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21. 发明公开

EP0431328A3 Fungicides 失效
标题翻译：杀菌剂
公开(公告)号：EP0431328A3
公开(公告)日：1991-07-03
申请号：EP90121211.8
申请日：1985-10-03
申请人： ZENECA LIMITED
发明人： Anthony, Vivienne Margaret , Clough, John Martin , De Fraine, Paul , Godfrey, Christopher Richard Ayles , Beautement, Kevin , Bushell, Michael John
IPC分类号： C07C69/00 , C07C57/00
CPC分类号： C07D213/643 , A01N37/36 , A01N37/38 , A01N37/42 , A01N37/44 , A01N37/46 , A01N37/48 , A01N41/10 , A01N43/08 , A01N43/12 , A01N43/40 , C07C69/734 , C07C69/736 , C07C205/56 , C07C255/00 , C07C317/44 , C07C323/56 , C07C323/62 , C07C2601/14 , C07C2603/26 , C07D307/54
摘要： Chemical compounds of the formula:
in which R 1 , X, Y and Z have various specified values. The compounds are useful in the preparation of agricultural acrylic acid derivatives described in EP-A-178826.
摘要翻译：其中R 1，X，Y和Z具有各种规定值的下式的化合物：。该化合物可用于制备EP-A-178826中描述的农业丙烯酸衍生物。

22. 发明公开

EP0387923A3 Fungicides 失效
标题翻译：杀菌剂
公开(公告)号：EP0387923A3
公开(公告)日：1990-10-10
申请号：EP90109068.8
申请日：1987-03-31
申请人： ZENECA LIMITED
发明人： Anthony, Vivienne Margaret , Clough, John Martin , DeFraine, Paul , Godfrey, Christopher Richard Ayles , Ferguson, Ian , Crowley, Patrick Jelf , Hutchings, Michael Gordon
IPC分类号： C07D213/64 , C07D239/00 , A01N43/00
CPC分类号： C07D213/65 , A01N43/40 , A01N43/54 , C07D213/643 , C07D213/66 , C07D213/68 , C07D213/69 , C07D213/70 , C07D213/71 , C07D213/80 , C07D213/84 , C07D213/85 , C07D215/22 , C07D215/227 , C07D239/10 , C07D239/34 , C07D239/38 , C07D239/52 , C07D239/56 , C07D239/58 , C07D239/80
摘要： An intermediate chemical of formula:
in which A is 0 or S(O) n wherein n is 0, 1 or 2; W is a substituted pyridinyl or pyrimidinyl group; R 1 is optionally substituted alkyl and X, Y and Z have various specified values. The chemical is useful for the preparation of agricultural acrylic acid derivatives described in EP-A-242081.

23. 发明公开

EP0267734A3 Chemical compounds 失效
标题翻译：化合物
公开(公告)号：EP0267734A3
公开(公告)日：1990-03-14
申请号：EP87309768.7
申请日：1987-11-04
申请人： ZENECA LIMITED
发明人： Anthony, Vivienne Margaret , Clough, John Martin , Godfrey, Christopher Richard Ayles
IPC分类号： C07C69/734 , C07C67/343 , C07C67/31 , A01N37/10
CPC分类号： A01N37/36 , A01N43/32 , C07D319/24 , C07D327/08 , C07D339/08
摘要： Compounds of the formula:
and stereoisomers thereof wherein X and Y, which are the same or different, are hydrogen, halogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted aryloxy, optionally substituted heteroaryloxy, optionally substituted arylalkoxy, optionally substituted heteroarylalkoxy, optionally substituted acyloxy, optionally substituted amino, acylamino, nitro, cyano, -CO₂R³, -CONR⁴R⁵, or -COR⁶, except that X and Y are not both hydrogen; R¹ and R², which are the same or different, are alkyl or fluoroalkyl; and R³, R⁴, R⁵ and R⁶, which are the same or different, are hydrogen, alkyl, alkenyl, alkynyl, optionally substituted aryl, optionally substituted aralkyl, or cycloalkylalkyl. The compounds are useful in agriculture, especially as fungicides but also as plant growth regulators, insecticides and miticides.
摘要翻译：下式的化合物及其立体异构体，其中X和Y相同或不同，为氢，卤素，任选取代的烷基，任选取代的环烷基，任选取代的环烷基烷基，任选取代的烯基，任选取代的炔基，任选取代的芳基，任选取代的杂芳基，任选取代的烷氧基，任选取代的芳氧基，任选取代的杂芳氧基，任选取代的芳基烷氧基，任选取代的杂芳基烷氧基，任选取代的酰氧基，任选取代的氨基，酰基氨基，硝基，氰基，和Y不都是氢; R 1和R 2相同或不同，是烷基或氟代烷基; R 3，R 4，R 5和R 6可以相同或不同，为氢，烷基，链烯基，炔基，任意取代的芳基，任意取代的芳烷基或环烷基烷基。这些化合物可用于农业，特别是作为杀真菌剂，但也可用作植物生长调节剂，杀虫剂和杀螨剂。

