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11. 发明公开

EP3103819A4 PRODUCTION METHOD OF (METH)ACRYLIC RESIN COMPOSITION 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG EINER（METH）ACRYLHARZZUSAMMENSETZUNG
公开(公告)号：EP3103819A4
公开(公告)日：2017-10-04
申请号：EP15745810
申请日：2015-02-06
申请人： KURARAY CO
发明人： KITADE YASUHITO , OZAWA HIROSHI , TANAKA SHOUJI
IPC分类号： C08F2/02 , C08F20/14 , C08F120/14 , C08F220/14
CPC分类号： C08F20/68 , C08F2/02 , C08F20/14 , C08F120/14 , C08F220/14 , C08F220/18 , C08L33/06
摘要： A (meth) acrylic resin composition is obtained by a method that comprises: preparing a liquid starting material (A) comprising methyl methacrylate, an acrylic acid alkyl ester and a chain transfer agent, having a mass ratio of the acrylic acid alkyl ester to the methyl methacrylate of 0/100 to 20/80, and having a dissolved oxygen concentration of not more than 50 ppm, preparing a liquid starting material (B) comprising a radical polymerization initiator, a polymerization inhibitor and methyl methacrylate, and having been maintained at a temperature of not more than 10°C in the presence of oxygen, continuously feeding the liquid starting material (A) and the liquid starting material (B) into a tank reactor, allowing bulk polymerization to proceed in the tank reactor at a polymerization conversion ratio of 40 to 70 % by mass to give a reaction product, and continuously discharging the reaction product from the tank reactor.
摘要翻译：（甲基）丙烯酸树脂组合物通过以下方法获得：制备包含甲基丙烯酸甲酯，丙烯酸烷基酯和链转移剂的液体原料（A），所述液体原料（A）的丙烯酸烷基酯与甲基丙烯酸甲酯为0/100〜20/80，溶解氧浓度为50ppm以下，制备含有自由基聚合引发剂，阻聚剂和甲基丙烯酸甲酯的液体原料（B），并保持在在氧气存在下温度不超过10℃，将液体原料（A）和液体原料（B）连续加入罐式反应器中，在罐式反应器中进行本体聚合，进行聚合转化比例为40〜70质量％，得到反应生成物，并从罐式反应器连续地排出反应生成物。

12. 发明公开

EP2768872A4 METHYLENE BETA-KETOESTER MONOMERS, METHODS FOR MAKING METHYLENE BETA-KETOESTER MONOMERS, POLYMERIZABLE COMPOSITIONS AND PRODUCTS FORMED THEREFROM 有权
标题翻译：亚甲基β-酮酯单体，用于生产亚甲基β-酮酯单体，可聚合的组合物以及它们的生产的商品
公开(公告)号：EP2768872A4
公开(公告)日：2015-08-26
申请号：EP12846728
申请日：2012-10-18
申请人： SIRRUS INC
发明人： MALOFSKY BERNARD MILES , MALOFSKY ADAM GREGG , DEY TANMOY , SULLIVAN JEFFREY M
IPC分类号： C08F16/36 , C07C69/38 , C07D307/46 , C07D333/22
CPC分类号： C08F20/28 , C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/03 , C07C67/30 , C07C69/604 , C07C69/738 , C07D307/46 , C07D307/54 , C07D333/22 , C07D333/24 , C08F20/14 , C08F20/30 , C08F20/38 , C08F20/68 , C08F22/20 , C08F24/00 , C08F28/06 , C08F116/36 , C08F128/06 , C08F222/1006 , C08F222/14 , C08K3/0033 , C08K3/013 , C08K5/0008 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D4/00 , C09D129/12 , C09D133/14 , C09D133/16 , C09D135/02 , C09D141/00 , C09J133/06 , C09J133/14 , C09J133/16 , C09J135/02 , Y02P20/127
摘要： The present invention provides methylene beta-ketoester monomers, methods for producing the same, and compositions and products formed therefrom. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester is reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to further processing, which may be vaporization by contact with an energy transfer means in order to isolate the beta-ketoester monomer. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).
摘要翻译：本发明提供的多官能单体，包括但不限于包括多官能亚甲基丙二酸酯和亚甲基β-酮酯单体; 其制造方法; 和组合物以及产品由其形成。本发明的多官能单体可以通过酯交换反应或通过从单官能单体亚甲基丙二酸二乙酯或亚甲基β-酮酯单体直接合成来制造。本发明进一步的组合物和产品的本发明的亚甲基β-酮酯单体，包括基于单体产品（例如，油墨，粘合剂，涂料，密封剂或反应性模塑）和基于聚合物的产品（例如，纤维，膜，片形成，医疗聚合物，复合材料的聚合物和表面活性剂）。

