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    • 12. 发明公开
    • METAL COMPLEX AND LIGHT EMITTING ELEMENT USING SAME
    • METALLKOMPLEX UND LICHTEMITTIERENDES ELEMENT DAMIT
    • EP3093292A1
    • 2016-11-16
    • EP14877977.0
    • 2014-12-18
    • Sumitomo Chemical Company, Limited
    • SAITO, TakakazuISHII, YusukeOHUCHI, KazueiASADA, KoheiAKINO, Nobuhiko
    • C07F15/00C09K11/06H01L51/50
    • H01L51/0085C07F15/0033C09K11/06C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1059C09K2211/185H01L51/5016
    • A metal complex represented by the formula (1):

      [wherein,
      M represents an iridium atom or a platinum atom.
      n 1 represents 1, 2 or 3. n 2 represents 0, 1 or 2.
      E 1 to E 4 represent a nitrogen atom or a carbon atom.
      R 1 to R 10 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryl group, an aryloxy group, a monovalent heterocyclic group or a halogen atom. At least one selected from the group consisting of R 1 to R 4 is a group represented by the formula (D-A) or (D-B).
      X a and X b represent a direct bond, an oxygen atom, a sulfur atom, -C(= O)-, -CR Xa 2 - or -NR Xa -. R Xa represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or a monovalent heterocyclic group. At least one of X a and X b is an oxygen atom, a sulfur atom, -C(= O)-, -CR Xa 2 - or -NR Xa -.
      A 1 -G 1 -A 2 represents an anionic bidentate ligand, and G 1 represents an atomic group constituting a bidentate ligand together with A 1 and A 2 . A 1 and A 2 each independently represent a carbon atom, an oxygen atom or a nitrogen atom.]


      [wherein,
      m DA1 to m DA7 represent an integer of 0 or more.
      G DA represents an aromatic hydrocarbon group or a heterocyclic group.
      Ar DA1 to Ar DA7 represent an arylene group or a divalent heterocyclic group.
      T DA represents an aryl group or a monovalent heterocyclic group.].
    • 由式(1)表示的金属络合物:[其中,M表示铱原子或铂原子。 n 1表示1,2或3.n 2表示0,1或2.E 1至E 4表示氮原子或碳原子。 R 1〜R 10表示氢原子,烷基,环烷基,烷氧基,环烷氧基,芳基,芳氧基,1价杂环基或卤素原子。 选自由R 1至R 4组成的组中的至少一种为由式(D-A)或(D-B)表示的基团。 X a和X b表示直接键,氧原子,硫原子,-C(= O) - , - CR X 2 2-或-NR X a - 。 R Xa表示氢原子,烷基,环烷基,芳基或1价杂环基。 X a和X b中的至少一个为氧原子,硫原子,-C(= O) - , - CR X 2 2-或-NR X a - 。 A 1 -G 1 -A 2表示阴离子二齿配位体,G 1表示与A 1和A 2一起构成二齿配体的原子团。 A 1和A 2各自独立地表示碳原子,氧原子或氮原子。] [其中,m DA1〜m DA7表示0以上的整数。 G DA表示芳族烃基或杂环基。 Ar DA1至ArDA7表示亚芳基或二价杂环基。 T DA表示芳基或1价杂环基。
    • 14. 发明公开
    • PROCESS FOR PRODUCING POLYMER
    • POLYMERHERSTELLUNGSVERFAHREN
    • EP1892258A1
    • 2008-02-27
    • EP06766521.6
    • 2006-06-09
    • Sumitomo Chemical Company, Limited
    • OHUCHI, KazueiFUKUSHIMA, DaisukeHIGASHIMURA, Hideyuki
    • C08G61/00
    • C08G61/125C08G73/10C09K11/06C09K2211/1416C09K2211/145H01L51/0035H01L51/0039H01L51/5012H05B33/14
    • A process for producing a polymer, characterized by comprising the following step (A) and step (B). (A) A step in which a polymer having repeating units represented by the general formula (1): -Ar 1 - (wherein Ar 1 represents an arylene, divalent heterocyclic, or divalent aromatic amine group having at least one C-H bond on the aromatic ring) is used as a raw material and one or more of the C-H bond(s) on the aromatic ring are converted to thereby produce a polymer having repeating units which have one or more characteristic groups X and are represented by the general formula (2): (wherein X represents a characteristic group; Ar 2 represents an arylene group, heterocyclic group, or aromatic amine group which each has a valence of n+2 and in each of which n of the C-H bonds on the aromatic ring of Ar 1 have been converted into a C-X bond; and n is an integer of 1-4) (hereinafter, this polymer is referred to as polymer having the characteristic group (X)). (B) A step in which the polymer having the characteristic group (X) produced in the step (A) is reacted with a compound having a characteristic group (Y) which reacts with the characteristic group (X) to form a bond.
