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11. 发明公开

EP2690196A1 METHOD FOR PROCESSING THIN CU PLATE 有权
标题翻译：一种用于处理薄铜板
公开(公告)号：EP2690196A1
公开(公告)日：2014-01-29
申请号：EP12761166.3
申请日：2012-03-06
申请人： NGK Insulators, Ltd.
发明人： MURAMATSU, Naokuni , AOSHIMA, Shoju
IPC分类号： C23C24/10 , B23K26/32 , B23K26/34 , C22C9/00 , C22C16/00 , C22C19/05 , C22C29/06 , C22C29/08 , C22C29/10 , C22C29/14
CPC分类号： B23K26/32 , B22F7/04 , B22F2007/047 , B22F2998/00 , B22F2998/10 , B23K26/342 , B23K35/007 , B23K35/0244 , B23K35/025 , B23K35/3033 , B23K2203/05 , B23K2203/12 , B23K2203/18 , B23K2203/26 , C22C1/0433 , C22C1/0458 , C22C9/00 , C22C9/06 , C22C16/00 , C22C19/056 , C22C19/058 , C22C19/07 , C22C32/0052 , C22C45/10 , C23C24/10 , B22F3/22 , B22F3/105 , C22C29/06 , C22C29/16 , C22C29/14
摘要： A method for treating a Cu thin sheet is provided. The method comprises the steps of: supplying a slurry in which a diffusion bonding aid and a reinforcing material are dispersed in a solvent to a predetermined portion on a Cu or Cu base alloy thin sheet, drying the supplied slurry, and applying a laser to induce melting, solidification, and fixation, so as to form a buildup layer. In the method, (a) a Ni or Ni-Cr alloy powder is used as the diffusion bonding aid, (b) a carbide base metal compound, a nitride base metal compound, or a boride base metal compound is used as the reinforcing material, and the weight ratio of the diffusion bonding aid to the reinforcing material is specified to be 80:20 to 50:50, and (c) the median diameters D 50 of both the diffusion bonding aid and the reinforcing material employed fall within 0.1 to 100 µm, the median diameter D 50 of the diffusion bonding aid is larger than the median diameter D 50 of the reinforcing material, and both the distribution ratio D 90 /D 10 of the diffusion bonding aid and the distribution ratio D 90 /D 10 of the reinforcing material are 4.0 or less.

12. 发明公开

EP2537953A1 HEAT TREATMENT METHOD AND HEAT TREATMENT APPARATUS 有权转让
标题翻译： WÄRMEBEHANDLUNGSVERORHRENUNDWÄRMEBEHANDLUNGSVORRICHTUNG
公开(公告)号：EP2537953A1
公开(公告)日：2012-12-26
申请号：EP11837980.9
申请日：2011-10-31
申请人： NGK Insulators, Ltd. , Yokohama National University
发明人： TAKEDA, Mahoto , MURAMATSU, Naokuni , TAKEUCHI, Ryota
IPC分类号： C22F1/08 , B21B1/00 , B21B27/08 , C21D1/34 , C21D9/46 , C22F1/05 , C22F1/00
CPC分类号： C22F1/08 , C21D9/52 , C22F1/00 , C22F1/047
摘要： A heat treatment method according to the present invention includes a preliminary-state-generating step of heat-treating an alloy that undergoes multiple-step transformation with temperature by bringing the alloy in contact with a contact-type heating element for 0.01 sec or more and 3.0 sec or less, the contact-type heating element being adjusted to a particular temperature within a preliminary-state-generating temperature region determined on the basis of a first temperature related to a particular first transformation of the alloy and a second temperature, which is higher than the first temperature, related to a particular second transformation of the alloy so as to generate a preliminary state in the alloy.
摘要翻译：根据本发明的热处理方法包括：通过使合金与接触型加热元件接触0.01秒以上的方式对通过温度进行多步转变的合金进行热处理的预备状态生成步骤，以及 3.0秒以下，接触型加热元件被调整到基于与合金的特定的第一次变形有关的第一温度而决定的预备状态发生温度区域内的特定温度，第二温度为高于第一温度，与合金的特定的第二次转变有关，以便在合金中产生初步状态。

