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21. 发明授权

EP2370477B1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 有权
公开(公告)号：EP2370477B1
公开(公告)日：2012-11-21
申请号：EP09793547.2
申请日：2009-12-21
申请人： Basell Poliolefine Italia S.r.l.
发明人： GUNDERT, Friedhelm , SCHNEIDER, Martin
IPC分类号： C08F4/651 , C08F4/655 , C08F110/02
CPC分类号： C08F110/02 , B01J27/135 , B01J27/138 , B01J31/0212 , B01J31/143 , B01J31/38 , B01J35/1038 , B01J35/1052 , C08F4/6555 , C08F4/651 , C08F4/6492 , C08F2500/18 , C08F2500/12 , C08F2500/24

22. 发明授权

EP2164897B1 MULTIMODAL POLYETHYLENE COPOLYMER RESIN COMPOSITION, A PREPARATION PROCESS THEREFORE AND A POLYMERIC PRODUCT COMPRISING THE SAME 无效
标题翻译：多模式POLYETHYLENCOPOLYMERHARZZUSAMMENSETZUNG，工艺生产同样与综合利用聚合物产品
公开(公告)号：EP2164897B1
公开(公告)日：2012-04-04
申请号：EP08773863.9
申请日：2008-07-03
申请人： Borealis Technology OY
发明人： BERGSTRA, Michiel, Friso , ERIKSSON, Erik, Johan, Gunnar
IPC分类号： C08L23/04 , C08L23/08 , C08F10/02
CPC分类号： C08L23/04 , C08F4/6555 , C08F210/16 , C08L23/0815 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/02 , C08F2500/01 , C08F2500/05
摘要： The present invention relates to a multimodal polyethylene copolymer resin composition comprising (a) a lower molecular weight (LMW) ethylene polymer fraction and (b) a higher molecular weight (HMW) ethylene copolymer fraction, wherein the higher molecular weight (HMW) ethylene copolymer fraction comprises (b1) a higher molecular weight (HMW) ethylene copolymer subfraction having a weight average molecular weight at least 2 times the weight average molecular weight (Mw) of said multimodal polyethylene copolymer resin composition, which (b1) higher molecular weight (HMW) ethylene copolymer subfraction amounts from about 1-30 wt% of the total amount of the multimodal polyethylene copolymer resin composition and comprises comonomers in amount of at least about 1 wt% of the total amount of comonomer present in said multimodal polyethylene copolymer resin composition, a process for its preparation and its use.

23. 发明公开

EP2356155A1 PROCESS FOR THE POLYMERIZATION OF ETHYLENE, AND ETHYLENE POLYMERS HAVING BROAD MOLECULAR WEIGHT DISTRIBUTION AND LONG- CHAIN BRANCHING 有权
标题翻译： PROCESS乙烯和乙烯聚合物的宽分子量分布和长链支化聚合
公开(公告)号：EP2356155A1
公开(公告)日：2011-08-17
申请号：EP09760774.1
申请日：2009-11-30
申请人： Basell Polyolefine GmbH
发明人： CIACCIA, Eleonora , VITTORIAS, Iakovos , MIHAN, Shahram , LUKESOVA, Lenka , LILGE, Dieter , HERRARA SALINAS, Maclovio , MEIER, Gerhardus , MANNEBACH, Gerd
IPC分类号： C08F10/02 , C08F4/70 , C08F4/655
CPC分类号： C08F10/02 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2410/04 , C08F4/6555 , C08F4/7042 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/11 , C08F2500/10
摘要： New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5s
-1 , at 150°C), branching index g' equal or lower than 0.9 (at Mw of 2⋅10
6 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100°C, for a time of at least 10 minutes.

