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    • 22. 发明公开
    • Method of processing a silver halide radiographic element
    • Verfahren zur Verarbeitung eines radiographischen Silberhalogenidelementes。
    • EP0559061A2
    • 1993-09-08
    • EP93102834.4
    • 1993-02-24
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • Bucci, MarcoMarchesano, CarloFerrari, DinoIlluminati, Carlo
    • G03C5/26G03C5/16G03C5/38G03C1/005G03C1/047
    • G03C1/0051F02B2075/027G03C5/16G03C5/26G03C5/38Y10S430/164Y10S430/167
    • This invention relates to a method of processing an image-wise exposed silver halide photographic material wherein said method comprises the following steps:

      (a) developing the photographic material for 5 to 15 seconds in an aqueous developing solution,
      (b) fixing the photographic material for 5 to 15 seconds in an aqueous fixing solution, and
      (c) washing the photographic material for 5 to 20 seconds,
         wherein both said developing and fixing solutions are free of gelatin hardeners.

      The method is particularly intended for use in processing radiographic films which:
         comprise a support and silver halide emulsion layer or layers, at least one of said silver halide emulsion layers containing tabular silver halide grains having an average diameter to thickness ratio of at least 3:1 and highly deionized gelatin, and
         show a swelling index lower than 140% and a melting time of from 45 to 120 minutes.
      The method shows the advantages of lower environmental pollution and shorter processing times.
    • 本发明涉及一种处理成像曝光的卤化银照相材料的方法,其中所述方法包括以下步骤:(a)在显影水溶液中显影照相材料5至15秒,(b)将照相材料 在定影液中固定5至15秒,和(c)将照相材料洗涤5至20秒,其中所述显影和定影液均不含明胶固化剂。 该方法特别用于处理放射线照相胶片,其包括载体和卤化银乳剂层,至少一种所述卤化银乳剂层含有平均粒径与厚度之比至少为3:1的片状卤化银颗粒, 1和高度去离子明胶,并且显示低于140%的溶胀指数和45至120分钟的熔融时间。 该方法显示出较低的环境污染和较短的加工时间的优点。
    • 30. 发明公开
    • Method of preparing ultrathin light-sensitive tabular grain emulsions rich in silver bromide
    • 一种用于容纳超薄片状颗粒溴化银乳液的制备过程
    • EP1178353A1
    • 2002-02-06
    • EP01000199.8
    • 2001-06-08
    • Agfa-Gevaert
    • Elst, KathyMans, Ilse
    • G03C1/005G03C1/047
    • G03C1/0051G03C1/047G03C1/07G03C1/46G03C5/16G03C2001/0055G03C2001/0156G03C2001/03511G03C2001/0357G03C2001/03594G03C2005/168G03C2200/03G03C2200/27G03C2200/44G03C2200/60
    • A method has been described of preparing an ultrathin tabular grain emulsion rich in silver bromide, having {111} major faces, wherein tabular grains having a thickness of less than 0.08 µm exhibit an average aspect ratio of more than 5:1 and account for at least 75 %, and more preferably at least 80 %, by number of hexagonal grains and a coefficient of variation on average equivalent surface area of less than 0.50, said process comprising: introducing into a temperature-controlled reaction vessel an aqueous dispersing medium and silver, bromide, and, optionally, iodide and/or chloride, and maintaining pBr values within said reaction vessel during grain nucleation and growth that favors the formation and growth of tabular grains, characterized in that at the time said tabular grains are being formed, (a) pH in said reaction vessel is maintained at a value ranging from 0.8 to 10; (b) a gelatino-peptizer is present in the reaction vessel in a concentration of from 0 to 50 g per liter of said dispersing medium, and (c) pBr within said reaction vessel having a value of at least 1.8 is maintained during grain nucleation, wherein nucleation is performed in a reaction vessel at a temperature in the range from 10-60°C and a pBr value within said reaction vessel is maintained at a value of less than 2.4 during growth, wherein growth is performed in a reaction vessel at a temperature in the range from 40-80°C, and more preferably in the range between 40 and 50°C in order to reach a grain thickness of less than 0.06 µm, provided that a gelatin peptizer which is free from calcium ions and has a methionine content of less than 30 micromoles per gram of gelatino-peptizer is present in said dispersing medium during grain nucleation and growth. Moreover a photographic material comprising an emulsion prepared according to the method of the present invention has been claimed.
    • 的方法已被描述准备超薄片状颗粒乳剂富含溴化银,具有ä111ü主面,worin具有厚度上的超过5平均纵横比小于0时08微米展品的片状颗粒:1和至少占 75%,更优选至少80%,由六角形颗粒的数目和小于0.50所说的方法包括的平均当量表面积的变化系数:引入到温度控制的反应容器中在wässrige分散介质和银, 溴,和,任选地,碘化物和/或氯化物,和晶粒成核和生长过程中保持所述反应容器内的pBr值做有利于形成与片状颗粒,在当时没有为特征的生长,所述片状颗粒正在形成中,(a )pH值在所述反应容器保持在从0.8至10的值; (B)一个明胶 - 胶溶剂存在于每升。所述的从0至50 g的浓度在反应容器分散介质,并且具有至少为1.8的值。所述反应容器内的(c)中的pBr颗粒成核过程中保持 ,worin成核在反应容器中在范围为10〜60℃的温度和所述反应容器内的的pBr值来进行被保持在低于2.4生长期间的值,worin生长在反应容器中,在执行的 在范围内的温度从40至80℃,并且更优选在以达到小于0时06微米,其颗粒厚度40和50℃之间的范围内,提供做了明胶胶溶剂所有这些是选自钙离子和自由 具有每克明胶 - 胶溶剂的小于30个微摩尔的蛋氨酸含量为晶粒成核和生长过程中存在于所述分散介质。 更过的照相材料,包括乳剂的制备雅丁到本发明的方法已被声明的。