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    • 121. 发明公开
    • Burner block and method for furnace
    • 炉子的燃烧器块和方法
    • EP0717240A2
    • 1996-06-19
    • EP95308446.4
    • 1995-11-24
    • THE BOC GROUP, INC.
    • Yap, Loo T.
    • F23M5/02F23C9/00C22B21/00
    • C03B5/2353F23C9/006F23C2202/40F23M5/025F27B3/205Y02P40/55
    • A burner block (12) for mounting a burner (14) within a furnace containing a melt to be heated by the burner. The burner block comprises a body (20) having a passageway (22) terminating in a divergent opening (24). The passageway is configured to receive the burner so that the burner is recessed within the divergent opening (24) and a flame (16) produced by the burner is directed out of the divergent opening and over the melt (18). The divergent opening has a lower section (26) angled in a downward direction and the lower section has a reversed step (28) to produce a primary recirculation zone (A) beneath the flame, thereby to draw the flame in a downward direction toward the melt. The reversed step is positioned within the divergent opening so that when the burner is in use, a secondary recirculation zone (B) forms between the opening and the melt and further draws the flame in the downward direction toward the melt. The height of this secondary recirculation zone will vary with the height of the melt within the furnace to produce a self adjustment of the flame toward the melt. In another aspect, the present invention relates to a furnace incorporating the aforesaid burner block, a burner positioned within the burner block and a melt.
    • 一种用于将燃烧器(14)安装在含有待由燃烧器加热的熔体的炉内的燃烧器块(12)。 燃烧器块包括具有终止于发散开口(24)的通道(22)的主体(20)。 通道构造成容纳燃烧器,使得燃烧器在发散开口(24)内凹入,并且由燃烧器产生的火焰(16)从歧管开口并在熔体(18)上方引出。 发散开口具有向下方向成角度的下部部分(26),并且下部部分具有相反的台阶(28)以在火焰下面产生主要再循环区域(A),由此沿着向下方向 熔化。 相反的台阶位于发散开口内,使得当使用燃烧器时,在开口与熔体之间形成第二再循环区域(B),并进一步将火焰向下引向熔体。 该第二回流区的高度将随着炉内熔体的高度而变化,以产生火焰朝向熔体的自我调节。 另一方面,本发明涉及装有上述燃烧器组件的炉子,位于燃烧器组件内的燃烧器和熔体。
    • 122. 发明公开
    • Pressure swing adsorption process
    • Druckwechsel Adsorptionsverfahren
    • EP0714690A2
    • 1996-06-05
    • EP95307907.6
    • 1995-11-06
    • THE BOC GROUP, INC.
    • Lemcoff, Norberto O.
    • B01D53/047
    • B01D53/053B01D2259/40003B01D2259/40007B01D2259/40079B01D2259/40081B01D2259/402
    • The components of a gas mixture are separated by pressure swing adsorption in a plurality of adsorption vessels. In the first step of the half-cycle adsorption takes place in a first bed while the second bed undergoes countercurrent desorption. At the end of the first step the first bed is vented countercurrently and the first and second beds undergo, as a first bed equalisation step, outlet-to-outlet equalisation or outlet to both inlet and outlet equalisation. The vent step may precede or be concurrent with the first bed equalisation step. In a second equalisation step the beds simultaneously undergo inlet-to-inlet and outlet-to-outlet equalisation. The second bed is then further pressurised with nonadsorbed product gas. The half cycle is then repeated but with the first bed being substituted for the second bed and vice versa.
    • 通过多个吸附容器中的变压吸附分离气体混合物的组分。 在半循环吸附的第一步骤在第一床中发生,而第二床进行逆流解吸。 在第一步骤结束时,第一床逆流排出,第一和第二床作为第一床均衡步骤进行出口到出口均衡或出口到入口和出口均衡。 排气步骤可以在第一床平衡步骤之前或同时进行。 在第二均衡步骤中,床同时进行入口到入口和出口到出口的均衡。 然后用非吸附产物气进一步加压第二床。 然后重复该半周期,但是第一床被替换为第二床,反之亦然。
    • 124. 发明公开
    • Air separation method and apparatus
    • 空气分离方法和设备
    • EP0713068A2
    • 1996-05-22
    • EP95307911.8
    • 1995-11-06
    • THE BOC GROUP, INC.
    • Mostello, Robert A.
