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21. 发明公开

EP2135671A2 Catalyst and method for producing carboxylic acid and/or carboxylic anhydride in the presence of the catalyst 失效
标题翻译：催化剂和方法在催化剂的存在下制备羧酸和/或羧酸酐的
公开(公告)号：EP2135671A2
公开(公告)日：2009-12-23
申请号：EP09162948.5
申请日：2009-06-17
申请人： Mitsubishi Gas Chemical Company, Inc.
发明人： Okamoto, Atsushi
IPC分类号： B01J23/28 , B01J27/199 , B01J27/20 , C07C37/60 , C07C51/15 , C07D493/04
CPC分类号： C07C51/235 , B01J21/18 , B01J23/20 , B01J23/22 , B01J23/24 , B01J23/28 , B01J27/198 , B01J37/0045 , C07C51/265 , C07C63/313
摘要： An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
摘要翻译：本发明的一个目的是提供一种催化剂具有特别在部分氧化反应的优异性能。另一个目的是提供一种通过有机化合物的气相部分氧化通过在催化剂的存在下使用含氧气的气体有效地生产羧酸或羧酸酐的方法。该催化剂含有（1）金刚石; （2）从第5族过渡元素的氧化物，统称氧化物A中选择的至少一种物质; 和（3）从第4族过渡元素的氧化物中选择的至少一种物质，统称氧化物B.用于制造羧酸或羧酸酐的方法，包括：通过使用经受有机化合物气相部分氧化的含氧在催化剂的存在下，worin有机化合物气体是在分子中具有一个或多个取代其的芳香族化合物，均包括在芳环键合到碳原子上的取代基。

22. 发明公开

EP1732681A4 CATALYST COMPOSITION FOR THE SELECTIVE CONVERSION OF ALKANES TO UNSATURATED CARBOXYLIC ACIDS, METHOD OF MAKING AND METHOD OF USING THEREOF 审中-公开
标题翻译：催化剂组合物用于饱和烷烃的不饱和羧酸用于生产和使用它们的方法选择性转化，PROCESS
公开(公告)号：EP1732681A4
公开(公告)日：2009-11-11
申请号：EP05732715
申请日：2005-03-23
申请人： SAUDI BASIC IND CORP , HAZIN PAULETTE N , ELLIS PAUL E
发明人： HAZIN PAULETTE N , ELLIS PAUL E JR
IPC分类号： B01J23/00 , B01J23/08 , B01J23/18 , B01J23/20 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/68 , B01J37/00 , B01J37/02 , C07C51/215 , C07C253/24 , C07C255/08
CPC分类号： B01J23/002 , B01J23/08 , B01J23/18 , B01J23/20 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/686 , B01J37/0036 , B01J37/0045 , B01J37/009 , B01J37/0236 , B01J2523/00 , C07C51/215 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08 , B01J2523/18 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/32 , B01J2523/54 , B01J2523/69 , B01J2523/19

23. 发明公开

EP1651345A4 SUPPORTED CATALYSTS USING NANOPARTICLES AS THE SUPPORT MATERIAL 审中-公开
标题翻译：纳米粒子的负载型催化剂作为载体材料
公开(公告)号：EP1651345A4
公开(公告)日：2009-10-28
申请号：EP04776251
申请日：2004-06-03
申请人： UNIV RICE WILLIAM M
发明人： WONG MICHAEL S , WACHS ISRAEL E , KNOWLES WILLIAM V
IPC分类号： B01J31/00 , B01J20060101 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/36 , B01J31/06 , B01J35/00 , B01J35/10 , B01J37/00 , C04B38/00 , C04B38/02
CPC分类号： B01J35/0013 , B01J21/06 , B01J21/066 , B01J23/20 , B01J23/24 , B01J23/30 , B01J29/0308 , B01J29/041 , B01J31/06 , B01J31/063 , B01J35/10 , B01J35/1061 , B01J35/1085 , B01J37/0018 , B01J37/036 , C01G23/047 , C01G23/0536 , C01G25/00 , C01G31/00 , C01G41/00 , C01P2006/12 , C01P2006/16 , C04B38/02 , C04B2111/0081 , C07C5/3332 , C07C2523/30 , Y02P20/52 , C04B35/48 , C07C11/06

