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12. 发明公开

EP2716739A1 MONOCYCLIC AROMATIC HYDROCARBON PRODUCTION METHOD AND MONOCYCLIC AROMATIC HYDROCARBON PRODUCTION PLANT 无效
标题翻译： PROCESS了一种用于制造环芳香族烃的单环芳香族碳氢化合物和植物
公开(公告)号：EP2716739A1
公开(公告)日：2014-04-09
申请号：EP12790290.6
申请日：2012-05-24
申请人： JX Nippon Oil & Energy Corporation , Chiyoda Corporation
发明人： YANAGAWA, Shinichiro , IWASA, Yasuyuki , YASUI, Susumu , SUGI, Yoshishige , FUKUI, Atsushi , NAGUMO, Atsuro , HIROHATA, Osamu
IPC分类号： C10G11/18
CPC分类号： C07C4/06 , C10G11/18 , C10G35/14 , C10G45/68 , C10G45/70 , C10G2300/1096 , C10G2300/301 , C10G2400/30
摘要： A producing method of monocyclic aromatic hydrocarbons in which reaction products including monocyclic aromatic hydrocarbons are produced by bringing an oil feedstock and an aromatic production catalyst into contact with each other, the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140°C and a 90 volume % distillation temperature of less than or equal to 380°C, the method including the steps of: introducing the oil feedstock into a fluidized-bed reaction apparatus (10) housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other in the fluidized-bed reaction apparatus; and introducing steam into the fluidized-bed reaction apparatus (10) based on the introducing amount of the oil feedstock per hour.
摘要翻译：在其中反应产物的单环芳香族烃，包括单环芳香族烃的制造方法是通过使油原料量和芳族生产催化剂接触海誓山盟生产的，具有更高的10％馏出温度小于或等于140的原料油 ℃且小于或等于380℃，该方法包括以下步骤的90体积％馏出温度：将所述油原料成容纳芳香生产催化剂的流化床反应装置（10）; 使原料油和芳香族生产催化剂到流化床反应装置海誓山盟接触; 和将蒸汽引入基于每小时油原料的导入量的流化床反应装置（10）。

13. 发明公开

EP2690159A1 METHOD FOR PRODUCING SINGLE-RING AROMATIC HYDROCARBONS 无效
标题翻译：生产单环芳香烃的方法
公开(公告)号：EP2690159A1
公开(公告)日：2014-01-29
申请号：EP12762799.0
申请日：2012-03-23
申请人： JX Nippon Oil & Energy Corporation , Chiyoda Corporation
发明人： YANAGAWA, Shinichiro , KOBAYASHI, Masahide , IDA, Ryoji , YASUI, Susumu , SUGI, Yoshishige , FUKUI, Atsushi , NAGUMO, Atsuro
IPC分类号： C10G69/04 , C10G11/05 , C10G11/10 , C10G11/18 , C10G45/44 , C07B61/00 , C07C4/18 , C07C5/13 , C07C15/04 , C07C15/06 , C07C15/08
CPC分类号： C07C4/06 , C10G69/04 , C10G69/10 , C10G2300/4081 , C10G2400/30 , Y02P20/582
摘要： A method for producing monocyclic aromatic hydrocarbons includes a cracking/reforming reaction step of introducing the feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with the catalyst, and causing the feedstock oil to react, thereby obtaining a product, a purification/recovery step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the cracking/reforming reaction step, a hydrogenation reaction step of hydrogenating a heavy fraction separated from the product produced in the cracking/reforming reaction step, and a recycling step of returning a hydrogenation reactant of the heavy fraction obtained in the hydrogenation reaction step to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant of the heavy fraction is introduced at a location different from an introduction location of the feedstock oil into the cracking/reforming reactor so that a time during which the hydrogenation reactant of the heavy fraction is in contact with the catalyst for monocyclic aromatic hydrocarbon production in the cracking/reforming reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst for monocyclic aromatic hydrocarbon production in the cracking/reforming reactor.
摘要翻译：单环芳香族烃的制造方法包括将原料油导入裂化重整反应器，使原料油与催化剂接触并使原料油反应而得到产物的裂化重整反应工序，精制回收从在裂化重整反应工序中生成的产物中分离出的单环芳香族烃的精制回收工序，将从在裂化重整反应工序中生成的产物中分离出的重质馏分氢化的氢化反应工序，将氢化反应工序中得到的重质馏分的氢化反应物返回到裂化重整反应工序的工序。在再循环步骤中，将重质馏分的氢化反应物在不同于原料油的引入位置的位置处引入裂化/重整反应器中，使得重质馏分的氢化反应物与裂化重整反应器中的单环芳香族烃制造用催化剂比原料油与裂解改性反应器内的单环芳香族烃制造用催化剂接触的时间短。