24. 发明公开

EP2227491A4 ETHYLENE-BASED POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 审中-公开
标题翻译： POLYMERZUSAMMENSETZUNGEN AUF ETHYLENBASIS，VERFAHREN ZU IHRER HERSTELLUNG UND ARTIKEL DARAUS
公开(公告)号：EP2227491A4
公开(公告)日：2011-07-13
申请号：EP08865935
申请日：2008-12-18
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： KAPUR MRIDULA , JORGENSEN ROBERT , WAGNER BURKHARD , MICHIE WILLIAM
IPC分类号： C08F4/00 , C08F4/52 , C08F4/642
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0807 , C08L2205/02 , C08F4/6543 , C08F4/6555 , C08F4/651 , C08F4/6567 , C08F2/001 , C08L2666/06 , C08F2500/02 , C08F2500/12 , C08F210/14 , C08F2500/01
摘要： The invention provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer, and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer has a density less than, or equal to, 0.955 g/cm3, and wherein the blend has a high load melt index (I21) greater than, or equal to, 15 g/10 min, and wherein the blend has a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. The invention also provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer component has a density less than, or equal to, 0.945 g/cm3, and a melt index (I2) less than, or equal to, 0.1 g/10 min, and wherein the blend has a high load melt index (I21) less than, or equal to, 15 g/10 min, and a melt index (I5) less than, or equal to 1 g/10 min, and a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. Additional compositions are disclosed.
摘要翻译：本发明提供一种包含共混物的组合物，其包含高分子量乙烯基聚合物和低分子量乙烯基聚合物，并且其中高分子量乙烯基聚合物的密度小于或等于 0.955g / cm3，并且其中所述共混物具有大于或等于15g / 10min的高负荷熔体指数（I21），并且其中所述共混物的分子量分布（Mw / Mn）大于或等于本发明还提供一种包含共混物的组合物，其包含高分子量乙烯基聚合物和低分子量乙烯基聚合物，并且其中高分子量乙烯基聚合物组分的密度小于，或等于0.945g / cm 3，熔体指数（I 2）小于或等于0.1g / 10min，并且其中所述共混物具有小于或等于的熔体指数（I 21） 15g / 10min，熔体指数（I5）小于或等于1g / 10min，分子w 八分配（Mw / Mn）大于或等于15.另外的组合物被公开。

25. 发明公开

EP2246368A1 Improved ethylene polymerization catalyst composition 审中-公开
标题翻译：乙烯聚合酶催化剂
公开(公告)号：EP2246368A1
公开(公告)日：2010-11-03
申请号：EP09159141.2
申请日：2009-04-30
申请人： Borealis AG
发明人： Garoff, Thomas , Waldvogel, Päivi , Kallio, Kalle , Eriksson, Virginie
IPC分类号： C08F4/655 , C08F210/16
CPC分类号： C08F210/16 , C08F4/6555 , C08F210/08 , C08F2500/12 , C08F2500/18 , C08F2500/08
摘要： Ziegler-Natta catalyst composition capable of producing ethylene/alpha-olefins copolymers, particularly linear low density polyethylene; the composition having an improved stability of its behaviour during polymerization in respect to time.
The Ziegler-Natta catalyst composition comprises:
A) a procatalyst, which procatalyst comprises
a) an AI compound having the formula Al(alkyl) x Cl 3-x (I), where alkyl is an alkyl group with 1 to 12 and 0 ≤ x ≤ 3,
b) a magnesium hydrocarbyloxy compound of formula Mg(OR 1 ) 2-n (R 2 ) n (II), wherein each R 1 and R 2 is independently a C 1-20 hydrocarbon residue which may optionally be substituted with halogen and 0 ≤ n
c) a chlorine-containing titanium compound of the formula ClyTi(OR 3 ) 4-y (III), wherein R 3 is a C 2-20 hydrocarbon residue and y is 1, 2, 3 or 4,
with compounds a), b) and c) being supported on a particulate inorganic carrier and
B) a halogenated aluminium alkyl cocatalyst of the formula (IV) (C 1 -C 3 -alkyl) m -Al-X 3-m , wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2,
whereby the composition shows a reduced change of comonomer response with polymerization time compared to compositions using non-halogenated cocatalysts.
摘要翻译：能够生产乙烯/α-烯烃共聚物，特别是线性低密度聚乙烯的齐格勒 - 纳塔催化剂组合物; 该组合物在聚合过程中相对于时间具有改进的其行为稳定性。齐格勒 - 纳塔催化剂组合物包含：A）前催化剂，其主催化剂包括a）具有式Al（烷基）x Cl 3-x（I）的Al化合物，其中烷基是具有1至12和0‰的烷基 ¤x‰3，b）式Mg（OR 1）2-n（R 2）n（II）的镁烃氧基化合物，其中每个R 1和R 2独立地为C 1-20烃残基，其可任选地用卤素代替，0‰n <2，c）式ClyTi（OR 3）4-y（III）的含氯钛化合物，其中R 3是C 2-20烃残基，y是1 ，2,3或4，其中化合物a），b）和c）负载在颗粒状无机载体上，B）式（Ⅳ）的卤化烷基铝助催化剂（C 1 -C 3 - 烷基）m -Al -X 3-m，其中X是氯，溴，碘或氟，m是1或2，由此与使用非卤化助催化剂的组合物相比，组合物表现出聚合时间下共聚单体响应的变化减小。