    • F25J3/04
    • F25J3/04309F25J3/04375
    • A stream of compressed air is cooled in a heat exchanger 20 to a temperature suitable for its separation by rectification. The compressed air stream is separated by rectification in an air separation unit 22. A pressurised nitrogen stream is withdrawn from the unit 22, is cooled in the heat exchange 20, and is expanded in a turboexpander 30 with the performance of work. The expanded stream is drawn through the heat exchanger 20 from its cold end to its warm end by a blower 34 which has an inlet pressure below atmospheric pressure. The blower 34 raises the pressure of the expanded stream to at least atmospheric pressure.
    • 压缩空气流在热交换器20中冷却至适于通过精馏分离的温度。 压缩空气流在空气分离单元22中通过精馏分离。加压的氮气流从单元22中抽出,在热交换器20中冷却,并且在涡轮膨胀机30中膨胀并进行工作。 膨胀后的物流通过换热器20从其冷端通过鼓风机34吸入,该鼓风机的入口压力低于大气压。 鼓风机34将膨胀流的压力升高到至少大气压。
    • 126. 发明公开
    • Catalyst regeneration process
    • 催化剂再生过程
    • EP0704516A3
    • 1996-05-08
    • EP95306405.2
    • 1995-09-13
    • THE BOC GROUP, INC.
    • Menon, Raghu K.Ramachandran, Ramakrishnan
    • C10G11/18
    • C10G11/182B01D53/56Y02P30/446
    • A hydrocarbon cracking catalyst having coke deposits thereon is regenerated by the combustion of the deposits in a regenerator 2 having a lower combustion zone 12 and an upper reducing zone 14. A mixture of oxygen and an inert gas (e.g. nitrogen or carbon dioxide) is introduced into the combustion zone 12 through a distributor 18. The combustion zone 12 is at least 24% by volume of the total flow rate of all gases into the zone 12. At least part of the coke is combusted. In addition nitrogen in the coke is converted to nitrogen oxides (NO x ). A substantially oxygen-free combustion gas comprising carbon dioxide, nitrogen oxides and at least 1% by volume of carbon monoxide flows into the reducing zone 14 with the result that at least part of the nitrogen oxides are reduced to nitrogen.
    • 其上具有焦炭沉积物的烃裂化催化剂通过在具有下部燃烧区12和上部还原区14的再生器2中的沉积物的燃烧而再生。引入氧气和惰性气体(例如氮气或二氧化碳)的混合物 通过分配器18进入燃烧区12.燃烧区12为进入区12的全部气体总流量的至少24%。至少部分焦炭被燃烧。 另外,焦炭中的氮转化为氮氧化物(NOx)。 包含二氧化碳,氮氧化物和至少1体积%一氧化碳的基本上无氧的燃烧气体流入还原区14,结果至少部分氮氧化物被还原成氮气。
    • 127. 发明公开
    • Hydrocarbon catalytic cracking process
    • Katalytisches Kohlenwasserstoffkrackverfahren
    • EP0704517A2
    • 1996-04-03
    • EP95306407.8
    • 1995-09-13
    • THE BOC GROUP, INC.
    • Menon, Raghu K.Ramachandran, Ramakrishnan
    • C10G11/18
    • C10G11/18C10G55/06C10G70/046Y02P30/446
    • A hydrocarbon feedstock is cracked in reactor 2. Used catalyst is sent to a regenerator 4 in which coke deposits on the catalysed are oxidised in the presence of the gas mixture comprising oxygen and inert gas (e.g. CO₂). Regenerated catalyst is returned to the reactor 2. A cracked hydrocarbon product stream flows to a fractionating column 6. An overhead stream from the fractionating column 6 is cooled so as to form a liquid-vapour mixture. Downstream of phase separation in an accumulator 10, a stream of the vapour phase ("wet gas") has methane and hydrogen separated therefrom by pressure swing adsorption in plant 8. Higher hydrocarbons than methane are adsorbed in the plant 8 and on regeneration of the adsorbent form a desorbed gas fraction which is sent to an upstream wet gas compressor 12 and from there to a downstream wet gas compressor 16. A compressed wet gas stream is sent from the downstream wet gas compressor 16 to further hydrocarbon processing units (not shown). The feed to the PSA plant 8 may be taken from upstream of the compressor 12 or from intermediate the compressors 12 and 16, or from both locations. Throughput of hydrocarbon feedstock through the cracking plant is able to increased.
