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    • 12. 发明公开
    • Curable composition
    • 可固化组合物
    • EP0497231A2
    • 1992-08-05
    • EP92101212.6
    • 1992-01-25
    • KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
    • Ando, Naotami
    • C08L33/04C08L51/00C08L43/04C09D143/04C09D133/06C08L51/06
    • C08L43/04C08L51/003C09D143/04C08L2666/24
    • The curable composition comprising (A) an alkoxysilyl group-containing acrylic copolymer or a mixture therof with a hydroxyl group-containing acrylic resin, (B) a curing catalyst, (C) an organic solvent and (D) fine particles of a cross-linked polymer which is insoluble but stably dispersible in the components (A), (B) and (C), the cross-linked polymer (D) comprising (d1) a backbone polymer polymerized from a monomer mixture having mainly an alkyl acrylate and (d2) a grafted phase polymerized in the presence of the backbone polymer (d1) from a monomer mixtuer having mainly an alkyl methacrylate. The composition of the present invention is improved in sag resistance as well as excellent in durability and film appearance, so a satisfactorily thick film can be obtained by one application of the composition.
    • (A)含有烷氧基甲硅烷基的丙烯酸类共聚物或其与含有羟基的丙烯酸类树脂的混合物,(B)固化催化剂,(C)有机溶剂和(D)交联剂的微粒的固化性组合物, (A),(B)和(C)中不溶但稳定分散的交联聚合物,所述交联聚合物(D)包含(d1)主要聚合物,其主要聚合物主要由丙烯酸烷基酯和 d2)在主链聚合物(d1)存在下由主要具有甲基丙烯酸烷基酯的单体混合物聚合的接枝相。 本发明的组合物的抗流挂性得到改善,并且具有优异的耐久性和膜外观,因此通过一次施用组合物可以获得令人满意的厚膜。
    • 18. 发明公开
    • Room temperature cross-linkable aqueous composition and process for preparing the same
    • 在室温下可固化的含水组合物及其制备方法。
    • EP0598294A2
    • 1994-05-25
    • EP93118020.2
    • 1993-11-06
    • KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
    • Ando, NaotamiMasuda, ToshiyukiHatano, Takanori
    • C08F230/08
    • C08F230/08
    • A room temperature cross-linkable aqueous composition which contains an emulsion-polymerized copolymer comprising (I) a reaction product prepared by reacting (A) a monomer having at least one polymerizable double bond and a silyl group represented by the general formula (I):

      wherein R¹: monovalent hydrocarbon selected from the group consisting of C₁₋₁₀ alkyl, aryl and aralkyl, X: a halogen, alkoxy, hydroxyl, acyloxy, aminoxy, phenoxy, thioalkoxy, or amino, a: 0, 1 or 2, and (B) a basic compound; and (II) a vinyl monomer copolymerizable with said (I) reaction product, and a process for preparing the same. The composition of the present invention has excellent storage stability and excellent room temperature cross-linkability which can be polymerized in stable condition without gelation.
    • 甲室温交联性wässrige组合物,其在乳液聚合的共聚物含有包括(i)通过使(A)具有至少一个可聚合双键和由通式(I)表示的甲硅烷基团的单体制备的反应产物: worin - [R <1>:选自C 1-10烷基,芳基和芳烷基中选出的一价烃基,X:卤素,烷氧基,羟基,酰氧基,氨氧基,苯氧基,硫代烷氧基,或氨基,A:0, 1或2,和(B)碱性化合物; 和(II)共聚的乙烯基单体与上述(I)的反应产物,以及制备它们的方法。 本发明的组合物具有优异的储存稳定性并且可以以稳定的条件进行聚合,而不胶凝优良室温交联的能力。