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    • 18. 发明公开
    • System for the extraction and utilization of oxygen and other ligands from fluids
    • 一种用于提取和使用氧和其他配体从流体工艺。
    • EP0176446A2
    • 1986-04-02
    • EP85401857.9
    • 1985-09-24
    • AQUANAUTICS CORPORATION
    • Bonaventura, JosephBonaventura, Celiavan Ryzin, Joseph C.Zenner, Bruce DeAnderson, C. William
    • C01B13/02C25B1/02
    • H01M8/0606C01B13/0251C01B13/0255C01B13/0285C01B2210/005C25B1/02H01M8/0656H01M8/18Y02E60/528
    • A method for extracting oxygen from a fluid environment, which comprises the steps of (1) contacting a first fluid environment containing oxygen with a first surface of a first oxygen permeable membrane having a first and a second surface, wherein the membrane separates the environment from an Interior space of a closed container, (2) transporting a carrier fluid into contact with the second surface of the membrane, wherein the carrier fluid is confined in the closed container and the carrier fluid contains a binding-state oxygen carrier, whereby oxygen which diffuses through the membrane binds to the carrier to give a bound oxygen complex, (3) transporting the carrier fluid containing the bound oxygen complex to a first electrode compartment of an electrochemical cell which forms a second portion of the closed container, (4) electrochemically modifying the binding-state oxygen carrier to an oxidation state having less binding affinity for oxygen, thereby releasing free oxygen into the carrier fluid and producing a nonbinding-state oxygen carrier, (5) removing oxygen from the carrier fluid, (6) transporting the carrier fluid containing the nonbinding- state oxygen carrier to a second electrode compartment of an electrochemical cell which forms a third portion of the closed container, and (7) electrochemically modifying the nonbinding-state oxygen carrier to the binding-state oxygen carrier, is disclosed along with an apparatus useful for carrying out the method of the invention.
    • 分机。 O2的从流体通过(a)使所述流体与在其内表面与在封闭容器中的载体流体,其中载体流体含有O2载体在接触的O 2渗透膜是谁的外表面进行 结合状态调查做到了结合O2扩散通过该膜,以形成复合物; (B)输送复contg。 载体流体的电化学电池形成密闭容器的一部分的第一电极室; (C)在oxidn电化学修改O2载体。 状态较少的结合亲和力为O2,从而释放游离O2入运载流体和产生非结合O2载体; (D)从所述载体流体中除去O2; (E)输送载体流体的第二电极室形成密闭容器的一部分; 和(f)第二电极室形成密闭容器的一部分; 和(f)以电化学修改O2载体以再生其结合状态。 所以声称类似步骤的方法(B) - (F),用于可逆地从配体载体中除去的配体。