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    • 21. 发明公开
    • PROCESS FOR PRODUCING THERMOPLASTIC RESIN COMPOSITION
    • VERFAHREN ZUR HERSTELLUNG EINER THERMOPLASTISCHEN HARZZUSAMMENSETZUNG
    • EP3026081A1
    • 2016-06-01
    • EP14830260.7
    • 2014-07-25
    • The Yokohama Rubber Co., Ltd.
    • SATO, Shun
    • C08L23/26B60C5/14F16L11/04
    • C08L23/26B60C1/0008C08L23/0861C08L51/06C08L77/00C08L2205/03F16L11/04
    • A process for producing a thermoplastic resin composition in which the continuous phase comprises an ethylene/vinyl alcohol copolymer (A) and a polyamide resin (B) and the dispersed phase comprises an acid-modified polyolefin elastomer (C), the process being characterized by comprising: step (I) in which an ethylene/vinyl alcohol copolymer (A) and an acid-modified polyolefin elastomer (C) are kneaded to form a mixture in which the acid-modified polyolefin elastomer (C) has been dispersed in the ethylene/vinyl alcohol copolymer (A); step (II) in which a polyamide resin (B) is subsequently added to the mixture obtained in step (I), and the resultant mixture is further kneaded; and step (III) in which a terminal-blocking agent (D) for the polyamide resin (B) is subsequently added to the mixture obtained in step (II) in an amount of 0.1-5 parts by mass per 100 parts by mass of the polyamide resin (B), and the resultant mixture is melt-kneaded at a temperature not lower than the melting point of the polyamide resin (B).
    • 一种热塑性树脂组合物的制造方法,其中连续相包含乙烯/乙烯醇共聚物(A)和聚酰胺树脂(B),分散相包含酸改性聚烯烃弹性体(C),该方法的特征在于 包括:其中将乙烯/乙烯醇共聚物(A)和酸改性聚烯烃弹性体(C)捏合以形成其中酸改性聚烯烃弹性体(C)已经分散在乙烯中的混合物的步骤(I) /乙烯醇共聚物(A); 随后将步骤(II)中的聚酰胺树脂(B)加入到步骤(I)中获得的混合物中,并将所得混合物进一步捏合; 和步骤(III),其中随后将在步骤(II)中获得的混合物中加入聚酰胺树脂(B)的封端剂(D),相对于每100质量份的 聚酰胺树脂(B),所得混合物在不低于聚酰胺树脂(B)的熔点的温度下熔融捏合。