    • 烃原料在反应器2中裂解。使用的催化剂被送到再生器4,在再生器4中,在包含氧和惰性气体(例如CO 2)的气体混合物的存在下,催化的焦炭沉积物被氧化。 再生的催化剂返回到反应器2.裂化的烃产物流流到分馏塔6.来自分馏塔6的塔顶物流被冷却以形成液体 - 蒸气混合物。 在蓄能器10中相分离的下游,气相(“湿气”)具有通过工厂8中的变压吸附而分离的甲烷和氢气。比甲烷更高的烃被吸附在设备8中,并且再生 吸附剂形成解吸的气体馏分,其被送到上游湿气压缩机12并从那里输送到下游的湿气压缩机16.压缩的湿气流从下游的湿气压缩机16送到另外的烃处理装置(未示出) 。 PSA设备8的进料可以从压缩机12的上游或从压缩机12和16的中间或从两个位置取出。 通过裂解装置的烃原料通量能够增加。
    • 128. 发明公开
    • Catalyst regeneration process
    • Verfahren zur Regeneration von Katalysatoren
    • EP0704516A2
    • 1996-04-03
    • EP95306405.2
    • 1995-09-13
    • THE BOC GROUP, INC.
    • Menon, Raghu K.Ramachandran, Ramakrishnan
    • C10G11/18
    • C10G11/182B01D53/56Y02P30/446
    • A hydrocarbon cracking catalyst having coke deposits thereon is regenerated by the combustion of the deposits in a regenerator 2 having a lower combustion zone 12 and an upper reducing zone 14. A mixture of oxygen and an inert gas (e.g. nitrogen or carbon dioxide) is introduced into the combustion zone 12 through a distributor 18. The combustion zone 12 is at least 24% by volume of the total flow rate of all gases into the zone 12. At least part of the coke is combusted. In addition nitrogen in the coke is converted to nitrogen oxides (NO x ). A substantially oxygen-free combustion gas comprising carbon dioxide, nitrogen oxides and at least 1% by volume of carbon monoxide flows into the reducing zone 14 with the result that at least part of the nitrogen oxides are reduced to nitrogen.
    • 其上具有焦炭沉积物的烃裂解催化剂通过沉积物在具有较低燃烧区12和上部还原区14的再生器2中的燃烧而再生。引入氧气和惰性气体(例如氮气或二氧化碳)的混合物 通过分配器18进入燃烧区12.燃烧区12是进入区12的所有气体的总流速的至少24体积%。至少部分焦炭被燃烧。 此外,焦炭中的氮被转化为氮氧化物(NOx)。 包含二氧化碳,氮氧化物和至少1体积%的一氧化碳的基本上无氧的燃烧气体流入还原区14,结果是至少部分氮氧化物被还原成氮气。
    • 129. 发明公开
    • Mechanism for oscillating a sample holder within a sample vessel
    • 天竺葵um es e es es es es es es es es es
    • EP0703442A2
    • 1996-03-27
    • EP95305743.7
    • 1995-08-17
    • THE BOC GROUP, INC.
    • Bülow, MartinMicke, André
    • G01N7/02
    • G01N7/02
    • A mechanism used in connection with determining a time resolved interaction between a target substance, for instance, an adsorbent and at least one agent, for instance, an adsorbate capable of interacting with the target substance. In accordance with the method the target substance and agent(s) are introduced into a sample vessel. At the same time, the target substance is oscillated within the sample vessel without changing the volume of the sample vessel. A concentration of one or more components associated with the time resolved interaction as a function of time is measured by measuring chamber pressure and simultaneously performing a mass spectroscopical analysis of chamber content at discrete time intervals. The target substance is oscillated by a mechanical movement which oscillates a sample holder configured to hold the target substance. The movement has a finger-like member, preferably formed by welded steel bellows and a curved member rotating within the finger-like member so that motion of the finger-like member does not change chamber volume and therefore effect the pressure measurements that are to be made in accordance with the method.
    • 该机构包括用于密封样品容器的进入口的密封装置。 密封装置具有开口,以及具有敞开的近端和封闭的远端的指状构件。 一种装置,用于将样品架连接到指状构件的远端。 后者通过其开放的近端与密封装置密封地连接,使得开口的近端与开口对准,并且当运动使用时,远端可操作以伸入样品容器中。 一个装置投射到指状构件中,用于向手指状构件的远端施加振荡运动。