24. 发明授权

EP1286942B1 VERFAHREN UND KATALYSATOR ZUR SELEKTIVEN HERSTELLUNG VON ESSIGSÄURE DURCH KATALYTISCHE OXIDATION VON ETHAN UND/ODER ETHYLEN 有权
标题翻译：方法和催化剂FOR由ETHAN和/或乙烯的催化氧化醋酸的选择性生产
公开(公告)号：EP1286942B1
公开(公告)日：2009-04-22
申请号：EP01940393.0
申请日：2001-05-03
申请人： Celanese International Corporation
发明人： ZEYSS, Sabine , DINGERDISSEN, Uwe
IPC分类号： C07C51/215 , C07C51/25 , B01J23/652 , C07C53/08
CPC分类号： C07C51/25 , B01J23/002 , B01J23/18 , B01J23/20 , B01J23/6525 , B01J37/0045 , B01J2523/00 , C07C51/215 , C07C53/08 , B01J2523/23 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/824
摘要： A method for the selective production of acetic acid from a gas-phase feed of ethane, ethylene, or mixtures thereof and oxygen at elevated temperatures. The gas-phase feed is brought into contact with a catalyst, containing the elements Mo, Pd, X and Y in the gram atom ratios a:b:c: in combination with oxygen according to formula (I): MO a Pd b X c Y d . The symbols X and Y have the following meanings: X=one or several elements chosen from the group Cr, Mn, Nb, Ta, Ti, V, Te and W; Y=one or several elements chosen from the group B, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Ir, Cu, Ag, Au, Fe, Fu, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Nb, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, Ti and U: the indices a, b, c, d and x=the gram atom ration for the corresponding elements, where: a=1; b-0.0001 to 0.01; c=0.4 to 1; and d=0.005 to 1, wherein the space-time yield for the above oxidation to yield acetic acid is 470 kg/(hm 3 ) and the selectivity of the oxidative reaction of ethane and/or ethylene to give acetic acid is, in particular, >=70 mol %. X=preferably Nb and an ammonium salt of niobium is used as niobium source.

25. 发明公开

EP1996676A2 APPARATUS AND METHOD FOR RESUSCITATING AND REVITALIZING HYDROCARBON FUELS 审中-公开
标题翻译：装置和方法，再生和治疗碳氢燃料
公开(公告)号：EP1996676A2
公开(公告)日：2008-12-03
申请号：EP07758925.7
申请日：2007-03-20
申请人： Advanced Power Systems International, Inc.
发明人： BERLIN, Alvin, J. , WRIGHT, Ralph, H.
IPC分类号： C10G31/00
CPC分类号： B01J23/20 , B01J23/14 , B01J23/18 , B01J23/24 , B01J23/626 , C10G2400/04 , C10L1/1208 , C10L1/1216 , C10L1/1233 , C10L1/1283 , C10L10/02 , C10L2200/0476 , C22C13/02 , F23K5/08 , F23K2900/05081
摘要： The invention provides a metal alloy fuel catalyst for decontaminating a hydrocarbon fuel, including diesel and bio-diesel fuel, of a bacterial contamination. The metal alloy fuel catalysts preferably includes about 70% Sn, about 22% Sb, about 4% Bi, and about 4% Pb, although other formulations are possible. The fuel catalyst can take the form of an in-line component in a fuel system or be coated within a fuel storage container.

26. 发明授权

EP1295636B1 Process for producing acrylic acid 有权
标题翻译：生产丙烯酸的方法
公开(公告)号：EP1295636B1
公开(公告)日：2008-10-08
申请号：EP02020181.0
申请日：2002-09-09
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Yunoki, Hiromi
IPC分类号： B01J23/16 , B01J23/68 , B01J23/887 , C07C57/055
CPC分类号： C07C51/252 , B01J23/002 , B01J23/18 , B01J23/20 , B01J23/28 , B01J23/72 , B01J23/8877 , B01J35/0006 , B01J37/0236 , B01J2523/00 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69

27. 发明授权

EP1293479B1 MESO-POROUS TRANSITION METAL OXIDE HAVING CRYSTALLIZED PORE WALL AND METHOD FOR PREPARING THE SAME 有权
标题翻译：生产同样具有晶体多孔壁和方法孔过渡
公开(公告)号：EP1293479B1
公开(公告)日：2008-06-04
申请号：EP00977887.9
申请日：2000-11-24
申请人： Japan Science and Technology Agency
发明人： DOMEN, Kazunari , LI, Byonjin , NOMURA, Junko
IPC分类号： C01G1/00 , B01J23/20
CPC分类号： C01G33/00 , B01J20/06 , B01J20/28083 , B01J23/20 , B01J29/0308 , B01J29/041 , B01J35/10 , B01J35/1061 , B01J37/08 , C01B37/00 , C01G1/00 , C01G1/02 , C01G31/006 , C01P2002/01 , C01P2002/02 , C01P2002/72 , C01P2002/88 , C01P2004/04 , C01P2006/12 , C01P2006/14 , C01P2006/17
摘要： A meso-porous transition metal oxide comprising one or more transition metal oxides, wherein the metal is selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Ru, Cd, In, Sn, Sb, Hf, Ta, W and Re, and the pore wall of the meso pore thereof has a crystalline structure; and a method for preparing the meso-porous transition metal oxide, characterized as comprising a step of carrying out a secondary burning at 600 to 800 °C for 10 minutes to 10 hours.

