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    • 14. 发明公开
    • EP0746651A4 -
    • CN102166204A - - Google专利
    • EP0746651A4
    • 1997-01-15
    • EP93906003
    • 1993-02-16
    • C01B17/22D21C3/02D21C3/26D21C11/00D21C11/04D21C11/06D21C11/10D21C11/12
    • D21C3/022D21C3/26D21C11/0064D21C11/04D21C11/06D21C11/12Y10S423/03
    • Off gases (11) from black liquor heat treatment (10) evaporators, wood pulp digesters, etc. are treated to produce primarily hydrogen sulfide and sulfur free fuel gases such as methane, carbon monoxide, hydrogen, and ethylene. Then the hydrogen sulfide is used to produce sodium polysulfide in white liquor for cooking wood chips to produce pulp by the kraft process. Polysulfide may be formed in three different ways: by supplying air to a fuel cell (15) into which white liquor and the hydrogen sulfide containing gas have been introduced; by bringing clarified white liquor and hydrogen sulfide containing gas into contact with a wet-proofed activated carbon catalyst and oxygen containing gas; or by bringing unclarified white liquor into contact with the gas and oxygen containing gas, with lime mud acting as a catalyst, and then clarifying the polysulfide-rich white liquor produced to remove the lime mud. The white liquor produced contains about 0.5-8% on wood sodium polysulfide.
    • 处理来自黑液热处理(10)蒸发器,木浆蒸煮器等的废气(11)主要产生硫化氢和不含硫的燃料气体,例如甲烷,一氧化碳,氢气和乙烯。 然后使用硫化氢在白液中生产多硫化钠,用于烹饪木片以通过硫酸盐法生产纸浆。 可以通过三种不同的方式形成多硫化物:向已经引入白液和含硫化氢气体的燃料电池(15)供应空气; 将澄清的白液和含硫化氢气体与防湿活性炭催化剂和含氧气体接触; 或者通过将未澄清的白液与含气体和含氧气体接触,用作为催化剂的石灰泥,然后澄清所产生的富含多硫化物的白液以除去白泥。 所产生的白液在木多硫化钠上含有约0.5-8%。
    • 16. 发明公开
    • A method in the activation of lignocellulosic material with a gas containing nitrogen dioxide
    • Verfahren in der Aktivierung von Lignocellulose Materials mit einem Stickstoffdioxid enthaltenden Gas。
    • EP0309998A2
    • 1989-04-05
    • EP88115896.8
    • 1988-09-27
    • MO OCH DOMSJÖ AKTIEBOLAG
    • Samuelson, Hans Olof, Prof.
    • D21C11/06D21C9/00D21C9/10
    • D21C1/00D21C11/06
    • Method of activating aqueous lignocellulosic material with a gas containing nitrogen oxide, followed by a delignification stage for the purpose of obtaining a high quality end product with no or only a slight effect on the environment. In accordance with the inventive method, the lignocellulosic material is brought into contact (18) with an oxygen-containing gas (19), and activating gas is separated from the lignocellulosic material during and/or subsequent to the activating process (9). The method is characterized by a) controlling the supply of oxygen-containing gas (12) such that the separated gas (27) contains at least 2 kg nitric oxide (NO) calculated on 1000 kg of dry lignocellulosic material, and by b) reacting the separated gas (27) in one or more stages (26) with absorption solution (25) whose original pH lies within the range 3-13.5, and by passing (28) the gas purified with the aid of absorption solution to atmosphere, or to a destruction plant optionally subsequent ot further purification of the gas.
    • 用含有氮氧化物的气体活化含水木质纤维素材料的方法,然后进行脱木质阶段,以获得对环境没有或仅对环境产生轻微影响的高质量终产物。 根据本发明的方法,使木质纤维素材料与含氧气体(19)接触(18),并且在活化过程(9)期间和/或之后将活化气体与木质纤维素材料分离。 该方法的特征在于a)控制含氧气体(12)的供应,使得分离的气体(27)含有至少2kg的在1000kg干木质纤维素材料上计算的一氧化氮(NO),以及b)使 在一个或多个阶段(26)中分离的气体(27)具有吸收溶液(25),其原始pH在3-13.5范围内,并且通过(28)将借助于吸收溶液净化的气体通过气氛,或 任选地随后进一步净化气体。
    • 17. 发明公开
    • A method for delignification of pulp
    • Ein Verfahren zur Delignifizierung von Zellstoff。
    • EP0225638A1
    • 1987-06-16
    • EP86117166.8
    • 1986-12-09
    • MO OCH DOMSJÖ AKTIEBOLAG
    • Samuelson, Hans Olof
    • D21C11/06D21C9/00
    • D21C11/06
    • The present invention solves the problems encountered when charging oxygen (0 2 ) to and removing inert gas from the reactor gas obtained in the activation of lignocellulosic material with gas that contains nitrogen dioxide (N0 2 ) and subsequent delignification of the material, the material being preferably in the form of chemical, aqueous cellulose pulp. The invention resides in a method which is characterized by separating (5) gas rich in nitrogen oxides from the lignocellulosic material during and/or after the activation thereof; by treating (6) all or part of the separated gas rich in nitrogen oxides with oxygen (7) in an amount corresponding to 10-200 mole percent calculated on the amount of nitric oxide (NO) present in the gas rich in nitrogen oxides separated for this treatment; by bringing (8) oxygen-treated gas into contact with lignocellulosic material so as to activate the material; and by separating gas lean in nitrogen oxides from the lignocellulosic material during a stage of the activation process different to that from which gas rich in nitrogen oxides was taken; and by removing (9) gas lean in nitrogen oxides from the process.
    • 本发明解决了在用包含二氧化氮(NO 2)的气体和随后的材料脱木质素在木质纤维素材料活化中获得的反应器气体中加入氧气(O 2)并除去惰性气体时遇到的问题,该材料优选在 化学,水性纤维素纸浆的形式。 本发明在于一种方法,其特征在于在其活化期间和/或之后从木质纤维素材料中分离(5)富含氮氧化物的气体; 通过处理(6)富含氮氧化物的全部或部分富含氮氧化物的氧气(7),其数量对应于存在于富含氮氧化物的气体中的一氧化氮(NO)的量为10-200摩尔% 用于治疗; 通过使氧处理气体(8)与木质纤维素材料接触以使材料活化; 并且在活化过程的阶段通过分离来自木质纤维素材料的氮氧化物中的贫气,与从其中获得富含氮氧化物的气体不同; 并通过从工艺中除去(9)贫氮气中的氮气。