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    • 122. 发明公开
    • ACRYLIC POLYMER HAVING MULTILAYER STRUCTURE AND METHACRYLIC RESIN COMPOSITION CONTAINING THE SAME
    • 丙烯酸酯聚合物麻省理工学院
    • EP0989144A1
    • 2000-03-29
    • EP98923121.2
    • 1998-06-04
    • Mitsubishi Rayon Co., Ltd.
    • UNO, HirofumiNAKAUCHI, Jun
    • C08F285/00C08L51/00C08L33/10
    • C08F285/00C08F220/12
    • A multilayered acrylic polymer comprising an innermost layer polymer (A) formed from a C 1-4 alkyl methacrylate, a C 1-8 alkyl acrylate, etc., an intermediate layer polymer (B) formed from a C 1-8 alkyl acrylate, an aromatic vinyl monomer, etc., and an outermost layer polymer (C) formed from a C 1-4 alkyl methacrylate, a C 1-8 alkyl acrylate, etc., and wherein the average value of the coating ratio, i.e. [(minimum thickness of the intermediate layer) ÷ (maximum thickness of the intermediate layer)] x 100, is not less than 30%; and a methacrylic resin composition containing the same. This multilayered acrylic polymer can improve the falling-ball or falling-weight impact strength, resistance to impact whitening, transparency and other properties of the methacrylic resin composition.
    • 包含由甲基丙烯酸C 1-4烷基酯,丙烯酸C 1-8烷基酯等形成的最内层聚合物(A),丙烯酸C 1-8烷基酯形成的中间层聚合物(B),芳香族乙烯基 单体等,以及由甲基丙烯酸C 1-4烷基酯,丙烯酸C 1-8烷基酯等形成的最外层聚合物(C),其中涂层比例的平均值即Ä(中间体的最小厚度 层)DIVIDED(中间层的最大厚度)Üx 100,不小于30%; 和含有该甲基丙烯酸系树脂组合物的甲基丙烯酸系树脂组合物。 这种多层丙烯酸类聚合物可以改善甲基丙烯酸树脂组合物的落球或落锤冲击强度,耐冲击增白,透明度等特性。
    • 128. 发明公开
    • Methacrylate resin composition
    • Methacrylatharz-Zusammensetzung。
    • EP0571918A2
    • 1993-12-01
    • EP93108350.5
    • 1993-05-24
    • SUMITOMO CHEMICAL COMPANY, LIMITED
    • Date, ShinjiKoyama, TeruhisaMatsumoto, Kanki
    • C08L33/10C08L51/00
    • C08L33/10C08L51/003C08L2205/22Y10S525/902C08L2666/24C08L2666/04
    • A methacrylate resin composition containing 20 to 99 % by weight of a methacrylate resin and 80 to 1 % by weight of a methacrylic two-layer polymer which has an inner layer and an outer layer and is characterized by the properties: (a) the inner layer having repeating units derived from methyl methacrylate and having a viscosity average molecular weight of 500,000 to 5,000,000, (b) the outer layer of the two-layer polymer having repeating units derived from methyl methacrylate and having a viscosity average molecular weight of 50,000 to 300,000, (c) a weight ratio of the inner layer to the outer layer of 1:9 to 9:1, (d) a glass transition temperature of 50 to 120°C and (e) an average particle size of 20 to 500 nm, which composition is excellent in moldability, resistance to heat distortion, mechanical properties and also solvent resistance.
    • 含有20〜99重量%的甲基丙烯酸酯树脂和80〜1重量%的具有内层和外层的甲基丙烯酸系双层聚合物的甲基丙烯酸酯树脂组合物,其特征在于:(a) 层,其具有衍生自甲基丙烯酸甲酯的重均单元,粘均分子量为500,000至5,000,000;(b)具有衍生自甲基丙烯酸甲酯的重复单元的双层聚合物的外层,其粘均分子量为50,000至300,000 ,(c)内层与外层的重量比为1:9〜9:1,(d)玻璃化转变温度为50〜120℃,(e)平均粒径为20〜500nm ,其成型性,耐热变形性,机械性能和耐溶剂性优异。