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    • 17. 发明公开
    • COLLECTOR, ELECTRODE STRUCTURE, NON-AQUEOUS ELECTROLYTE BATTERY, AND ELECTRICITY STORAGE COMPONENT
    • 收集器,电极结构,非水电解质电池和电存储部件
    • EP2738847A1
    • 2014-06-04
    • EP11870226.5
    • 2011-07-29
    • UACJ CorporationUACJ Foil Corporation
    • SEKI, MasakazuKATO, OsamuSAITO, SoheiHONKAWA, YukiouSUZUKI, SatoshiASHIZAWA, KoichiWASAMOTO, MitsuyukiKADOWAKI, KenichiYAMAMOTO, KenjiFURUTANI, Tomohiko
    • H01M4/66C22C21/00C22F1/04C22F1/00
    • H01G11/68C22C21/00C22F1/00C22F1/04H01M4/662H01M4/667H01M4/668H01M10/0525
    • An object of the present invention is to provide a current collector which includes an aluminum alloy foil for electrode current collector, with high electrical conductivity and high strength after a drying process performed after application of an active material. According to the present invention, provided is a current collector including a conductive substrate and a resin layer provided on one side or both sides of the conductive substrate, wherein: the conductive substrate is an aluminum alloy foil containing 0.03 to 1.0 mass% (hereinafter mass% is referred to as %) of Fe, 0.01 to 0.3% of Si, 0.0001 to 0.2 % of Cu, with the rest being Al and unavoidable impurities, an aluminum alloy foil after a final cold rolling having a tensile strength of 180 MPa or higher, a 0.2% yield strength of 160 MPa or higher, and an electrical conductivity of 58% IACS or higher; an aluminum alloy foil after performing a heat treatment at 120°C for 24 hours, at 140°C for 3 hours, or at 160°C for 15 minutes after the final cold rolling having a tensile strength of 170 MPa or higher, and a 0.2% yield strength of 150 MPa or higher; the resin layer includes a resin containing an acryl-based resin, a soluble nitrocellulose-based resin or a chitosan-based resin, and a conductive material; and a water contact angle of the resin layer surface measured by θ/2 method in a thermostatic chamber at 23°C is 30 degrees or more and 105 degrees or less when the resin is the acryl-based resin, 100 degrees of more and 110 degrees or less when the resin is the soluble nitrocellulose-based resin, and 20 degrees or more and 50 degrees or less when the resin is the chitosan-based resin.
    • 本发明的目的在于提供一种集电体,其含有电极集电体用铝合金箔,该电极集电体用铝合金箔在涂布活性物质后进行干燥处理后具有高导电性和高强度。 根据本发明,提供一种集电体,其具有导电性基体和设置在该导电性基体的一面或两面上的树脂层,其中,所述导电性基体为铝合金箔,其含有0.03〜1.0质量%(以下, %表示为Fe),0.01〜0.3%的Si,0.0001〜0.2%的Cu,其余为Al和不可避免的杂质,最终冷轧后的抗拉强度为180MPa的铝合金箔或 0.2%屈服强度为160MPa以上,电导率为58%IACS以上, 在最终冷轧后,在120℃下热处理24小时,在140℃下3小时或在160℃下热处理15分钟后的铝合金箔和拉伸强度为170MPa以上的铝合金箔, 0.2MPa屈服强度为150MPa或更高; 树脂层包含含有丙烯酸类树脂,可溶性硝化纤维素类树脂或壳聚糖类树脂的树脂和导电材料; 在23℃的恒温槽内通过θ/ 2法测定的树脂层表面的水接触角在树脂为丙烯酸系树脂时为30度以上且105度以下,更优选为110度 当树脂为可溶性硝化纤维素类树脂时为20度以下,树脂为壳聚糖类树脂时为20度以上且50度以下。