26. 发明公开

EP2227491A1 ETHYLENE-BASED POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 审中-公开
标题翻译：聚合物组合物乙烯基地，用于生产及其制品
公开(公告)号：EP2227491A1
公开(公告)日：2010-09-15
申请号：EP08865935.4
申请日：2008-12-18
申请人： Dow Global Technologies Inc.
发明人： KAPUR, Mridula , JORGENSEN, Robert , WAGNER, Burkhard , MICHIE, William
IPC分类号： C08F4/00 , C08F4/52 , C08F4/642
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0807 , C08L2205/02 , C08F4/6543 , C08F4/6555 , C08F4/651 , C08F4/6567 , C08F2/001 , C08L2666/06 , C08F2500/02 , C08F2500/12 , C08F210/14 , C08F2500/01
摘要： The invention provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer, and a low molecular weight ethylene- based polymer, and wherein the high molecular weight ethylene-based polymer has a density less than, or equal to, 0.955 g/cm3, and wherein the blend has a high load melt index (I2i) greater than, or equal to, 15 g/10 min, and wherein the blend has a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. The invention also provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer component has a density less than, or equal to, 0.945 g/cm3, and a melt index (I2) less than, or equal to, 0.1 g/10 min, and wherein the blend has a high load melt index (I2i) less than, or equal to, 15 g/10 min, and a melt index (I5) less than, or equal to 1 g/10 min, and a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. Additional compositions are disclosed.

27. 发明公开

EP2144955A1 BIMODAL POLYETHYLENE RESINS THAT HAVE HIGH STIFFNESS AND HIGH ESCR 无效
标题翻译：具有高刚度，高抗落泪UMGEBUNGSTBEDINGTE电压BI MODAL聚乙烯树脂
公开(公告)号：EP2144955A1
公开(公告)日：2010-01-20
申请号：EP08747536.4
申请日：2008-05-02
申请人： Fina Technology, Inc.
发明人： COFFY, Tim , GEUNTHER, Gerhard , GRAY, Steven
IPC分类号： C08G85/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F2/001 , C08F2500/05 , C08F2500/13 , C08F2500/07 , C08F2500/11 , C08F2500/12 , C08F210/08
摘要： A bimodal polyethylene having a high density ranging from about 0.955 to about 0.959 g/cc, an improved environmental stress cracking resistance (ESCR) of from about 400 to about 2500 hours, and an improved 0.4% flesxural modulus of from about 180,000 to about 260,000 psi (1,200 MPa to about 1,800 MPa) may be formed using a Ziegler-Natta polymerization catalyst using two reactors in series. The bimodal polyethylene may have a high load melt index (HLMI) of from about 2 and about 30 dg/min and may be optionally made with a small amount of alpha-olefinic comonomer in the second reactor. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.72(b).

28. 发明授权

EP1268583B1 Pre-polymerised catalyst components for the polymerisation of olefins 有权
标题翻译：用于烯烃聚合的预聚合催化剂组分
公开(公告)号：EP1268583B1
公开(公告)日：2009-08-26
申请号：EP01951489.2
申请日：2001-05-07
申请人： Basell Poliolefine Italia S.r.l.
发明人： SACCHETTI, Mario , BRITA, Diego , COLLINA, Gianni
IPC分类号： C08F4/649 , C08F4/655 , C08F4/656 , C08F110/02
CPC分类号： C08F4/6492 , C08F4/6555 , C08F4/6567 , C08F110/02 , C08F110/06 , C08F2500/18 , C08F2500/07 , C08F2500/12
摘要： Catalyst components for the preparation of ethylene (co)polymers capable to produce polymers with high bulk density, to avoid the problems of formation of fines and that have a high activity are provided. Said catalyst components are characterized by comprising a non-stereospecific solid catalyst component, comprising a titanium compound and a magnesium dihalide, which is pre-polymerized with an alpha olefin CH2=CHRI wherein R is a C1-C8 alkyl group, to such an extent that the amount of the α-olefin pre-polymer is up to 100 g per g of said solid catalyst component.