13. 发明授权

EP0128701B1 Acrylate and methacrylate monomers and polymers and process for thermoformed articles 失效
标题翻译：丙烯酸酯和甲基丙烯酸酯单体和聚合物及其热处理方法
公开(公告)号：EP0128701B1
公开(公告)日：1989-08-02
申请号：EP84303636.9
申请日：1984-05-30
申请人： MINNESOTA MINING AND MANUFACTURING COMPANY
发明人： Hammar, W. James
IPC分类号： C07C69/653 , C08F20/28 , C08J5/00
CPC分类号： C08F20/68 , C07F7/1852 , G02B1/043 , C08L33/16

14. 发明授权

EP2871192B1 POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND 有权
公开(公告)号：EP2871192B1
公开(公告)日：2018-06-20
申请号：EP13816607.9
申请日：2013-05-30
申请人： Zeon Corporation
发明人： SAKAMOTO Kei , KIRIKI Satoshi , OKUYAMA Kumi , TAIRA Kanako
IPC分类号： C07D277/82 , C07D277/84 , C07D417/12 , C07D513/04 , C08F20/36 , C08L33/08 , G02B5/30
CPC分类号： C07D277/82 , C07C69/753 , C07C251/86 , C07C2601/14 , C07D277/84 , C07D417/12 , C07D513/04 , C08F20/36 , C08F20/68 , C08F22/105 , C08F22/14 , C08F22/20 , C08F22/22 , C08F22/24 , C08F22/26 , C08F26/06 , C08F28/06 , C08F2500/26 , C09K19/0403 , C09K2019/0414 , C09K2019/0481 , G02B5/30 , G02F1/137 , G02F2202/022 , G02F2202/40
摘要： The present invention is a polymerizable compound (I), a polymerizable composition comprising the polymerizable compound and an initiator, a polymer obtained by polymerizing the polymerizable compound or polymerizable composition, an optically anisotropic article comprising the polymer, a carbonyl compound (4), a method for producing a polymerizable compound (I), the method comprising reacting the carbonyl compound (4) with a hydrazine compound, and a method for using the carbonyl compound (4) as a raw material for producing a polymerizable compound (I). According to the present invention, provided is a polymerizable compound or the like that has a practical low melting point, exhibit excellent solubility in a general-purpose solvent, and can produce an optical film that can be produced at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. Also provided is a carbonyl compound or the like that is useful as a raw material for producing the polymerizable compound, a method for producing the polymerizable compound using the carbonyl compound or the like. (In the formula (I), Y 1 to Y 8 represent -C(=O)-O-, or the like, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group or the like, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group that includes at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group or the like, A 1 represents a trivalent aromatic group or the like, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group or the like, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom or the like.)

15. 发明公开

EP3103819A1 PRODUCTION METHOD OF (METH)ACRYLIC RESIN COMPOSITION 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG EINER（METH）ACRYLHARZZUSAMMENSETZUNG
公开(公告)号：EP3103819A1
公开(公告)日：2016-12-14
申请号：EP15745810.0
申请日：2015-02-06
申请人： Kuraray Co., Ltd.
发明人： KITADE, Yasuhito , OZAWA, Hiroshi , TANAKA, Shouji
IPC分类号： C08F2/02 , C08F20/14
CPC分类号： C08F20/68 , C08F2/02 , C08F20/14 , C08F120/14 , C08F220/14 , C08F220/18 , C08L33/06
摘要： A (meth) acrylic resin composition is obtained by a method that comprises: preparing a liquid starting material (A) comprising methyl methacrylate, an acrylic acid alkyl ester and a chain transfer agent, having a mass ratio of the acrylic acid alkyl ester to the methyl methacrylate of 0/100 to 20/80, and having a dissolved oxygen concentration of not more than 50 ppm, preparing a liquid starting material (B) comprising a radical polymerization initiator, a polymerization inhibitor and methyl methacrylate, and having been maintained at a temperature of not more than 10°C in the presence of oxygen, continuously feeding the liquid starting material (A) and the liquid starting material (B) into a tank reactor, allowing bulk polymerization to proceed in the tank reactor at a polymerization conversion ratio of 40 to 70 % by mass to give a reaction product, and continuously discharging the reaction product from the tank reactor.
摘要翻译：通过以下方法获得（甲基）丙烯酸树脂组合物：包括：制备包含甲基丙烯酸甲酯，丙烯酸烷基酯和链转移剂的液体原料（A），其具有丙烯酸烷基酯与甲基丙烯酸甲酯为0/100至20/80，溶解氧浓度不大于50ppm，制备包含自由基聚合引发剂，阻聚剂和甲基丙烯酸甲酯的液体原料（B），并保持在在存在氧气的情况下不超过10℃的温度，将液体原料（A）和液体原料（B）连续进料到罐式反应器中，从而允许本体聚合在釜式反应器中进行聚合转化比例为40〜70质量％，得到反应产物，并从反应器中连续排出反应产物。

