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    • 22. 发明公开
    • Fast photovoltachromic device and the application thereof
    • Schnelle photovoltachromische Vorrichtung und deren Anwendung
    • EP2241934A2
    • 2010-10-20
    • EP10159522.1
    • 2010-04-09
    • National Cheng Kung University
    • Wu, Jih-JenHsieh, Min-DaLiao, Wen-PinWu, Wei-TingChen, Jen-SueHuang, Jow-Lay
    • G02F1/155G02F1/163E06B9/24H01M14/00
    • G02F1/155B82Y20/00G02F1/1523G02F1/163G02F2001/13324G02F2202/36H01G9/2022H01M4/9016H01M4/92H01M14/005
    • A photovoltachromic device (600) includes a photoelectrode, a counter electrode electrically connected to the photoelectrode, and an electrolyte layer (660) disposed between the photoelectrode and the counter electrode. The photoelectrode includes a first transparent electrode (610) supported by the first transparent substrate (612), an electron-transport layer (630) disposed on the first transparent electrode, and a sensitizing layer (632) disposed on the electron-transport layer. The counter electrode includes a second transparent electrode (620) supported by the second transparent substrate (622) and an electrochromic layer (640) disposed on the second transparent electrode and an auxiliary conductive catalyst layer (650) disposed on the second transparent electrode. The auxiliary conductive catalyst layer contacts both the electrolyte layer (660) and the electrochromic layer (640) thereby accelerating the response times for coloring and bleaching the photovoltachromic device. For achieving a lower transmittance of the photovoltachromic device in colored state the thickness of the electrochromic layer (660) can be increased. The photovoltachromic device (600) may include a switch (670) and a variable resistor (680) instead of an electrical connection between the two transparent electrodes such that the transmittance can be variable by adjusting the resistance.
    • 光电装置(600)包括光电极,与光电极电连接的对电极,以及设置在光电极和对电极之间的电解质层(660)。 光电极包括由第一透明基板(612)支撑的第一透明电极(610),设置在第一透明电极上的电子传输层(630)和设置在电子传输层上的敏化层(632)。 对电极包括由第二透明基板(622)支撑的第二透明电极(620)和设置在第二透明电极上的电致变色层(640)和设置在第二透明电极上的辅助导电催化剂层(650)。 辅助导电催化剂层与电解质层(660)和电致变色层(640)接触,从而加快色素和漂白光电装置的响应时间。 为了在有色状态下实现光电变装置的较低透射率,可以增加电致变色层(660)的厚度。 光电装置(600)可以包括开关(670)和可变电阻器(680),而不是两个透明电极之间的电连接,使得透射率可以通过调节电阻而变化。