14. 发明公开

EP2554260A1 HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME 有权
标题翻译：对于加氢烃油的是这样就产生和方法加氢催化剂用于烃油和加工
公开(公告)号：EP2554260A1
公开(公告)日：2013-02-06
申请号：EP11762619.2
申请日：2011-03-22
申请人： Chiyoda Corporation
发明人： INOUE Shinichi , WADA Yukitaka , MUTOU Akihiro , ONO Takeo
IPC分类号： B01J31/34 , B01J35/10 , B01J37/02 , C10G45/08
CPC分类号： B01J31/38 , B01J21/04 , B01J21/063 , B01J23/88 , B01J23/882 , B01J23/883 , B01J27/19 , B01J35/002 , B01J35/0026 , B01J35/0033 , B01J35/1019 , B01J35/1038 , B01J35/1047 , B01J35/1061 , B01J35/1085 , B01J37/0207 , B01J37/0219 , B01J37/0221 , B01J37/06 , C10G45/08
摘要： Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100°C and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the driedproduct with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.

15. 发明公开

EP2452740A1 Exhaust gas treating method using gaseous iodine 有权
标题翻译： Abgasbehandlungverfahren unter Verwendung vongasförmigemJod
公开(公告)号：EP2452740A1
公开(公告)日：2012-05-16
申请号：EP12153676.7
申请日：2008-03-05
申请人： Chiyoda Corporation
发明人： Kawamura, Kazushige , Takeda, Dai , Awai, Eiji , Kumagai, Akira
IPC分类号： B01D53/50 , B01D53/34 , B01D53/64 , B01D53/78 , B01D53/14
CPC分类号： B01D53/1456 , B01D53/64 , B01D53/78 , B01D2251/106 , B01D2257/108 , B01D2257/302 , B01D2257/602
摘要： An exhaust gas treating method removes sulfur dioxide from exhaust gas containing at least sulfur dioxide and mercury by bringing the exhaust gas into contact with absorption liquid. Iodine gas is added to the exhaust gas before the exhaust gas is brought into contact with the absorption liquid. A high removal rate for both sulfur dioxide and mercury is stably maintained if the load of power generation and the composition of exhaust gas fluctuate.
摘要翻译：排气处理方法通过使废气与吸收液体接触而从至少含有二氧化硫和汞的排气中除去二氧化硫。在废气与吸收液体接触之前，将碘气加入废气中。如果发电负荷和废气组成波动，二氧化硫和汞的去除率都很高。

16. 发明公开

EP2261172A1 PROCESS FOR PRODUCING LIQUID HYDROCARBON FROM NATURAL GAS 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VONFLÜSSIGEMKOHLENWASSERSTOFF AUS ERDGAS
公开(公告)号：EP2261172A1
公开(公告)日：2010-12-15
申请号：EP09728372.5
申请日：2009-03-25
申请人： Japan Oil, Gas and Metals National Corporation , INPEX Corporation , JX Nippon Oil & Energy Corporation , Japan Petroleum Exploration Co., Ltd. , Cosmo Oil Co., Ltd. , Nippon Steel Engineering Co., Ltd. , CHIYODA CORPORATION
发明人： YAGI, Fuyuki , KAWAZUISHI, Kenichi
IPC分类号： C01B3/38 , B01J23/46 , C01B3/48 , C01B3/56 , C10G2/00 , C10G49/00 , C10L3/10
CPC分类号： C01B3/48 , B01J21/10 , B01J23/462 , B01J23/58 , B01J37/0201 , C01B3/38 , C01B2203/0233 , C01B2203/0238 , C01B2203/0283 , C01B2203/043 , C01B2203/062 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , C01B2203/127 , C01B2203/146 , C01B2203/148 , C10G2/32 , C10G49/00 , C10G2300/1025 , C10G2300/202 , C10G2300/42 , C10G2300/807 , Y02P20/52
摘要： In a so-called GTL process for producing liquid hydrocarbons containing fuel oil by producing synthesis gas from natural gas, subsequently producing Fischer-Tropsch oil from the obtained synthesis gas by way of Fischer-Tropsch synthesis and upgrading the produced Fischer-Tropsch oil, the synthesis gas produced from a synthesis gas production step is partly branched at a stage prior to getting to a Fischer-Tropsch oil production step and high-purity hydrogen is separated and produced from the synthesis gas entering the branch line. All the separated high-purity hydrogen is supplied to an upgrading reaction step and consumed as hydrogen for an upgrading reaction. Additionally, the synthesis gas entering the branch line is subjected to a water gas shift reaction to raise the hydrogen concentration before the step of separating and producing high-purity hydrogen and the residual gas left after the separation may be circulated to the synthesis gas production step as raw material for producing synthesis gas.
摘要翻译：在由天然气生产合成气生产含燃料油的液态烃的所谓GTL方法中，随后通过费 - 托合成法生产费 - 托合成法，并对生产的费 - 托油进行升级，生产费 - 托油从合成气生产步骤产生的合成气在进入费 - 托油生产步骤之前的阶段部分支化，并且从进入分支管线的合成气分离和产生高纯度氢。将所有分离的高纯度氢气供应至升级反应步骤，并作为氢气用于升级反应。此外，进入分支管线的合成气进行水煤气变换反应，以在分离和生产高纯度氢气的步骤之前提高氢气浓度，并且分离后留下的残留气体可循环到合成气生产步骤作为生产合成气的原料。