16. 发明公开

EP2941444A1 PREPARATION OF LOW-VISCOSITY POLYMERS 审中-公开
标题翻译：生产低粘度的聚合物
公开(公告)号：EP2941444A1
公开(公告)日：2015-11-11
申请号：EP13818215.9
申请日：2013-12-19
申请人： Evonik Oil Additives GmbH
发明人： SIRAK, Sofia M. , RADANO, Christopher Paul
IPC分类号： C08F20/18 , C08F20/68 , C08F2/38 , C10M145/14 , C08F10/14 , C10M107/10 , C08L23/24 , C08L33/06
CPC分类号： C08F222/10 , C08F2/38 , C08F10/14 , C08F20/18 , C08F20/68 , C08F220/18 , C08L23/24 , C08L33/06 , C10M107/10 , C10M107/28 , C10M145/14 , C10M2209/0845 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/033 , C10M2205/0285 , C08F210/14 , C08F2220/1883 , C08F2220/1875 , C08F2500/17
摘要： The present invention relates to a method for preparing a polymer composition, said method comprising the steps of: a) preparing a reaction mixture comprising as component A) an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers and as component B) a 1-alkene or a mixture of 1-alkenes; b) adding a Co(ll) complex as a catalytic chain transfer agent to the reaction mixture; c) adding a radical initiator; and d) reacting the reaction mixture to obtain the polymer composition, wherein the total amount of the radical initiator added to the reaction mixture is at least 0.05% by weight relative to the total weight of components A) and B). The present invention also relates to the use of a Co(ll) complex as catalytic chain transfer agent for the polymerization of a reaction mixture comprising an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers, a radical initiator, and a 1-alkene or a mixture of 1-alkenes, wherein the total amount of the radical initiator added to the reaction mixture is at least 0.05% by weight relative to the total weight of the ethylenically unsaturated monomer or mixture of ethylenically unsaturated monomers and the 1-alkene or mixture of 1-alkenes.

17. 发明公开

EP2599807A4 SYNTHESIS METHOD OF POLYCARBOXYLIC ACID WATER-REDUCING AGENT 审中-公开
标题翻译：合成方式，一种是聚减水剂
公开(公告)号：EP2599807A4
公开(公告)日：2015-07-29
申请号：EP10855151
申请日：2010-10-29
申请人： SHANGHAI TAIJIE CHEMICAL CO LTD
发明人： FANG JIAN
IPC分类号： C08F290/06 , C04B24/16 , C04B24/24 , C04B24/26 , C04B103/30 , C08F2/38 , C08F6/02 , C08F20/06 , C08F20/68 , C08F22/20 , C08F26/02
CPC分类号： C08F26/02 , C04B24/165 , C04B24/2647 , C04B24/2658 , C04B2103/302 , C08F2/38 , C08F6/02 , C08F20/06 , C08F20/68 , C08F22/20 , C08F290/06
摘要： A method for synthesizing concrete polycarboxylic acid water-reducing agent at room temperature under non-stirring situation is disclosed, which comprises dissolving reactive materials, initiator, chain transfer agent and promoter into a solvent, reacting on standing at 0-50°C; then adding neutralizing agent at the end of reaction. The method makes use of oxidation-reduction system reacting at low temperature, and can adapt to a variety of reactive material monomers. It does not need to control feeding speed or provide extra heating, does not need to stir during the reaction, and remarkably simplifies operation steps in traditional process, which makes it possible to not only produce in large scale, but also produce in small scale in concrete construction site at any moment.

18. 发明授权

EP2630193B1 HYBRID SILICONE COMPOSITION FOR LIGHT EMITTING DEVICE 有权
标题翻译：混合硅组合物技术发光器件
公开(公告)号：EP2630193B1
公开(公告)日：2015-04-15
申请号：EP10858537.3
申请日：2010-10-19
申请人： Ablestik (Shanghai) Limited , Henkel AG & Co. KGaA
发明人： ZHOU, Jing , GILLISSEN, Stijn , LEYSSENS, Karen , PLANTENBERG, Thomas , DUNEKAKE, Ralf , BORQUE, Leticia
IPC分类号： C08L83/04 , C08G77/04 , H01L23/29 , C08F283/12
CPC分类号： C08F20/68 , C08F283/124 , C08G77/20 , C08L83/06 , H01L23/296 , H01L33/56 , H01L2924/0002 , H01L2924/00