24. 发明公开

EP0307103A2 Fungicides 失效
标题翻译： Schimmelbekämpfungsmittel。
公开(公告)号：EP0307103A2
公开(公告)日：1989-03-15
申请号：EP88307746.3
申请日：1988-08-22
申请人： ZENECA LIMITED
发明人： Anthony, Vivienne Margaret , Heaney, Stephen Paul , Beautement, Kevin , Clough, John Martin , Crowley, Patrick Jelf , Godfrey, Christopher Richard Ayles , de Fraine, Paul John , Buckley, Alan John , Hutchings, Michael Gordon , Ferguson, Ian
IPC分类号： C07C69/736 , C07C323/62 , C07C315/00 , C07C229/44 , C07C69/72 , C07C381/00 , C07C309/63 , C07C67/327 , A01N37/38 , A01N41/10
CPC分类号： C07D213/64 , A01N37/38 , A01N37/40 , A01N41/04 , A01N41/06 , A01N41/10 , A01N43/10 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , A01N43/66 , A01N43/74 , A01N43/90 , A01N47/20 , A01N57/24 , C07C45/59 , C07C205/35 , C07C205/37 , C07C205/38 , C07C205/52 , C07C217/92 , C07C233/25 , C07C233/75 , C07C235/56 , C07C245/08 , C07C251/24 , C07C251/48 , C07C255/54 , C07C271/28 , C07C311/29 , C07C317/22 , C07C323/20 , C07C327/16 , C07D207/34 , C07D213/643 , C07D213/65 , C07D213/68 , C07D213/74 , C07D213/85 , C07D213/89 , C07D215/227 , C07D215/36 , C07D231/12 , C07D233/56 , C07D237/14 , C07D239/34 , C07D239/38 , C07D239/60 , C07D241/18 , C07D241/44 , C07D249/08 , C07D251/26 , C07D263/58 , C07D277/24 , C07D277/68 , C07D333/56 , C07D495/04 , C07F9/5456 , C07C47/575
摘要： Fungicidal compounds of the formula (I) :
and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is 0, S(O) n , NR 4 , CR'R 2 , CHR S , CO, CR'(OR 2 ), C=CR 1 R 2 , CHR 1 CHR 2 , CR' =C R 2 , CHR 1 CR 2 =CH, C-C, OCHR', CHR'O, OCHR'O, S(O) n CHR', S(O) n CHR'O, CHR'S(0) n , CHR 1 OSO 2 , NR 4 CHR 1 , CHR 1 NR 4 , C0 2 , 0 2 C, S0 2 0, OSO 2 , CO.CO, COCHR', COCHR'O, CHR'CO, CHOH.CHR 1 , CHR'.CHOH,
CONR 4 , OCONR 4 , NR 4 CO, CSNR 4 , OCS.NR4, SCO.NR 4 , NR 4 CO 2 , NR 4 CS, NR 4 CSO, NR4COS, NR4CONR4, S(O) n NR 4 , NR 4 S(O) n , CS 2 , S 2 C, CO.S, SCO, N=N, N=CR 1 , CR 1 =N, CHR 1 CHR 2 CH(OH), CHR'OCO, CHR'SCO, CHR 1 NR 4 CO, CHR'NR 4 COR 4 , CHR'CHR 2 CO, O.N=CR', CHR 1 O.N=CR 2 , CO.OCR'R 2 , CHR'CHR 2 CHR 3 , OCHR 1 CHR 2 , (CH 2 ) m O, CHR 1 OCHR 2 , CHR'CHR 2 0, OCHR'CHR 2 0, S(O)- n CHR 1 CHR 1 , CHR 1 S(O) n CHR 2 , CHR'CHR 2 S(O) n . CR 1 =NNR 4 . NR 4 N=CR 1 , CHR 1 CONR 2 , CHR 1 OCO.NR 2 , CH=CHCH 2 O, COCHR 1 CHR 2 O or (R 5 ) 2 P + CHR 2 Q-; A, B and E, which may be the same or different, are H, hydroxy, halo, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, C 1-4 alkylcarbonyl, C 1-4 alkoxycarbonyl, phenoxy, nitro or cyano; R', R 2 and R 3 , which may be the same or different, are H, C 1-4 alkyl or phenyl; R 4 is H, C 1-4 alkyl or COR'; R 5 is optionally substituted phenyl; Q- is a halide anion; n is 0, 1 or 2 and m is a 3, 4 or 5; except that when Z is unsubstituted phenyl and X and K are oxygen, A, B and E are not all hydrogen.
摘要翻译：式（I）的杀真菌化合物：及其立体异构体，其中K是氧或硫; Z是任选取代的芳基或任选取代的杂芳基; X是O，S（O）n，NR 4，CR 1 R 2，CHR 5，CO，CR 1（OR 2），C = CR 1 R CH 2，CHR 1 CHR 2，CR 1 = CR 2，CHR 1 CR 2 = CH，C标识C，OCHR 1，CHR 1 O，OCHR 1 O，S（O）n CHR 1，S（O）n CHR 1 O，CHR 1 S（O）n，CHR 1 OSO 2，NR 4 CHR 1，CHR < 1，NR 4，CO 2，O 2 C，SO 2 O，OSO 2，CO.CO，COCHR 1，COCHR 1 O，CHR 1 CO，CHOH.CHR 1，CHR 1，CHOH， OCONR 4，NR 4 CO，CSNR 4，OCS.NR 4，SCO.NR 4，NR 4 CO 2，NR 4 CS， NR 4，CSO，NR 4，COS，NR 4 CONR 4，S（O）n NR 4，NR 4 S（O）n，CS 2， N = N，N = CR 1，CR 1 = N，CHR 1 CHR 2 CH（OH），CHR 1 OCO，CHR 1 SCO，CHR 1 NR 4 CO，CHR 1 NR 4 COR 4，CHR 1 CHR 2 CO，ON = CR 1，CHR 1 ON = CR 2，COOOR 1， R 2，CHR 1 CHR 2 CHR 3，OCHR 1 CHR 2，（CH 2）m O，CHR 1 OCHR 2，CHR 1 CHR 2 O ，OCHR 1 CHR 2 O，S（O）n CHR 1 CHR 2，CHR 1 S（O）n CHR 2，CHR 1 CHR 2 S（O）n ，CR 1 = NNR 4，NR 4 N = CR 1，CHR 1 CONR 2，CHR 1 OCO.NR 2，CH = CHCH 2 O，COCHR 1， CHR 2 O或（R 5）2 P + CHR 2 Q - ; A，B和E可以相同或不同，是H，羟基，卤素，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基，C 1-4卤代烷氧基，C 1-4烷基羰基，C 1-4烷氧基羰基，苯氧基，硝基或氰基; R 1，R 2和R 3可以相同或不同，是H，C 1-4烷基或苯基; R 4是H，C 1-4烷基或COR 1; R 5是任选取代的苯基; Q是卤化物阴离子; n为0,1或2，m为3,4或5; 除了当Z是未取代的苯基且X和K是氧时，A，B和E不都是氢。

