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111. 发明公开

EP0259450A4 PROCESS FOR THE PREPARATION OF TRIBROMOTETRAMETHYLBIPHENOL AND RELATED COMPOUNDS. 失效
标题翻译：方法TRIBROMOTETRAMETHYLBIPHENOL及相关化合物。
公开(公告)号：EP0259450A4
公开(公告)日：1988-06-20
申请号：EP87901918
申请日：1987-02-19
申请人： DOW CHEMICAL CO
发明人： MENDOZA ABEL
IPC分类号： C07C37/07 , C07C27/00 , C07C29/143 , C07C37/62 , C07C39/12 , C07C39/24 , C07C39/32 , C07C39/367 , C07C67/00
CPC分类号： C07C37/62 , C07C39/367
摘要： Prepare 3,3',5-tribromo-2,2',6,6'-tetra(primary alkyl)-1,1'-biphenol in high yields by contacting a 3,3',5,5'-tetra-substituted diphenoquinone and a brominating agent under proper reaction conditions.

112. 发明公开

EP0225915A4 PROCESS AND INTERMEDIATES FOR PREPARING 1-g(a)-HYDROXYVITAMIN D COMPOUNDS. 失效
标题翻译：过程与在1-α-羟基维生素D CONNECTIONS THE PRODUCTION中间体化合物。
公开(公告)号：EP0225915A4
公开(公告)日：1987-08-12
申请号：EP86903850
申请日：1986-05-20
申请人： WISCONSIN ALUMNI RES FOUND
发明人： DELUCA HECTOR F , SCHNOES HEINRICH K , LEE SEOK HO
IPC分类号： C07C35/17 , C07C27/00 , C07C29/14 , C07C35/32 , C07C45/00 , C07C45/29 , C07C45/30 , C07C45/52 , C07C47/267 , C07C47/277 , C07C67/00 , C07C401/00 , C07F7/18 , C07J9/00 , C07C27/10 , C07C29/10 , C07C35/00 , C07C35/02 , C07C35/04 , C07C47/00
CPC分类号： C07C45/296 , C07C35/32 , C07C45/30 , C07C47/267 , C07C47/277 , C07C401/00
摘要： Ring A-diol units suitable for synthesizing 1 alpha -hydroxyvitamin D compounds by subsequent condensation with appropriate C/D-ring fragments and to methods for preparing such ring A-diol units.

113. 发明公开

EP0152828A3 NEW DISTILLATION AND RECTIFICATION PROCESS OF ALCOHOLS AND APPARATUS FOR ITS PERFORMANCE 失效
标题翻译：酒精及其性能的新的蒸馏和整理方法及性能
公开(公告)号：EP0152828A3
公开(公告)日：1987-06-03
申请号：EP85100955
申请日：1985-01-30
申请人： CARRAZON FLORES, EMILIO
发明人： CARRAZON FLORES, EMILIO
IPC分类号： C07C29/80 , B01D3/00 , C07C27/00 , C07C31/08 , C07C67/00 , C12F1/08
CPC分类号： B01D3/005
摘要： This invention is referred to an alcohol distillation and rec tification process, for which an apparatus formed by three in torconnected and superposed recipients is used, being the lower one a rectification dispositive provided with an ensemble of communicant vases to use up the product to be distilled, and in whose interior steam at high temperature is being in jected. in order to arrive the boiling point of the product to be distilled, which passes through the second recipient placed in an intermediate location and superposed to the first one, and endowed with a series of concentration plattes, from which, when the product overflows, it passes through a tubular ele ment toward the rectification recipient, and the produced steams, which carry the highest alcohol concentration, pass to a third recipient, that is located at the top, so that the heaviest alcohols are being purged from this second recipient.
With this process alcohols in very high concentration, as well as with minimum impurities and at a very low cost are be ing attained.