17. 发明公开

EP2260940A1 CARBONACEOUS CATALYST FOR FLUE GAS DESULFURIZATION, PROCESS FOR PRODUCING THE SAME AND USE THEREOF FOR REMOVAL OF MERCURY FROM EXHAUST GAS 有权转让
标题翻译：碳催化剂，脱硫工艺对于去除汞从废气PRODUCING及其用途
公开(公告)号：EP2260940A1
公开(公告)日：2010-12-15
申请号：EP08765411.7
申请日：2008-06-04
申请人： CHIYODA CORPORATION
发明人： KAWAMURA, Kazushige , TAKEDA, Dai , AWAI, Eiji
IPC分类号： B01J27/08 , B01D53/86 , B01J21/18 , B01J33/00 , B01J37/22
CPC分类号： B01D53/8609 , B01D2255/702 , B01D2257/302 , B01D2257/602 , B01J21/18 , B01J23/04 , B01J27/08 , B01J37/0201 , C01B17/78 , F23J2215/20 , F23J2215/60 , F23J2219/10 , F23J2219/30 , F23J2219/60
摘要： A carbon-based catalyst for flue gas desulfurization is brought into contact with a flue gas containing at least SO 2 gas, oxygen and water vapor so that the SO 2 gas can react with the oxygen and the water vapor to form sulfuric acid which is to be recovered. On a surface of the carbon-based catalyst, iodine, bromine or a compound thereof is added, ion exchanged or supported and a water-repellent treatment is applied. The carbon-based catalyst can also be used as a mercury adsorbent for flue gas treatment for adsorbing and removing metallic mercury from a flue gas containing metallic mercury, SO 2 gas, oxygen and water vapor.
摘要翻译：排烟脱硫甲碳系催化剂所接触与烟道气含有至少SO 2个气体，氧气和水蒸汽，以便做的SO 2种气体可与氧和水蒸汽反应，以形成硫酸所有这是为了恢复。在碳系催化剂，碘，溴或它们被添加的化合物的表面，离子交换或负载和一个防水处理被应用。因此，该碳系催化剂，可以使用作为汞吸附剂烟气处理用于吸附和从含有金属汞，二氧化硫气体，氧气和水蒸汽的烟道气中除去金属汞。

18. 发明公开

EP2253585A1 PROCESS FOR PRODUCING LIQUID HYDROCARBONS FROM NATURAL GAS 有权
标题翻译： VERFAHREN ZUR HERSTELLUNGFLÜSSIGERKOHLENWASSERSTOFFE AUS ERDGAS
公开(公告)号：EP2253585A1
公开(公告)日：2010-11-24
申请号：EP09719518.4
申请日：2009-03-11
申请人： Japan Oil, Gas and Metals National Corporation , INPEX Corporation , JX Nippon Oil & Energy Corporation , Japan Petroleum Exploration Co. Ltd. , Cosmo Oil Co., Ltd. , Nippon Steel Engineering Co., Ltd. , CHIYODA CORPORATION
发明人： YAGI, Fuyuki , KAWAZUISHI, Kenichi
IPC分类号： C01B3/38 , C01B3/48 , C01B3/56 , C10G2/00
CPC分类号： C01B3/38 , C01B3/48 , C01B2203/02 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/048 , C01B2203/062 , C01B2203/1064 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/146 , C01B2203/148 , C10G2/32 , C10G49/00 , C10G2300/1025 , C10G2300/202 , C10G2300/807
摘要： In a so-called GTL process of producing synthesis gas from natural gas, producing Fischer-Tropsch oil by way of Fischer-Tropsch synthesis of the obtained synthesis gas and producing liquid hydrocarbons containing fuel oil by upgrading, the synthesis gas produced from the synthesis gas production step is partly branched off prior to getting to the Fischer-Tropsch oil production step and the synthesis gas entering the branch line is subjected to a water gas shift reaction to raise the hydrogen concentration thereof. Subsequently, high-purity hydrogen is isolated from the synthesis gas and the residual gas left after the isolation is circulated to the synthesis gas production step and used as raw material for synthesis gas production. As a result, a significant improvement can be achieved in terms of raw material consumption per product of the entire process.
摘要翻译：在天然气生产合成气的所谓GTL工艺中，通过费 - 托合成所得合成气生产费 - 托油，并通过升级生产含燃料油的液态烃，由合成气生产的合成气生产步骤在进入费 - 托油生产步骤之前部分分支，并且进入分支管线的合成气进行水煤气变换反应以提高其氢浓度。随后，从合成气中分离高纯度氢气，分离后剩下的残留气体循环到合成气生产步骤中，并用作合成气生产原料。因此，在整个过程的每个产品的原料消耗方面可以获得显着的改善。

