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    • 26. 发明公开
    • METHOD FOR MANUFACTURING ZINC SULFIDE BASED PHOSPHOR
    • 制备硫化锌基磷光体的方法
    • EP2319896A1
    • 2011-05-11
    • EP09804903.4
    • 2009-07-30
    • Kuraray Co., Ltd.
    • TSUJI, YoshihisaINOUE, KazumaTAKAI, JunIWASAKI, Hideharu
    • C09K11/08C09K11/56
    • C09K11/625C09K11/876H05B33/14
    • The present invention provides a method for producing a zinc sulfide based phosphor by firing a zinc sulfide based phosphor precursor, comprising at least: a first firing step of firing a mixture containing a zinc sulfide based phosphor precursor, sulfur, and a chlorine-containing flux; and a second firing step of further firing the fired product obtained from the first firing step, wherein the first firing step comprises: heating the mixture in an atmosphere wherein an air stream is introduced so that a temperature of the mixture is increased from normal temperature to a transformation temperature at which a crystal system of the phosphor precursor is transformed; when a temperature of the mixture is increased above the transformation temperature, switching the atmosphere to a nitrogen atmosphere and continuing the heating of the mixture; and when the temperature of the mixture reaches a temperature in a range of 1000°C to 1200°C, inclusive, maintaining the temperature of the mixture at a constant level and thereafter rapidly quenching the mixture and washing the mixture to obtain a fired product; and wherein the second firing step comprises heating in the nitrogen atmosphere the fired product obtained from the first firing step so that the temperature of the fired product is increased from normal temperature to a temperature in a range of 650°C to 1000°C, inclusive; and when a temperature of the fired product reaches the temperature in the range of 650°C to 1000°C, inclusive, introducing oxygen while maintaining the temperature of the fired product and thereafter rapidly quenching the fired product and washing the fired product to obtain a zinc sulfide based phosphor. Use of the method of the present invention makes it possible to provide a zinc sulfide based phosphor material suitable for use in the production of an EL device that shows high brightness.
    • 本发明提供一种通过煅烧硫化锌系荧光体前体来制造硫化锌系荧光体的方法,至少包括:第一烧成工序,烧制含有硫化锌系荧光体前体,硫和含氯熔剂的混合物 ; 以及第二烧成工序,对由所述第一烧成工序得到的烧成物进一步烧成,其中,所述第一烧成工序包括如下工序:在导入空气流的气氛中加热所述混合物,使所述混合物的温度从常温升温至 磷光体前体的晶体体系转变的转变温度; 当混合物的温度升高到高于转变温度时,将气氛切换到氮气氛并继续加热混合物; 并且当混合物的温度达到1000℃至1200℃范围内的温度时,保持混合物的温度恒定并随后快速骤冷混合物并洗涤混合物以获得烧制产物; 并且其中所述第二烧制步骤包括在所述氮气氛中加热从所述第一烧制步骤获得的所述烧制产品,使得所述烧制产品的温度从常温升高至650℃至1000℃的温度 ; 在烧成体的温度达到650℃以上且1000℃以下的范围内的温度的状态下,在维持烧成体的温度的状态下导入氧,然后使烧成体骤冷并清洗,得到 硫化锌基磷光体。 使用本发明的方法可以提供适合用于制造显示高亮度的EL器件的硫化锌基荧光体材料。