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    • 13. 发明公开
    • METHOD FOR RECLAIMING IRON AND PHOSPHORUS FROM STEELMAKING SLAG
    • 从炼钢渣中回收铁和磷的方法
    • EP3239308A1
    • 2017-11-01
    • EP17171814.1
    • 2009-12-22
    • JFE STEEL CORPORATION
    • KIKUCHI, NaokiMATSUI, AkitoshiTAKAHASHI, KatsunoriTOBO, HiroyukiKISHIMOTO, Yasuo
    • C21C5/28C04B5/06C21C1/02C22B1/16
    • C22B7/04C04B5/06C21B3/06C21C1/025C21C7/0087C21C7/076C22B5/04C22B5/10Y02P10/216Y02P10/234Y02P10/242Y02W30/543
    • The invention provides a method for recovering (collecting) iron and phosphorus from steelmaking slag, which includes a first step in which phosphorus-containing steelmaking slag such as dephosphorization slag is reduced using a reducing agent containing for example carbon, Si or Al to reduce iron oxide and phosphorus oxide in the slag and to recover them as phosphorus-containing molten iron, a second step in which the steelmaking slag from which the iron oxide and the phosphorus oxide have been removed is used as a CaO source in a sintering step and the resultant sintered ore is recycled to a blast furnace, a third step in which the phosphorus-containing molten iron recovered by the reduction is dephosphorized to a phosphorus concentration in the phosphorus-containing molten iron of not more than 0.1% by mass, thereby phosphorus being concentrated in a CaO-containing flux, and a fourth step in which the phosphorus-containing molten iron dephosphorized to a phosphorus concentration of not more than 0.1% by mass is mixed as an iron source with a blast furnace hot metal. The method thus enables inexpensive recovery of phosphorus and iron from the steelmaking slag, and the phosphorus and the iron recovered are effectively used as resources.
    • 本发明提供了一种从炼钢炉渣中回收(收集)铁和磷的方法,该方法包括第一步骤,其中使用包含例如碳,Si或Al的还原剂还原脱磷炉渣等含磷炼钢炉渣以还原铁 氧化物和氧化磷,并将其作为含磷铁水回收;第二步,其中已经除去了氧化铁和氧化磷的炼钢炉渣用作烧结步骤中的CaO源, 将所得到的烧结矿再循环至高炉;第三步,将通过还原回收的含磷铁水脱磷至磷含铁水中的磷浓度不超过0.1质量%,从而使磷 浓缩在含有CaO的助熔剂中,以及第四步骤,其中将含磷铁水脱磷至磷浓度为 不超过0.1质量%作为铁源与高炉铁水混合。 因此该方法能够廉价地从炼钢渣中回收磷和铁,并且回收的磷和铁被有效地用作资源。
    • 14. 发明公开
    • METHOD FOR RECLAIMING IRON AND PHOSPHORUS FROM STEELMAKING SLAG
    • VERFAHREN ZURRÜCKGEWINNUNGVON EISEN UND PHOSPHOR AUS STAHLWERKSSCHLACKE
    • EP2383352A1
    • 2011-11-02
    • EP09835099.4
    • 2009-12-22
    • JFE Steel Corporation
    • KIKUCHI, NaokiMATSUI, AkitoshiTAKAHASHI, KatsunoriTOBO, HiroyukiKISHIMOTO, Yasuo
    • C21C5/28C04B5/06C21C1/02C22B1/16
    • C22B7/04C04B5/06C21B3/06C21C1/025C21C7/0087C21C7/076C22B5/04C22B5/10Y02P10/216Y02P10/234Y02P10/242Y02W30/543
    • The invention provides a method for recovering (collecting) iron and phosphorus from steelmaking slag, which includes a first step in which phosphorus-containing steelmaking slag such as dephosphorization slag is reduced using a reducing agent containing for example carbon, Si or Al to reduce iron oxide and phosphorus oxide in the slag and to recover them as phosphorus-containing molten iron, a second step in which the steelmaking slag from which the iron oxide and the phosphorus oxide have been removed is used as a CaO source in a sintering step and the resultant sintered ore is recycled to a blast furnace, a third step in which the phosphorus-containing molten iron recovered by the reduction is dephosphorized to a phosphorus concentration in the phosphorus-containing molten iron of not more than 0.1% by mass, thereby phosphorus being concentrated in a CaO-containing flux, and a fourth step in which the phosphorus-containing molten iron dephosphorized to a phosphorus concentration of not more than 0.1% by mass is mixed as an iron source with a blast furnace hot metal. The method thus enables inexpensive recovery of phosphorus and iron from the steelmaking slag, and the phosphorus and the iron recovered are effectively used as resources.
    • 本发明提供了一种从钢铁渣中回收(收集)铁和磷的方法,其中包括第一步,其中使用含有例如碳,Si或Al的还原剂还原含磷钢渣如脱磷渣,以还原铁 在炉渣中的氧化物和氧化磷,并将其回收为含磷铁水,在烧结步骤中,将除去了氧化铁和氧化磷的炼钢炉渣作为CaO源的第二工序, 将得到的烧结矿再循环至高炉,第3工序中,将通过还原反应回收的含磷铁水脱磷至含磷铁水中的磷浓度为0.1质量%以下,磷为 浓缩在含CaO的助熔剂中,第四步是将含磷铁水脱磷至磷浓度 不高于0.1质量%的铁矿源与高炉铁水混合。 因此,该方法能够从钢铁炉渣中廉价地回收磷和铁,并且所回收的磷和铁被有效地用作资源。