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    • 26. 发明公开
    • Production of ammonia from urea for removing nitrogen oxides from exhaust gas streams
    • VERBESSERTES VERFAHREN ZUR HERSTELLUNG VON AMMONIAK AUS HARNSTOFF
    • EP2842915A1
    • 2015-03-04
    • EP14195497.4
    • 2008-12-05
    • EC & C Technologies, Inc.
    • Spencer, Herbert W.Peters, H. JamesHankins, William G.Fujita, Madoka
    • C01C1/08F01N3/20B01D53/94
    • C01C1/086B01D2251/2062F01N3/208F01N2240/40F01N2610/02F01N2610/06F01N2610/10F01N2610/14F01N2900/1808F01N2900/1811F01N2900/1814Y02T10/24
    • A process for removing nitrogen oxides from a combustion gas stream which process comprises:
      (a) heating an aqueous solution of urea, or a mixture of urea, containing biuret or ammonium carbamate on site, in a hydrolysis reactor such that a gaseous ammonia-containing product is obtained which is essentially free of urea, biuret, or ammonium carbamate, the temperature and pressure being maintained by the input of heat to the reactor;
      (b) separating the gaseous ammonia-containing product from the liquid phase aqueous reaction media at the operating pressure;
      (c) retaining the liquid phase reaction medium in the reactor for further conversion to gaseous ammonia and carbon dioxide, and/or recycling at least a portion of the said reaction medium back into the reactor, a urea dissolver, or the feed solution to the reactor for further conversion;
      (d) withdrawing the gaseous ammonia and carbon dioxide-containing product separated in step (b) at a controlled rate; and
      (e) contacting the gaseous ammonia-containing product with the combustion gas stream at a rate which essentially matches the demand requirement of nitrogen oxides removal in said combustion gas stream;
      characterised in that the temperature in the hydrolysis reactor is not controlled but is allowed to vary to match the demand requirement for ammonia and in which the pressure is varied as function of the demand requirement for ammonia or reactor operating temperature.
    • 一种用于从燃烧气流中除去氮氧化物的方法,该方法包括:(a)在水解反应器中加热尿素水溶液或含有缩二脲或铵氨基甲酸铵的尿素混合物,使得含气态氨 获得基本上不含尿素,缩二脲或氨基甲酸铵的产物,通过向反应器输入热量来维持温度和压力; (b)在操作压力下从气相含水反应介质中分离含气态氨的产物; (c)将液相反应介质保留在反应器中以进一步转化为气态氨和二氧化碳,和/或将至少一部分所述反应介质再循环回反应器,尿素溶解器或向 反应堆进一步转化; (d)以受控的速率取出在步骤(b)中分离出的气态氨和二氧化碳的产品; 和(e)以基本上与所述燃烧气体流中的氮氧化物去除的需求要求基本相匹配的速率使含气态氨的产物与燃烧气体流接触; 其特征在于水解反应器中的温度不受控制,但允许其变化以匹配氨的需求量,其中压力随氨或反应器操作温度的需求要求而变化。