13. 发明公开

EP3778064A1 FORGING TOOL 有权
公开(公告)号：EP3778064A1
公开(公告)日：2021-02-17
申请号：EP19774396.6
申请日：2019-03-28
申请人： NGK Insulators, Ltd. , Miura, Hiromi
发明人： MURAMATSU, Naokuni , KAWAMOTO, Tadahiro , MIURA, Hiromi
IPC分类号： B21J1/02 , B21J13/02
摘要： A forging tool 10 is to forge a workpiece W in a cuboidal forging space S by using first to sixth wall surfaces 21 to 26. The forging tool 10 includes a first die 30, a second die 40, and a third die 60. The first die 30 forms the first wall surface 21 and the second wall surface 22 adjacent to the first wall surface 21. The second die 40 forms the third wall surface 23 and the fourth wall surface 24 adjacent to the third wall surface 23. The third die 60 forms the sixth wall surface 26 in a region surrounded by a contact surface 61 when bottom surfaces 32, 42 of the first die 30 and the second die 40 are brought into contact with the contact surface 61. The first die 30 forms a triangular region 25a two sides of which are a line of intersection of the fifth wall surface 25 with the first wall surface 21 and a line of intersection of the fifth wall surface 25 with the second wall surface 22, the second die 49 forms a triangular region 25b two sides of which are a line of intersection of the fifth wall surface 25 with the third wall surface 23 and a line of intersection of the fifth wall surface 25 with the fourth wall surface 24, and the workpiece W is pressed between the fifth wall surface 25 and the sixth wall surface 26.

14. 发明授权

EP3006588B1 COPPER-ALLOY PRODUCTION METHOD, AND COPPER ALLOY 有权
公开(公告)号：EP3006588B1
公开(公告)日：2018-07-18
申请号：EP14807420.6
申请日：2014-06-04
申请人： NGK Insulators, Ltd. , National University Corporation Kanazawa University
发明人： MONZEN, Ryoichi , MURAMATSU, Naokuni
IPC分类号： C22F1/08 , C22C9/02 , C22C9/06 , C22F1/00
CPC分类号： C22F1/08 , C21D1/18 , C22C9/02 , C22C9/06
摘要： A method for manufacturing a copper alloy of the present invention is a method for manufacturing a Cu-Ni-Sn-based copper alloy and includes: a first aging treatment step of performing an aging treatment in a temperature range of 300°C to 500°C using a solution treated material; an inter-aging processing step of performing cold working after the first aging treatment step; and a second aging treatment step of performing an aging treatment in a temperature range of 300°C to 500°C after the inter-aging processing step. In the first aging treatment step, a peak aging treatment is preferably performed. In addition, in the second aging treatment step, the aging treatment is preferably performed for a short period as compared to that of the aging treatment in the first aging treatment step. In the inter-aging processing step, cold working is preferably performed at a processing rate of more than 60% to 99%.

15. 发明公开

EP2927913A1 VOLTAGE NON-LINEAR RESISTANCE ELEMENT 审中-公开
标题翻译：电压非线性电阻元件
公开(公告)号：EP2927913A1
公开(公告)日：2015-10-07
申请号：EP13858795.1
申请日：2013-10-24
申请人： NGK Insulators, Ltd.
发明人： MURAMATSU, Naokuni
IPC分类号： H01C7/10 , B22F1/00 , B22F1/02 , B22F3/14
CPC分类号： H01C7/10 , B22F3/105 , B22F2003/1051 , B22F2999/00 , C22C1/0425 , C22C1/0491 , C22C9/00 , H01C7/108 , H01C17/00 , B22F2202/13
摘要： A voltage nonlinear resistive element 20 of the present invention includes a voltage nonlinear resistive material 30 composed of a copper alloy which has a two-phase structure containing a Cu phase 31 and a Cu-Zr compound phase 32 not containing a eutectic phase, and electrodes 21 and 22. The voltage nonlinear resistive material 30 may have a mosaic-shaped structure in which the Cu phase 31 and the Cu-Zr compound phase 32 are dispersed as crystals with a size of 10 µm or less in a cross-sectional view. The Cu-Zr compound phase 32 may be at least one of Cu 5 Zr, Cu 9 Zr 2 , and Cu 8 Zr 3 . Also, the voltage nonlinear resistive material 30 may be formed by spark plasma sintering of a Cu-Zr binary alloy powder. The voltage nonlinear resistive material 30 may contain 0.2 at% or more and 18.0 at% or less of Zr.
摘要翻译：本发明的电压非线性电阻元件20包括由铜合金构成的电压非线性电阻材料30，该铜合金具有包含Cu相31和不包含共晶相的Cu-Zr化合物相32的两相结构，并且电极电压非线性电阻材料30可以具有马赛克形结构，其中Cu相31和Cu-Zr化合物相32在截面图中以10μm或更小的尺寸分散成晶体。 Cu-Zr化合物相32可以是Cu 5 Zr，Cu 9 Zr 2和Cu 8 Zr 3中的至少一种。而且，电压非线性电阻材料30可以通过Cu-Zr二元合金粉末的放电等离子体烧结来形成。电压非线性电阻材料30可以包含0.2原子％以上且18.0原子％以下的Zr。