29. 发明公开

EP2011822A1 Multimodal polyethylene co-polymer resin composition, a preparation process therefore and a polymeric product comprising the same 审中-公开
标题翻译：多峰聚乙烯共聚物树脂组合物，其制造方法及由此制得的聚合物产物
公开(公告)号：EP2011822A1
公开(公告)日：2009-01-07
申请号：EP07075558.2
申请日：2007-07-04
申请人： Borealis Technology Oy
发明人： Bergstra, Michiel Friso , Eriksson, Erik Johan Gunnar , Pakkanen, Britt Anneli , Gustafsson, Bill Benjamin Rudolf , Weickert, Günter
IPC分类号： C08L23/04 , C08L23/08
CPC分类号： C08L23/04 , C08F4/6555 , C08F210/16 , C08L23/0815 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/02 , C08F2500/01 , C08F2500/05
摘要： The present invention relates to a multimodal polyethylene co-polymer resin composition comprising (a) a lower molecular weight (LMW) ethylene polymer fraction and (b) a higher molecular weight (HMW) ethylene copolymer fraction, wherein the higher molecular weight (HMW) ethylene co-polymer fraction comprises (b1) a higher molecular weight (HMW) ethylene co-polymer subfraction having a weight average molecular weight at least 2 times the weight average molecular weight (Mw) of said multimodal polyethylene co-polymer resin composition, which (b1) higher molecular weight (HMW) ethylene co-polymer subfraction amounts from about 1-30 wt% of the total amount of the multimodal polyethylene co-polymer resin composition and comprises comonomers in amount of at least about 1 wt% of the total amount of comonomer present in said multimodal polyethylene copolymer resin composition, a process for its preparation and its use.
摘要翻译：本发明涉及多峰聚乙烯共聚物树脂组合物包括：（A）较低分子量（LMW）乙烯聚合物部分和（b）较高分子量（HMW）乙烯共聚物部分，worin较高分子量（HMW）乙烯共聚物部分包含（B1）具有的重均分子量的至少2倍的重均分子量，所述多峰聚乙烯共聚物树脂组合物（Mw）为，其中较高分子量（HMW）乙烯共聚物子部分（B1）由所述多峰聚乙烯共聚物树脂组合物，并且包括共聚单体的总量的约1〜30％（重量）的较高分子量（HMW）乙烯共聚物子量为至少占总数的约1重量％的量存在于所述多峰聚乙烯共聚物树脂组合物，其制备方法和其使用的方法共聚单体的量。

30. 发明公开

EP1896532A1 POLYETHYLENE MOLDING COMPOSITION FOR PRODUCING INJECTION-MOLDED FINISHED PARTS 有权
标题翻译：聚乙烯表格合并用于生产注塑成型组件READY
公开(公告)号：EP1896532A1
公开(公告)日：2008-03-12
申请号：EP06777475.2
申请日：2006-06-27
申请人： Basell Polyolefine GmbH
发明人： BERTHOLD, Joachim , VOGT, Heinz , STERN, James , WEBER, Albert
IPC分类号： C08L23/08 , C08L23/06 , C08F10/02
CPC分类号： C08F297/083 , C08F210/16 , C08F297/08 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08F4/6555 , C08L2666/06 , C08F2500/01 , C08F2500/12 , C08F2500/07 , C08F2500/17
摘要： The invention relates to a polyethylene molding composition which has a multimodal molecular mass distribution and comprises a low molecular weight ethylene homopolymer A, a high molecular weight ethylene copolymer B and an ultrahigh molecular weight ethylene copolymer C. The molding composition has a density at a temperature of 23°C in the range from 0.940 to 0.957 g/cm3, an MFR (190°C/2.16 kg) in the range from 0.5 to 4 dg/min and a viscosity number VN3 of the mixture of ethylene homopolymer A, copolymer B and ethylene copolymer C, measured in accordance with ISO/R 1191 in decalin at a temperature of 135°C, in the range from 150 to 300 cm3/g. The invention further relates to the use of such a molding composition for producing injection-molded finished parts, and to finished parts produced by injection molding.

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