25. 发明公开

EP0267734A2 Chemical compounds 失效
标题翻译： Chemische Verbindungen。
公开(公告)号：EP0267734A2
公开(公告)日：1988-05-18
申请号：EP87309768.7
申请日：1987-11-04
申请人： ZENECA LIMITED
发明人： Anthony, Vivienne Margaret , Clough, John Martin , Godfrey, Christopher Richard Ayles
IPC分类号： C07C69/734 , C07C67/343 , C07C67/31 , A01N37/10
CPC分类号： A01N37/36 , A01N43/32 , C07D319/24 , C07D327/08 , C07D339/08
摘要： Compounds of the formula:
and stereoisomers thereof wherein X and Y, which are the same or different, are hydrogen, halogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted aryloxy, optionally substituted heteroaryloxy, optionally substituted arylalkoxy, optionally substituted heteroarylalkoxy, optionally substituted acyloxy, optionally substituted amino, acylamino, nitro, cyano, -CO₂R³, -CONR⁴R⁵, or -COR⁶, except that X and Y are not both hydrogen; R¹ and R², which are the same or different, are alkyl or fluoroalkyl; and R³, R⁴, R⁵ and R⁶, which are the same or different, are hydrogen, alkyl, alkenyl, alkynyl, optionally substituted aryl, optionally substituted aralkyl, or cycloalkylalkyl.
The compounds are useful in agriculture, especially as fungicides but also as plant growth regulators, insecticides and miticides.
摘要翻译：下式的化合物及其立体异构体，其中X和Y相同或不同，为氢，卤素，任选取代的烷基，任选取代的环烷基，任选取代的环烷基烷基，任选取代的烯基，任选取代的炔基，任选取代的芳基，任选取代的杂芳基，任选取代的烷氧基，任选取代的芳氧基，任选取代的杂芳氧基，任选取代的芳基烷氧基，任选取代的杂芳基烷氧基，任选取代的酰氧基，任选取代的氨基，酰氨基，硝基，氰基，-CO 2 R 3，-CONR 4 R 5或-COR 6，除了X和Y不同时为氢; R 1和R 2相同或不同，是烷基或氟代烷基; 和R 3，R 4，R 5和R 6相同或不同，是氢，烷基，烯基，炔基，任选取代的芳基，任选取代的芳烷基或环烷基烷基。这些化合物可用于农业，特别是杀真菌剂，也可用作植物生长调节剂，杀虫剂和杀螨剂。

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