通过聚合可聚合化合物或可聚合组合物获得的聚合物,包含该聚合物的光学各向异性制品,羰基化合物(4), 制造聚合性化合物(I)的方法,使羰基化合物(4)与肼化合物反应的方法,以及使用该羰基化合物(4)作为制造聚合性化合物(I)的原料的方法。 根据本发明,提供具有实用的低熔点,在通用溶剂中表现出优异的溶解性,并且可以生产可以以低成本生产的光学膜,并且呈现低反射亮度的可聚合化合物等 并且实现在宽波长带,光学各向异性制品上的均匀偏振光转换。 还提供了用作制备聚合性化合物的原料的羰基化合物等,使用羰基化合物等制造聚合性化合物的方法。 (式(I)中,Y 1〜Y 8表示-C(= O)-O-等,G 1和G 2表示碳原子数1〜20的直链脂肪族基团等,Z 1和Z 2表示碳原子数2〜10 未取代或被卤原子取代的烯基,Ax表示包含至少一个芳环的C2-30有机基团,Ay表示氢原子或C1-20烷基等,A1表示三价芳族基团 A2和A3表示C3-30二价脂环族烃基等,A4和A5表示C6-30二价芳香族基团等,Q1表示氢原子等)。
    • 23. 发明公开
    • POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL
    • POLYMERISIERBARE VERBINDUNG,POLYMERISIERBARE ZUSAMMENSETZUNG,POLYMER SOWIE OPTISCH ANISOTROPES MATERIAL
    • EP2857424A1
    • 2015-04-08
    • EP13796461.5
    • 2013-05-30
    • Zeon Corporation
    • SAKAMOTO KeiOKUYAMA Kumi
    • C08F20/36C07D277/82C07D513/04C08L33/08C09K19/38G02B5/30
    • C08F22/24C07D277/82C07D513/04C08F122/24C08F222/24C08F2222/102C09K19/24C09K19/322C09K19/348C09K19/3486C09K19/3488C09K19/3497C09K19/3852C09K19/3861C09K2019/0448C09K2019/2078G02B1/08G02B5/3016G02B5/3025
    • The present invention relates to : a polymerizable compound (1), wherein Y 1 to Y 6 are a chemical single bond, -O-C(=O)-, -C(=O)-O- or the like, G 1 and G 2 are a divalent aliphatic group having 1 to 20 carbon atoms or the like, Z 1 and Z 2 are an alkenyl group having 2 to 10 carbon atoms that is unsubstituted or substituted with a halogen atom, A x is a fused ring group represented by a formula (II), wherein X is -NR 3 -, an oxygen atom, a sulfur atom or the like, R 3 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and D is a substituted or unsubstituted ring having 1 to 20 carbon atoms that includes at least one nitrogen atom, A y is a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or the like, A 1 is a trivalent aromatic group or the like, A 2 and A 3 are a divalent aromatic group having 6 to 30 carbon atoms or the like, and Q 1 is a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms. The present invention provides a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and an optically anisotropic article.
    • 本发明涉及:可聚合化合物(1),其中Y 1至Y 6为化学单键,-OC(= O) - , - C(= O)-O-等,G 1和G 2为碳原子数1〜20的二价脂肪族基团,Z 1和Z 2为未取代或被卤素原子取代的碳原子数2〜10的烯基,A x为由 式(II)其中X为-NR 3 - ,氧原子,硫原子等,R 3为氢原子或碳原子数为1〜6的烷基,D为取代或未取代的环 具有1至20个碳原子,包括至少一个氮原子,A y是氢原子,具有1至20个碳原子的烷基等,A 1是三价芳族基团等,A 2和A 3 是碳原子数为6〜30的二价芳香族基团,Q 1为氢原子或碳原子数为1〜6的烷基。 本发明提供一种具有实用的低熔点,在通用溶剂中显示优异的溶解性的聚合性化合物,聚合性组合物和聚合物,能够以低成本制造出可以得到均匀转化率的光学膜 在宽波长带上的偏振光,以及光学各向异性物品。