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    • 30. 发明公开
    • Method and arrangement for concentrating hydrogen peroxide
    • Methode und Installation zur Konzentration von Wasserstoffperoxid
    • EP2799122A1
    • 2014-11-05
    • EP14166169.4
    • 2014-04-28
    • Instytut Lotnictwa
    • Rarata, GrzegorzSurmacz, PawelFlorczuk, Wojciech
    • B01D3/10C01B15/013B01D3/08
    • C01B15/013B01D3/085B01D3/10
    • The object of the invention is an arrangement for vacuum distillation of hydrogen peroxide feedstock, comprising in sequence: heating means (1), an axisymmetric distillation flask (2), means (3) for propelling the distillation flask (2) in rotation about its axis, a rectification column (4), a catch-drop (5), a connection of a vacuum pump (6), a condenser (7), an inlet for cooling water (8), a distillate receiver (9), characterised in that the axis of the distillation flask (2) is positioned at an angle of 105° to 140° respect to the rectification column (4), the distillation flask (2) is capable of rotation about its axis and is at least partially placed in the heating means (1), and furthermore the distillation flask (2) comprises an RI sensor for measuring the concentration of hydrogen peroxide. Furthermore, the invention relates to a method for obtaining hydrogen peroxide, especially of HTP class, for propulsion applications, by a two-step process of vacuum distillation, which is performed in the above arrangement for vacuum distillation, comprising: a) step of fractional vacuum distillation, consisting in concentrating the hydrogen peroxide feedstock, and then b) step of vacuum purification of hydrogen peroxide obtained above, consisting in distilling off hydrogen peroxide, preferably having a concentration of above 98%, is conducted, wherein in step a) the rotational distillation flask operates in conditions of about 80 revolutions/minute, at a negative pressure of 7 - 20 mbars and at a water bath temperature of 35 - 55°C, and in step b) the rotational vacuum evaporator operates in conditions of at least 120 revolutions/minute, at a negative pressure of up to 12 mbars and at a water bath temperature of up to 55°C.
    • 本发明的目的是用于真空蒸馏过氧化氢原料的装置,其顺序包括:加热装置(1),轴对称蒸馏烧瓶(2),用于推动蒸馏烧瓶(2)围绕其旋转的装置 精馏塔(4),捕集滴(5),真空泵(6),冷凝器(7),冷却水入口(8),馏出物接收器(9)的连接,其特征在于 因为蒸馏烧瓶(2)的轴线相对于精馏塔(4)以105°至140°的角度定位,所以蒸馏烧瓶(2)能够绕其轴线旋转并且至少部分地放置 在加热装置(1)中,此外,蒸馏瓶(2)包括用于测量过氧化氢浓度的RI传感器。 此外,本发明涉及通过真空蒸馏的上述布置中进行的两步骤的真空蒸馏来获得用于推进应用的特别是HTP类的过氧化氢的方法,包括:a)分级步骤 包括浓缩过氧化氢原料的真空蒸馏,然后b)进行上述获得的过氧化氢的真空净化步骤,其中蒸馏出优选浓度高于98%的过氧化氢,其中在步骤a)中, 旋转蒸馏瓶在约80转/分钟的条件下,在7-20千巴的负压和35-55℃的水浴温度下操作,并且在步骤b)中,旋转式真空蒸发器在至少 120转/分钟,负压达12毫巴,水浴温度高达55℃。