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    • 155. 发明公开
    • Acqueous polymer dispersion and process
    • WässrigePolymerdispersion und Verfahren zu ihrer Herstellung
    • EP1911771A1
    • 2008-04-16
    • EP06021165.3
    • 2006-10-09
    • CYTEC SURFACE SPECIALTIES, S.A.
    • The designation of the inventor has not yet been filed
    • C08F2/22C08F2/26C08F265/04C08F265/06C08F257/02C08L51/00C09D151/00C09J151/00
    • C08F2/22C08F2/26C08F220/18C08F220/28C08F257/02C08F265/04C08F265/06C08L51/003C08L2666/02C09D151/003C09J151/003
    • There is described a multi step process for preparing an aqueous dispersion of heterogeneous polymer particles by mini-emulsion polymerisation, the process comprising the steps of (I) (a) forming a mixture comprising: (i) water; (ii) at least one stabiliser (such as a surfactant and a hydrophobic co-stabliiser); (iii) at least one tackifier (such as polyterpenes, rosin resins and/or hydrocarbon resins); (iv) at least one α,β-ethylenically unsaturated monomer;, (b) applying high shear to the mixture from step (a) to form an essentially stable mini-emulsion comprising an aqueous continuous phase and dispersed therein stabilised droplets of average diameter from about 10 to about 1000 nm, (c) polymerising the monomer(s) within the droplets in the presence of a free radical initiator; (d) adding further monomer to the dispersed phase to form a dispersion; then: (II) using the dispersion from step (I) as a seed to form a dispersion of heterogeneous polymer particles in a subsequent emulsion polymerisation. The resultant tackified PSAs may have a core shell structure and are stable under high shear.
    • 描述了通过微乳液聚合制备非均相聚合物颗粒的水分散体的多步骤方法,该方法包括以下步骤:(I)(a)形成混合物,其包含:(i)水; (ii)至少一种稳定剂(例如表面活性剂和疏水共稳定剂); (iii)至少一种增粘剂(例如多萜烯,松香树脂和/或烃树脂); (iv)至少一种±,2-烯键式不饱和单体;(b)对来自步骤(a)的混合物施加高剪切以形成基本稳定的微乳液,其包含水性连续相,并分散有平均直径的稳定液滴 约10至约1000nm,(c)在自由基引发剂存在下在液滴内聚合单体; (d)向分散相中加入另外的单体以形成分散体; 然后:(II)使用来自步骤(I)的分散体作为种子以在随后的乳液聚合中形成非均相聚合物颗粒的分散体。 所得到的增粘PSA可以具有核壳结构,并且在高剪切下是稳定的。