19. 发明公开

EP1820779A3 Porous group 4 metal oxide and method for preparation thereof 审中-公开
标题翻译： PorösesOxid eines Metalls der Gruppe 4 und Verfahren zu seiner Herstellung
公开(公告)号：EP1820779A3
公开(公告)日：2007-09-12
申请号：EP07007481.0
申请日：2002-01-15
申请人： CHIYODA CORPORATION
发明人： Inoue, Shinichi , Kudou, Hidehiko, 206, Esperanesa Tsunashima , Mutou, Akihiro , Ono, Tateo , Makabe, Toshiji , Takatsuka, Toru , Nomura, Hisashi
IPC分类号： C01G23/04 , C01G25/02 , B01J21/06 , B01J32/00 , B01J23/88 , B01J27/19 , C10G45/08 , B01J23/882
CPC分类号： B01J21/063 , B01J21/06 , B01J21/066 , B01J23/28 , B01J23/85 , B01J23/88 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/188 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1085 , B01J37/0009 , B01J37/036 , C01G23/04 , C01G23/0536 , C01G25/02 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C01P2006/17 , C01P2006/21 , C01P2006/82 , C10G45/08
摘要： This invention relates to a porous group 4 metal oxide (preferably titanium oxide) and to a method for preparation thereof The group 4 metal oxide is prepared by adding a particle growth inhibiter to a hydrosol, a hydrogel or a dried product of a hydrous group 4 metal oxide represented by MO (2-x) (OH) 2x (wherein M denotes a group 4 metal and x > 0.1) followed by drying and calcining, to form a product having a specific surface area of 80 m 2 /g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more. The preparation of the group 4 metal oxide may involve a pH swing operation. The product has excellent heat stability and is useful as a catalyst or a catalyst carrier in which a catalyst metal is highly dispersed.
摘要翻译：本发明涉及一种4族金属氧化物及其制备方法以及通过将由颗粒生长抑制剂加入到由MO表示的含水4族金属氧化物的水溶胶，水凝胶或干燥产物而制备的4族金属氧化物 2-x）（OH）2×（其中M表示4族金属，x是大于0.1或x> 0.1的数），然后干燥和煅烧的比表面积为80m 2 / g以上，孔体积为0.2ml / g以上，孔清晰度为50％以上，热稳定性优异，可用于高催化剂金属分散的催化剂或催化剂载体。本发明还涉及一种多孔4族金属氧化物及其制备方法，通过应用pH挥发操作制备的4族金属氧化物的特征在于大比表面积，优异的热稳定性，高分散性的催化剂金属和可控的尖锐的孔分布，并且可用于具有优异反应选择性的催化剂或催化剂载体

20. 发明授权

EP0979799B1 PROCESS FOR PREPARING SYNTHESIS GAS BY AUTOTHERMAL REFORMING 失效
标题翻译：工艺生产合成气通过改革OUTOTHERMER
公开(公告)号：EP0979799B1
公开(公告)日：2004-08-25
申请号：EP98912783.2
申请日：1998-04-13
申请人： CHIYODA CORPORATION
发明人： YAGI, Fuyuki, Chiyoda Corporation , NAGUMO, Atsuro, Chiyoda Corporation , WADA, Yukitaka, Chiyoda Corporation , SHIMURA, Mitsunori, Chiyoda Corporation , ASAOKA, Sachio, Chiyoda Corporation , WAKAMATSU, Shuhei, Chiyoda Corporation
IPC分类号： C01B3/40 , B01J23/46 , B01J23/58 , B01J23/42 , B01J35/10 , B01J21/10 , C01B3/38
CPC分类号： B01J23/40 , C01B3/40 , C01B32/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , Y02P20/52
摘要： Disclosed is a process for producing a synthesis gas by an autothermal reforming method including a step of partially oxidizing a carbon-containing organic compound to produce a high temperature mixed gas, and a synthesis producing step of reacting the unreacted carbon-containing organic compound contained in the high temperature mixed gas with carbon dioxide and/or steam, wherein a catalyst having a considerably suppressed carbon deposition activity is used as a catalyst for the synthesis gas producing step. The catalyst is characterized in that the catalyst comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m /g or less, in that metal ion of the carrier metal oxide has electronegativity of 13.0 or less, and in that the amount of the catalytic metal supported is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide.

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