19. 发明公开

EP2768872A1 METHYLENE BETA-KETOESTER MONOMERS, METHODS FOR MAKING METHYLENE BETA-KETOESTER MONOMERS, POLYMERIZABLE COMPOSITIONS AND PRODUCTS FORMED THEREFROM 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG冯甲基 - BETA-KETOESTER-MONOMEREN
公开(公告)号：EP2768872A1
公开(公告)日：2014-08-27
申请号：EP12846728.9
申请日：2012-10-18
申请人： Bioformix LLC
发明人： MALOFSKY, Bernard Miles , MALOFSKY, Adam Gregg , DEY, Tanmoy , SULLIVAN, Jeffrey M.
IPC分类号： C08F16/36
CPC分类号： C08F20/28 , C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/03 , C07C67/30 , C07C69/604 , C07C69/738 , C07D307/46 , C07D307/54 , C07D333/22 , C07D333/24 , C08F20/14 , C08F20/30 , C08F20/38 , C08F20/68 , C08F22/20 , C08F24/00 , C08F28/06 , C08F116/36 , C08F128/06 , C08F222/1006 , C08F222/14 , C08K3/013 , C08K5/0008 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D4/00 , C09D129/12 , C09D133/14 , C09D133/16 , C09D135/02 , C09D141/00 , C09J133/06 , C09J133/14 , C09J133/16 , C09J135/02 , Y02P20/127
摘要： The present invention provides methylene beta-ketoester monomers, methods for producing the same, and compositions and products formed therefrom. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester is reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to further processing, which may be vaporization by contact with an energy transfer means in order to isolate the beta-ketoester monomer. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).
摘要翻译：本发明提供多官能单体，包括但不限于多官能亚甲基丙二酸酯和亚甲基β-酮酯单体; 生产方法; 以及由其形成的组合物和产品。本发明的多官能单体可以通过酯交换或通过从单官能亚甲基丙二酸酯单体或亚甲基β-酮酯单体的直接合成来制备。本发明还包括由本发明的亚甲基β-酮酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和基于聚合物的产品（例如纤维，薄膜，片材，医用聚合物，复合聚合物和表面活性剂）。

20. 发明公开

EP2688988A2 FUNCTIONALIZED MONOMERS 审中-公开
标题翻译：官能化的单体
公开(公告)号：EP2688988A2
公开(公告)日：2014-01-29
申请号：EP12711540.0
申请日：2012-03-23
申请人： Elevance Renewable Sciences, Inc.
发明人： DIBIASE, Stephen, Augustine , RIZVI, Syed, Q., A. , HATEGAN, Georgeta
IPC分类号： C10M129/72 , C10M133/16 , C10M159/20 , C10L1/18 , C10L1/22 , C11C3/00 , C08F20/14 , C08F20/68 , C08F210/14 , C10N10/02 , C10N10/04 , C10N10/06 , C10N10/08 , C10N10/10 , C10N20/02 , C10N30/06 , C10N40/25
CPC分类号： C07D307/60 , C08F20/14 , C08F20/68 , C08F120/04 , C08F120/10 , C08F122/105 , C08F210/14 , C08F2220/1866 , C08F2222/104 , C10L1/1883 , C10L1/1905 , C10L1/224 , C10M107/32 , C10M129/68 , C10M129/72 , C10M133/16 , C10M135/04 , C10M135/06 , C10M145/08 , C10M149/02 , C10M159/20 , C10M2201/02 , C10M2201/062 , C10M2203/1006 , C10M2203/1025 , C10M2205/028 , C10M2205/0285 , C10M2207/123 , C10M2207/282 , C10M2209/04 , C10M2209/1023 , C10M2215/08 , C10M2215/28 , C10M2217/06 , C10M2219/022 , C10M2219/024 , C10M2219/044 , C10M2219/046 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/05 , C10N2220/021 , C10N2220/022 , C10N2230/06 , C10N2230/08 , C10N2230/70 , C10N2240/10 , C10N2250/10 , C10N2260/06 , C10N2260/09 , C10N2270/02 , C11C3/00 , C11C3/003 , C11D3/3746 , C08F220/64 , C08F220/10 , C08F220/04
摘要： This invention relates to a composition, comprising: an unsaturated functionalized monomer of from about 5 to about 30 carbon atoms, which is: (a) polymerized to form a functionalized polymer; (b) copolymerized with a comonomer to form a functionalized copolymer; or (c) reacted with an enophilic reagent to form a polyfunctionalized monomer. The polyfunctionalized monomer may be polymerized to form a polyfunctionalized polymer which may be further reacted with one or more additional reagents. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents and polymeric resins.

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