    • 一种制备聚合物的方法,其特征在于包括以下步骤(A)和步骤(B)。 (A)具有由通式(1)表示的重复单元的聚合物:-Ar 1 - (其中Ar 1表示亚芳基,二价杂环基或在芳香族上具有至少一个CH键的二价芳族胺基的步骤) 环)作为原料,并且将芳环上的一个或多个CH键转化为由此产生具有一个或多个特征基团X并且由通式(2)表示的重复单元的聚合物 ):(其中X表示特征基团; Ar 2表示各自具有n + 2的化合价的亚芳基,杂环基或芳香族胺基,其中Ar 1的芳香环上的n为n个) 已经转化为CX键; n为1-4的整数)(以下,将该聚合物称为具有特征基团(X)的聚合物)。 (B)将具有在步骤(A)中制造的特征基团(X)的聚合物与具有与特征基团(X)反应的特征基团(Y)的化合物反应以形成键的步骤。
    • 15. 发明公开
    • METHOD FOR PRODUCING POLYMER COMPOUND
    • VERFAHREN ZUR HERSTELLUNG EINER POLYMERVERBINDUNG
    • EP1721922A1
    • 2006-11-15
    • EP05709917.8
    • 2005-02-02
    • Sumitomo Chemical Company, Limited
    • ONODERA, ToruOHUCHI, KazueiSASAKI, Shigeru
    • C08G61/00H01B1/06H01M8/02
    • H01M8/1023C08G61/00H01B1/122H01M8/0289H01M8/1067Y02P70/56
    • A method for polymerizing a monomer represented by the formula (1) or copolymerizing a monomer represented by the formula (1) and a monomer represented by the formula (2) in the co-presence of a condensation agent comprising a transition metal complex, to thereby produce a polymer compound represented by the formula (3): X 1 -Ar 1 -X 2 (1)X 3 -Ar 2- X 4 (2)-(Ar 1 )q-(Ar 2 )r-(3)[X 1 ,X 2 ,X 3 and X 4 represent groups separating in the condensation, Ar 1 represents a two-valent aromatic group having at least a sulfonic acid or a sulfonic acid via a connecting group as a substitutent, q represents a positive number, r represents 0 or a positive number, and the sum of q and r is 300 or more], characterized in that the above condensation agent and the above monomer are mixed at a temperature of 45°C or higher. The above method allows the production of a polymer compound which exhibits excellent fuel cell characteristics and has a high molecular weight.
    • 在由包含过渡金属络合物的缩合剂共存的情况下,使由式(1)表示的单体或由式(1)表示的单体与式(2)表示的单体共聚的方法, 从而制备由式(3)表示的高分子化合物:X 1 -Ar 1 -X 2(1)X 3 -Ar 2- X 4(2) - (Ar 1)q-(Ar 2)r-(3 )[X 1,X 2,X 3和X 4表示在缩合中分离的基团,Ar 1表示经由连接基团作为取代基的至少具有磺酸或磺酸的2价芳香族基团,q表示 正数,r表示0或正数,q和r的和为300以上],其特征在于,上述缩合剂和上述单体在45℃以上的温度下混合。 上述方法允许制备显示出优异的燃料电池特性并且具有高分子量的高分子化合物。