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    • 130. 发明公开
    • Ceramic metal articles and methods of manufacture
    • Formkörpernaus Cermet和Verfahren ihrer Herstellung
    • EP0711844A1
    • 1996-05-15
    • EP95116982.0
    • 1991-08-22
    • VALENITE INC.
    • Buljan, Sergej T.Lingertat, HelmutWayne, Steven F.
    • C22C29/00C22C29/06
    • C22C29/005B22F3/15B22F3/23C22C29/067
    • A dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475°-1675°C, then densifying by hot isostatic pressing at a temperature of about 1575°-1675°C, in an inert atmosphere, and at about 34-207 MPa pressure. Limiting the presintering temperature to 1475°-1575°C and keeping the presintering temperature at least 50°C below the hot pressing temperature produces an article of gradated hardness, harder at the surface than at the core. In this gradated product, the hard phase may alternatively be a carbide, nitride, carbonitride, oxycarbide, oxynitride, carboxynitride, or boride of an element selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, or B.
    • 包括约80-95体积%的粒状硬质相和约5-20体积%的金属相的密集金属陶瓷制品。 硬相是选自W-Ti,W-Hf,W-Nb,W-Ta,Zr-Ti,Hf-Ti,Hf-Ti的立方固溶体的碳化物,氮化物,碳氮化物,碳氮化物,氮氧化物或氮氧化物, Zr,V-Ti,Nb-Ti,Ta-Ti或Mo-Ti。 金属相主要由镍和铝的组合组成,镍与铝的比例为约90:10至约70:30重量,以及0-5重量%的选自钛,锆,铪的添加剂 ,钒,铌,钽,铬,钼,钨,钴,硼和/或碳。 制品可以通过在真空或惰性气氛中在约1475℃-1675℃预烧结硬相 - 金属相组分混合物,然后在约1575℃-1675℃的温度下通过热等静压进行致密化, 惰性气氛和约34-207MPa的压力。 将预烧温度限制在1475°-1575℃,并将预烧温度保持在低于热压温度的至少50℃,会产生一层比较硬的硬度,表面比核心硬。 在这种分级产品中,硬质相可以是选自Ti,Zr,Hf,V,Nb,Ta,Cr,Mo,W中的元素的碳化物,氮化物,碳氮化物,碳氧化物,氮氧化物,氮氧化物或硼化物。 B.