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21. 发明公开

EP0821686A1 NOVEL PORPHYRINS AND PORPHYRIN SYNTHESIS TECHNIQUES 失效
标题翻译：卟啉和卟啉技术TO
公开(公告)号：EP0821686A1
公开(公告)日：1998-02-04
申请号：EP95944070.0
申请日：1995-12-07
申请人： THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA , The Board of Regents of the University of Nebraska
发明人： DIMAGNO, Stephen , THERIEN, Michael, J.
IPC分类号： A61K31 , A61K41 , A61K47 , A61K51 , B01J31 , C07B61 , C07C29 , C07D207 , C07D487 , C07D519 , C07F3 , C07F7 , C08F30 , C08G73 , C08G79 , C09B47 , C09B69 , G01N27 , G03G5
CPC分类号： A61K41/0071 , A61K31/555 , A61K47/54 , A61K47/546 , A61K51/0485 , B01J31/0244 , B01J31/1608 , B01J31/1815 , B01J2231/70 , B01J2231/72 , B01J2531/025 , B01J2531/26 , C07C29/50 , C07D207/33 , C07D207/333 , C07D207/335 , C07D487/22 , C07D519/00 , C07F7/082 , C07F7/0832 , C08F30/04 , C08G73/0611 , C08G79/00 , C09B47/00 , C09B69/10 , C09B69/108 , G01N27/126 , G03G5/0696 , G03G5/076
摘要： Strapped porphyrins and electron-deficient porphyrins are provided, as well as processes and intermediates for their preparation. In certain embodiments, such compounds are prepared by nucleophilic displacement of leaving groups from methylpyrroles. In other embodiments, such compounds are prepared by condensing pyrrole derivatives and removing water thus formed from the resulting reaction mixture.

22. 发明公开

EP0723967A1 Organometallic compounds and polymers made therefrom 失效
标题翻译： Organometall-Verbindungen und davon abgeleitete Polymere
公开(公告)号：EP0723967A1
公开(公告)日：1996-07-31
申请号：EP96100214.4
申请日：1996-01-09
申请人： ELF ATOCHEM NORTH AMERICA, INC.
发明人： Silverman, Gary S. , Tseng, Kenneth K.S. , Uhm, Haewon L.
IPC分类号： C07F9/141 , C09D5/16 , C08F30/04 , A01N57/12
CPC分类号： C07F9/1417 , A01N25/10 , C08F30/04 , C09D5/1625 , C09D5/1637
摘要： Compounds of formula (I) are disclosed:

wherein L 1 is a main group atom, L 2 is a neutral ligand, M is a transition element or a metal element of Group 13, 14, 15, or 16 of the Periodic Table, x is the number of coordination sites of M, R 1 is a polymerizable group, R 2 , R 3 , and R 4 are ligands, and R 5 is an anionic ligand. The compounds or monomers of formula (I) are capable of conversion to polymers by combination with one or more other known monomers, such as methyl methacrylate. Such polymers can then be added as a binder in a paint formulation to make marine antifouling coating compositions. Also described is a method to prevent fouling on surfaces wherein a composition containing a metal complex compound of formula (II):

wherein M, x, L 2 , n, and R 4 have the same meaning as in formula (I), is applied to the surface susceptible to fouling.
摘要翻译：公开了式（I）的化合物：其中L 1是主要原子的CHEM，L 2是中性配体，M是第13,14,15或15或15位的过渡元素或金属元素 16，x是M的配位点数，R 1是可聚合基团，R 2，R 3和R 4是配体，R 5是阴离子配体。式（I）的化合物或单体可以通过与一种或多种其它已知的单体如甲基丙烯酸甲酯的组合转化成聚合物。然后可以将这样的聚合物作为粘合剂加入到油漆配方中以制备海洋防污涂料组合物。还描述了一种防止在表面上结垢的方法，其中含有式（II）的金属络合物的组合物：其中M，x，L 2，n和R 4具有与下式式（I），适用于容易污染的表面。