16. 发明公开

EP2915891A1 Cu-Be ALLOY AND METHOD FOR PRODUCING SAME 有权
标题翻译： CU-BE-LEGIERUNG UND VERFAHREN ZUR HERSTELLUNG DAVON
公开(公告)号：EP2915891A1
公开(公告)日：2015-09-09
申请号：EP13852279.2
申请日：2013-10-23
申请人： NGK Insulators, Ltd. , The University of Electro-Communications
发明人： MIURA, Hiromi , MURAMATSU, Naokuni
IPC分类号： C22C9/00 , C22F1/08 , C22F1/00
CPC分类号： C22C9/00 , C22F1/00 , C22F1/08 , H01B1/026 , H01B13/0016
摘要： A Cu-Be alloy according to the present invention is a Co-containing Cu-Be alloy, in which the Co content is 0.005% to 0.12% by mass, and the number of Cu-Co-based compound particles having a particle size of 0.1 µm or more that can be confirmed on a TEM image at a magnification of 20,000 is five or less in a field of view of 10 µm × 10 µm. Furthermore, a method for producing a Cu-Be alloy according to the present invention includes a solution annealing treatment step of subjecting a Cu-Be alloy raw material containing 0.005% to 0.12% by mass of Co and 1.60% to 1.95% by mass of Be to solution annealing treatment to obtain a solution-annealed material.
摘要翻译：根据本发明的Cu-Be合金是Co含量为0.005〜0.12质量％的Co-Cu系合金，Cu-Co系合金粒子的粒径为在10μm以上的TEM图像中可以确认的0.1μm以上的值在10μm以上的场合为5以下。此外，根据本发明的Cu-Be合金的制造方法包括：将含有0.005〜0.12质量％的Co的Cu-Be合金原料和1.60〜1.95质量％的Cu-Be合金原料进行固溶退火处理，得到固溶退火材料。

17. 发明公开

EP2908318A1 VOLTAGE NONLINEAR RESISTANCE ELEMENT 审中-公开
标题翻译： NICHTLINEARES SPANNUNGSWIDERSTANDSELEMENT
公开(公告)号：EP2908318A1
公开(公告)日：2015-08-19
申请号：EP13844715.6
申请日：2013-10-03
申请人： NGK Insulators, Ltd.
发明人： MURAMATSU, Naokuni
IPC分类号： H01C7/10 , C22C9/00 , C22F1/00 , C22F1/08
CPC分类号： H01C7/12 , C22C9/00 , H01C7/10 , H01C7/105
摘要： A voltage nonlinear resistive element of the present invention includes a voltage nonlinear resistive material composed of a copper alloy containing a Cu-Zr compound phase, and electrodes. In the voltage nonlinear resistive material, the Cu-Zr compound phase preferably contains at least one of a Cu 9 Zr 2 phase, a Cu 5 Zr phase, and a Cu 8 Zr 3 phase. The voltage nonlinear resistive material preferably contains a composite phase that contains a Cu phase and the Cu-Zr compound phase. More preferably, the composite phase is a eutectic phase containing the Cu phase and the Cu 9 Zr 2 phase.
摘要翻译：本发明的电压非线性电阻元件包括由含有Cu-Zr化合物相的铜合金构成的电压非线性电阻材料和电极。在电压非线性电阻材料中，Cu-Zr化合物相优选含有Cu 9 Zr 2相，Cu 5 Zr相和Cu 8 Zr 3相中的至少一种。电压非线性电阻材料优选含有包含Cu相和Cu-Zr化合物相的复合相。更优选地，复合相是含有Cu相和Cu 9 Zr 2相的共晶相。