28. 发明公开

EP1852518A4 PROCESS FOR PRODUCING MULTIFUNCTIONAL MATERIAL 有权
标题翻译：用于生产多功能材料
公开(公告)号：EP1852518A4
公开(公告)日：2008-05-07
申请号：EP06713849
申请日：2006-02-16
申请人： CENTRAL RES INST ELECT
发明人： FURUYA MASAHIRO
IPC分类号： C22F1/18 , B01J21/06 , B01J35/02 , B01J37/02 , C22C14/00
CPC分类号： B01J21/063 , B01J23/14 , B01J23/20 , B01J23/24 , B01J23/8472 , B01J35/002 , B01J35/004 , B01J35/10 , B01J37/0215 , B01J37/08 , B01J37/349 , C22C14/00 , C22F1/18 , C23C8/80 , Y10T428/252
摘要： A process for producing a multifunctional material which has high photocatalytic activity and can easily adsorb even VOCs. The process further produces a multifunctional material having a high film hardness and excellent in heat resistance, corrosion resistance, unsusceptibility to peeling, and wearing resistance. The process comprises: heating a surface of a base having a surface layer made of titanium, titanium oxide, a titanium alloy, or a titanium alloy oxide by applying a combustion flame to the surface so as to result in a surface layer temperature of 600°C or higher or heating the base surface in an oxygenous gas atmosphere so as to result in a surface layer temperature of 600°C or higher to thereby form in an inner part of the surface layer a layer bristling with fine columns made of titanium oxide or a titanium alloy oxide; and then cleaving the layer bristling with the fine columns in a direction parallel to the surface layer. Thus, the following are obtained: a member comprising a base having, in at least part of the surfaces thereof, an exposed layer bristling with fine columns made of titanium oxide or a titanium alloy oxide; and a member comprising a thin film, a projection part formed on the thin film and comprising many continuous narrow-width projections made of titanium oxide or a titanium alloy oxide, and exposed fine columns with which an area over the projection part bristles.

29. 发明公开

EP1852183A1 MULTIFUNCTIONAL MATERIAL 审中-公开
标题翻译：多功能材料
公开(公告)号：EP1852183A1
公开(公告)日：2007-11-07
申请号：EP06713850.3
申请日：2006-02-16
申请人： Central Research Institute of Electric Power Industry
发明人： FURUYA, Masahiro, Nuclear Technology Research Lab.
IPC分类号： B01J35/02 , B01J27/22 , C01G23/00
CPC分类号： B01J35/004 , B01D53/8668 , B01D2255/20707 , B01D2255/802 , B01J20/0211 , B01J20/06 , B01J20/20 , B01J20/28014 , B01J20/28057 , B01J20/28097 , B01J21/063 , B01J21/066 , B01J23/20 , B01J23/24 , B01J27/22 , B01J35/10 , B01J37/0226 , B01J37/349 , Y10T428/24413
摘要： The multifunctional material of the invention can readily adsorb even VOCs, which exhibits high photocatalytic activity and functions as visible-light-responsive photocatalyst by virtue of a large surface area and being doped with carbon, and which has high hardness and exhibits excellent exfoliation resistance, wear resistance, resistance to chemicals, and heat resistance. The multifunctional material has a large number of protrusions of titanium oxide or a titanium alloy oxide on at least a portion of a surface of the material (e.g., forest microcolumns of titanium oxide
摘要翻译：本发明的多功能材料可以容易地吸附甚至具有高光催化活性的VOC，并且由于表面积大并掺杂有碳，可见光响应性光催化剂，并且具有高硬度并且表现出优异的耐剥离性，耐磨性，耐化学性和耐热性。多功能材料在材料表面的至少一部分上具有大量氧化钛或钛合金氧化物的突起（例如，氧化钛的森林微柱

30. 发明公开

EP1833603A1 PROCEDE DE PREPARATION D'ACIDE ACRYLIQUE A PARTIR DU PROPANE, EN ABSENCE DE VAPEUR D'EAU 审中-公开
标题翻译：工艺的生产丙烯酸丙烷在蒸汽缺席
公开(公告)号：EP1833603A1
公开(公告)日：2007-09-19
申请号：EP05826593.5
申请日：2005-12-16
申请人： Arkema France
发明人： DUBOIS, Jean-Luc , GARRAIT, Dominique , LE GALL, Anne , BAZIN, Guy , SERREAU, Stéphanie
IPC分类号： B01J23/00 , B01J23/28 , B01J23/20 , B01J23/18 , B01J27/057 , C07C51/215 , C07C57/04
CPC分类号： B01J37/0045 , B01J23/002 , B01J23/18 , B01J23/20 , B01J23/28 , B01J23/92 , B01J27/0576 , B01J27/30 , B01J38/30 , B01J2523/00 , C07C51/215 , Y02P20/584 , C07C57/04 , B01J2523/41 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： The invention relates to a method of preparing acrylic acid by selective oxidation of propane in a circulating fluidised bed or in a fluidised bed in the presence of a catalyst having structure MolVaXbZcSidOx (I), wherein X represents tellurium or antimony and Z represents niobium or tantalum, and in which: - a is between 0.006 and 1, inclusive; - b is between 0.006 and 1, inclusive; - c is between 0.006 and 1, inclusive; - d is between 0 and 3.5, inclusive; and x is the amount of oxygen bound to the other elements and depends on the oxidation states thereof, which is performed under partial propane conversion conditions and without the introduction of water vapour into the initial gas mixture used to supply the reaction.

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