23. 发明公开

EP0502128A4 ANIONICALLY POLYMERIZABLE MONOMERS, POLYMERS THEREOF, AND USE OF SUCH POLYMERS IN PHOTORESISTS. 失效
标题翻译： ANIONISCH POLYMERISIERBARE MONOMERE，DARAUS HERGESTELLTE POLYMERE UND DIE VERWENDUNG DER POLYMERE INPHOTOWIDERSTÄNDEN。
公开(公告)号：EP0502128A4
公开(公告)日：1992-04-02
申请号：EP91902819
申请日：1990-11-20
申请人： LOCTITE CORP
发明人： WOODS JOHN G , COAKLEY PAULINE
IPC分类号： C07F7/10 , C07F7/08 , C07F7/18 , C07F7/28 , C08F30/04 , C08F30/08 , C08F130/04 , C08F130/08 , C08F136/14 , C23C16/00 , G03F7/027 , G03F7/038 , G03F7/039 , G03F7/075 , H01L21/027
CPC分类号： C07F7/0818 , C07F7/0854 , C07F7/1852 , C07F7/28 , C08F30/04 , G03F7/038 , G03F7/039 , G03F7/0758
摘要： Anionically polymerizable monomers containing at least one silicon or titanium atom for polymeric photoresists for use in microlithography. The monomers are of formula (I), wherein A is -H or -CH=CH2; X is a strong electron withdrawing group; Y is a strong electron withdrawing group containing at least one silicon or titanium atom. Preferably Y is (II), wherein n is 1-5 and R , R and R are C1-C10 alkyl. A particularly preferred monomer is 3-trimethylsilylpropyl 2-cyanoacrylate. Methods for applying a resist coating by vapour deposition of these monomers and exposure to radiation are described. A positive or negative tone image can be produced, depending upon the imaging method employed. The imaging layer may be applied over a planarizing layer to form a multilayer photoresist.
摘要翻译：含有至少一个硅或钛原子的可用于微光刻的聚合物光刻胶的可阴离子聚合单体。单体具有式（I），其中A是-H或-CH = CH 2; X是强吸电子基团; Y是含有至少一个硅原子或钛原子的强吸电子基团。优选Y是（II），其中n是1-5并且R 2，R 3和R 4是C 1 -C 10烷基。特别优选的单体是2-氰基丙烯酸3-三甲基甲硅烷基丙酯。描述了通过气相沉积这些单体并暴露于辐射来施加抗蚀剂涂层的方法。取决于所采用的成像方法，可以产生正色调或负色调图像。成像层可以施加在平坦化层上以形成多层光致抗蚀剂。

24. 发明授权

EP0204456B1 A hydrolyzable resin composition and an antifouling coating composition containing the same 失效
标题翻译：可水解的树脂组合物和含有它的防粘涂料组合物
公开(公告)号：EP0204456B1
公开(公告)日：1991-10-09
申请号：EP86303760.2
申请日：1986-05-16
申请人： Nippon Paint Co., Ltd.
发明人： Yamamori, Naoki , Ohsugi, Hiroharu , Eguchi, Yoshio , Yokoi, Junji
IPC分类号： C08F30/04 , C08G63/68 , C08G59/14 , C09D5/14
CPC分类号： C08G59/1433 , C08F30/04 , C08G63/68 , C09D5/165