18. 发明公开

EP2832470A1 FORGING METHOD AND MOLD FOR FORGING 有权转让
标题翻译： SCHMIEDEVERFAHREN UND FORUM ZUM SCHMIEDEN
公开(公告)号：EP2832470A1
公开(公告)日：2015-02-04
申请号：EP13768359.5
申请日：2013-03-14
申请人： NGK Insulators, Ltd. , The University of Electro-Communications
发明人： MIURA, Hiromi , MURAMATSU, Naokuni
IPC分类号： B21J5/02 , B21J5/00 , B21J13/02 , B21J13/14 , C22F1/08 , C22C9/00 , C22C9/06 , C22C38/00 , C22C38/18
摘要： A forging method according to the present invention is characterized by including the steps of placing a work W having a first shape which is a rectangular hexahedron in a work space 45 of a forging die 20 which has a rectangular opening, which is formed by rectangular plane wall portions, and which is provided with the work space 45 to hold the work in a placement step and applying a plastic strain to the work W by deforming the placed work W into a second shape which is a rectangular hexahedron in a working step, wherein the placement step and the working step are performed at least two times. For example, the work is press-deformed in the work space of the forging die and, thereby, the shape stability can be further ensured. Also, the forging die 20 has a structure in which a plurality of die parts are fitted into the inner periphery of the outer die, so that, for example, the stress applied to the inner die 50 during pressurization of the work W can be dispersed to the outer peripheral side more evenly by the plurality of die parts and breakage of the die and the like can be further suppressed.
摘要翻译：根据本发明的锻造方法的特征在于包括以下步骤：将具有矩形六面体的第一形状的工件W放置在具有矩形开口的锻造模具20的工作空间45中，该锻造模具由矩形平面壁部，并且设置有工作空间45，用于将工件保持在放置步骤中，并且在工作步骤中通过使放置的工件W变形为矩形六面体的第二形状而向工件W施加塑性应变，其中放置步骤和工作步骤至少进行两次。例如，在锻造模具的工作空间中进行压制变形，能够进一步确保形状的稳定性。此外，锻造模具20具有将多个模具部嵌入外模的内周的结构，例如，可以分散在加工工件W期间施加到内模50的应力可以进一步抑制多个模具部件更均匀地向外周侧的挤压，并且能够进一步抑制模具的断裂等。

19. 发明公开

EP2479297A1 COPPER ALLOY WIRE AND PROCESS FOR PRODUCING SAME 有权
标题翻译： KUPFERLEGIERUNGSDRAHT UND HERSTELLUNGSVERFAHRENDAFÜR
公开(公告)号：EP2479297A1
公开(公告)日：2012-07-25
申请号：EP10815488.1
申请日：2010-09-13
申请人： NGK Insulators, Ltd. , Tohoku University
发明人： MURAMATSU, Naokuni , KIMURA, Hisamichi , INOUE, Akihisa
IPC分类号： C22C9/00 , B22D11/059 , B22D21/00 , C22F1/08 , H01B1/02 , H01B5/02 , H01B13/00 , B22D11/00 , C22F1/00
CPC分类号： H01B1/026 , C22C1/02 , C22C9/00 , C22F1/08
摘要： The zirconium content of the alloy composition of a copper alloy wire 10 of the present invention is 3.0 to 7.0 atomic percent, and the copper alloy wire 10 includes copper matrix phases 30 and composite phases 20 composed of copper-zirconium compound phases 22 and copper phases 21. As shown in Fig. 1 , the copper matrix phases 30 and the composite phases 20 form a matrix phase-composite phase fibrous structure and are arranged alternately parallel to an axial direction as viewed in a cross-section parallel to the axial direction and including a central axis. In addition, the copper-zirconium compound phases 22 and the copper phases 21 in the composite phases 20 form a composite phase inner fibrous structure and are arranged alternately parallel to the axial direction at a phase pitch of 50 nm or less as viewed in the above cross-section. This double fibrous structure presumably makes the copper alloy wire 10 densely fibrous to provide a strengthening mechanism similar to the rule of mixture for fiber-reinforced composite materials.
摘要翻译：本发明的铜合金线10的合金组成的锆含量为3.0〜7.0原子％，铜合金线10包含铜基体相30和由铜 - 锆化合物相22和铜相构成的复合相20 如图21所示。如图1所示，铜基体相30和复合相20形成基体相复合相纤维结构，并且在与轴向平行的截面中观察并且包括中心轴线，交替平行于轴向布置。此外，复合相20中的铜 - 锆化合物相22和铜相21形成复合相内纤维结构，并且如上所述以相对间距50nm或更小的方式与轴向交替平行布置横截面。这种双重纤维结构可能使铜合金线10密集纤维化，以提供类似于纤维增强复合材料的混合规则的强化机理。

20. 发明授权

EP1759781B1 METHOD FOR FORMING METALLIC GLASS 有权
标题翻译：用于生产五金玻璃
公开(公告)号：EP1759781B1
公开(公告)日：2011-07-06
申请号：EP05743302.1
申请日：2005-05-27
申请人： NGK Insulators, Ltd. , TOHOKU UNIVERSITY
发明人： MURAMATSU, Naokuni , SUZUKI, Kenment , INOUE, Akihisa , KIMURA, Hisamichi
IPC分类号： B21D22/20 , B22D17/00 , B22D17/22
CPC分类号： B21D37/01 , B21D37/20 , B21J1/006 , B22D17/00 , B22D17/10 , B22D17/14 , C22C45/10 , Y10T29/49984
摘要： A method for forming a metallic glass, which comprises a step of subjecting a metallic glass to a rough forming by die casting, to prepare a roughly formed article, and a step of heating the roughly formed article to a temperature region corresponding to an undercooled liquid thereof, followed by subjecting the heated article to warm press forming.

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