26. 发明公开

EP1535950A4 DISPERSION OF ION-EXCHANGE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF 有权转让
标题翻译： DISPERSION VON IONENAUSTAUSCHERPOLYMER，HERSTELLUNGSVERFAHRENDAFÜRUND VERWENDUNG DAVON
公开(公告)号：EP1535950A4
公开(公告)日：2005-10-26
申请号：EP03741271
申请日：2003-07-08
申请人： ASAHI GLASS CO LTD
发明人： TERADA ICHIRO , HOMMURA SATORU , KASAHARA NOBUYUKI , UENO KATSUYA
IPC分类号： C08F30/04 , C08F130/04 , C08F230/04 , C08J3/03 , C08J5/20 , H01M4/86 , H01M4/88 , H01M4/92 , H01M4/96 , C08J5/22 , H01M8/10
CPC分类号： C08J5/2293 , C08F30/04 , C08F130/04 , C08F230/04 , C08J3/05 , C08J5/20 , C08J2327/12 , C08J2327/18 , H01M4/8605 , H01M4/8803 , H01M4/8828 , H01M4/921 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56 , Y10T428/24802
摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25 DEG C at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.
摘要翻译：通过向具有含磺酸基的氟化聚合物作为均匀分散在分散介质中的离子交换聚合物的离子交换聚合物分散体施加超声波振动或剪切力来获得增稠的离子交换聚合物分散体，使得分散体的粘度为25 在10（1 / s）的剪切速率下，DEGC在增稠步骤中增加2-2000倍。当形成膜时，该分散体可以形成具有均匀且小厚度，高强度的离子交换膜，其不发生开裂并且在水和蒸汽中显示恒定的溶胀。此外，可以使用通过将包含该分散体的涂布液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体涂布到基材上而形成的层，以制备膜 - 电极组件作为用于通过邻近离子交换膜设置催化剂层来实现阴极和阳极中的至少一个。由于催化剂层强度高，缺陷少，平滑性优异，所以能够得到固体高分子电解质型燃料电池用高性能膜电极接合体。

27. 发明公开

EP1511777A4 STEREOREGULAR POLAR VINYL POLYMERS AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：立体定向极性乙烯聚合物及其制造方法
公开(公告)号：EP1511777A4
公开(公告)日：2005-06-15
申请号：EP03728789
申请日：2003-05-09
申请人： UNIV NORTH CAROLINA STATE
发明人： KUWAHARA HIROAKI , NOVAK BRUCE M
IPC分类号： C08F2/00 , C08F4/00 , C08F4/06 , C08F30/04 , C08F12/28 , C08F120/18 , C08F120/44 , C08F120/52
CPC分类号： C08F4/00 , C08F30/04
摘要： The polymerization of polar vinyl monomers in the presence of Lewis acids produces stereoregular vinyl polymers. Polar vinyl monomers may be mixed with Lewis acids to form associations or complexes between the monomers and Lewis acids. The mixtures or monomer-Lewis acid complexes may be polymerized to produce the desire stereoregular vinyl polymers.

28. 发明公开

EP1535950A1 DISPERSION OF ION-EXCHANGE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF 有权转让
标题翻译：分散剂VONE IONENAUSTAUSCHERPOLYMER，HERSTELLUNGSVERFAHRENDAFÜRUND VERWENDUNG DAVON
公开(公告)号：EP1535950A1
公开(公告)日：2005-06-01
申请号：EP03741271.5
申请日：2003-07-08
申请人： Asahi Glass Company, Limited
发明人： TERADA, Ichiro Asahi Glass Company, Limited , HOMMURA, Satoru Asahi Glass Company, Limited , KASAHARA, Nobuyuki Asahi Glass Company, Limited , UENO, Katsuya Asahi Glass Company, Limited
IPC分类号： C08J3/03 , C08J5/22 , H01M8/10
CPC分类号： C08J5/2293 , C08F30/04 , C08F130/04 , C08F230/04 , C08J3/05 , C08J5/20 , C08J2327/12 , C08J2327/18 , H01M4/8605 , H01M4/8803 , H01M4/8828 , H01M4/921 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56 , Y10T428/24802
摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25°C at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.
摘要翻译：通过对具有磺酸基的氟化聚合物作为离子交换聚合物均匀分散在分散介质中的离子交换聚合物分散体施加超声振动或剪切力，从而使分散体在25℃下的粘度得到增稠的离子交换聚合物分散体在10（1 / s）的剪切速率下，DEGC在增稠步骤中增加2-2000次。当形成膜时，分散体可以形成具有均匀且小的厚度，高强度的离子交换膜，其没有破裂并且在水和蒸汽中显示恒定的溶胀。此外，可以使用通过将含有该分散体的涂布溶液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体的催化剂粉末涂布到基板上而形成的层，以制备作为催化剂层的膜 - 电极组件通过相邻于离子交换膜提供催化剂层，阴极和阳极中的至少一个。由于催化剂层的强度很高，缺点少，流平性好，因此可以得到固体高分子电解质型燃料电池用高性能膜 - 电极组件。

29. 发明公开

EP1516901A1 PHOSPHORS AND PROCESS FOR PRODUCTION THEREOF, LUMINESCENT COMPOSITIONS, AND ORGANIC ELECTROLUMINESCENT DEVICES AND PROCESSES FOR PRODUCTION THEREOF 审中-公开
标题翻译： LIGHT物质及其生产，发光组合物和有机电致发光及生产
公开(公告)号：EP1516901A1
公开(公告)日：2005-03-23
申请号：EP03736256.3
申请日：2003-06-26
申请人： JSR Corporation
发明人： SAKAKIBARA, Mitsuhiko c/o JSR Corporation , YASUDA, Hiroyuki c/o JSR Corporation , ERIYAMA, Yuichi c/o JSR Corporation
IPC分类号： C09K11/06 , C08F30/04 , H05B33/14 , H05B33/10
CPC分类号： H01L51/004 , C07B2200/11 , C07F15/004 , C07F15/0046 , C08F30/04 , C08F230/04 , C09K11/06 , C09K2211/1029 , C09K2211/1048 , C09K2211/14 , C09K2211/185 , H01L51/0042 , H01L51/007 , H01L51/0085 , H01L51/5012 , H05B33/14
摘要： Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof.
A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1).
[In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R 1 and R 2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R 1 and R 2 may be either the same or different, X 1 represents a phenylene group or a carbonyloxy group, X 2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]
摘要翻译：公开于是，具有发光层含有所述磷光剂，其可以通过湿式法形成薄膜，并提供给有机电致发光器件具有高亮度和其制造方法，以及含有该磷光剂的发光性组合物，在有机电致发光器件磷光剂及其生产方法。磷光剂gemäß到本发明的包括在其分子中具有由下列通式（1）表示的结构单元的聚合物。 A在通式（1）中，M具有darstellt的2〜4价的金属原子，每个R <1>和R <2> darstellt氢原子，卤原子，环烷基与芳基基和杂环基，R <1>和R <2>可以是相同或不同的，X <1> darstellt亚苯基或一个羰基，X <2>亚烷基团的darstellt，有机配体L的darstellt 中，p是1〜3的整数，q是0或1.U

30. 发明公开

EP1511777A1 STEREOREGULAR POLAR VINYL POLYMERS AND METHODS OF MAKING THE SAME 审中-公开
标题翻译： STEREO REGULAR POLAR乙烯基聚合物及其制造方法
公开(公告)号：EP1511777A1
公开(公告)日：2005-03-09
申请号：EP03728789.3
申请日：2003-05-09
申请人： North Carolina State University
发明人： KUWAHARA, Hiroaki,North Carolina State University , NOVAK, Bruce, M.,North Carolina State University
IPC分类号： C08F4/00 , C08F4/06 , C08F12/28 , C08F120/52 , C08F120/44 , C08F120/18
CPC分类号： C08F4/00 , C08F30/04
摘要： The polymerization of polar vinyl monomers in the presence of Lewis acids produces stereoregular vinyl polymers. Polar vinyl monomers may be mixed with Lewis acids to form associations or complexes between the monomers and Lewis acids. The mixtures or monomer-Lewis acid complexes may be polymerized to produce the desire stereoregular vinyl polymers.

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