114. 发明公开

EP0206085A1 Heterogeneous catalyst. 失效
标题翻译：非均相催化剂。
公开(公告)号：EP0206085A1
公开(公告)日：1986-12-30
申请号：EP86107859
申请日：1986-06-09
申请人： ETHYL CORP
发明人： GOINS DIXIE ELY , HOLMES SILAS WENDELL , BURT EDWARD ANGUS
IPC分类号： B01J31/00 , B01J31/06 , B01J31/08 , B01J31/10 , B01J31/40 , C07C27/00 , C07C37/14 , C07C39/06 , C07C67/00
CPC分类号： B01J31/4007 , B01J31/0202 , B01J31/0208 , B01J31/08 , B01J31/10 , B01J31/143 , B01J2231/323 , C07C37/14 , Y02P20/584 , C07C39/06
摘要： A process using heterogeneous resin-bonded aluminium phenoxide catalyst to alkylate phenols, the catalyst per se, and a process for making the catalyst. The inventive alkylation process uses ortho-tert-butyl-phenoxide bonded to a phenol-formaldehyde condensation resin heterogeneous catalyst to prepare 2,6-di-tert-butylphenol from isobutylene and ortho-tert-butylphenol.

115. 发明公开

EP0155591A3 Hydroxylated derivatives of campholenic aldehyde, their use as flavouring agents and flavouring compositions containing them 失效
标题翻译：化学合成醛的羟基衍生物，它们作为含氟化合物和挥发性组合物使用它们
公开(公告)号：EP0155591A3
公开(公告)日：1986-12-30
申请号：EP85102513
申请日：1985-03-06
申请人： FIRMENICH SA
发明人： SCHULTE-ELTE, KARL-HEINRICH, DR. , MULLER, BERNARD , PAMINGLE, HERVE
IPC分类号： C11D3/50 , A61K8/34 , A61Q13/00 , C07C27/00 , C07C29/14 , C07C29/40 , C07C33/12 , C07C45/30 , C07C45/62 , C07C45/68 , C07C45/74 , C07C45/75 , C07C47/225 , C07C49/21 , C07C67/00 , C11B9/00 , C11D9/44 , D06M13/02 , D06M13/144 , A23L1/226 , A61K7/46
CPC分类号： C11B9/003 , C07C29/14 , C07C29/40 , C07C33/12 , C07C45/305 , C07C45/62 , C07C45/68 , C07C45/74 , C07C45/75 , C07C47/225 , C07C49/21 , C07C2601/10 , C07C33/05

116. 发明授权

EP0128984B1 PROCESS FOR THE PRODUCTION OF PARA-VINYL PHENOL BY DEHYDROGENATION OF PARA-ETHYL PHENOL 失效
标题翻译：通过脱乙酰苯酚生产对苯乙烯酚的方法
公开(公告)号：EP0128984B1
公开(公告)日：1986-12-30
申请号：EP83304977
申请日：1983-08-30
申请人： MARUZEN PETROCHEMICAL CO., LTD.
发明人： FUJIWARA, HIROSHI , YAMAZAKI, HATSUTARO , OZAWA, KAZUO
IPC分类号： B01J21/00 , B01J23/00 , C07B61/00 , C07C27/00 , C07C37/00 , C07C39/20 , C07C67/00
CPC分类号： C07C37/001 , C07C39/20

117. 发明授权

EP0129912B1 Continuous process for co-producing linear, secondary, aliphatic alcohols and carboxylic acid esters 有权
标题翻译：连续生产线性，二次，二醇和羧酸酯的连续方法
公开(公告)号：EP0129912B1
公开(公告)日：1986-12-10
申请号：EP84107397.6
申请日：1984-06-27
申请人： UNION CARBIDE CORPORATION
发明人： Knopf, Robert John , Theiling, Louis Foster, Jr. , Berti, Leroy Paul
IPC分类号： C07C27/00 , C07C31/125 , C07C69/14
CPC分类号： C07C29/1285 , C07C67/04 , C07C31/125 , C07C69/14

118. 发明公开

EP0193801A2 Verfahren zur kontinuierlichen Homologisierung von Methanol 失效转让
标题翻译： Verfahren zur kontinuierlichen Homologisierung von甲醇。
公开(公告)号：EP0193801A2
公开(公告)日：1986-09-10
申请号：EP86102204.4
申请日：1986-02-20
申请人： Union Rheinische Braunkohlen Kraftstoff Aktiengesellschaft
发明人： Korff, Joachim, Dr. , Keim, Karl-Heinz, Dipl.-Ing. , Keim, Wilhelm, Prof. Dr. , Röper, Michael, Dr.
IPC分类号： C07C27/00 , C07C41/50 , C07C45/49 , C07C47/06 , C07C67/36
CPC分类号： C07C41/50 , C07C45/49 , C07C67/36 , Y02P20/584 , C07C47/06 , C07C43/303 , C07C69/14
摘要： Verfahren zur Homologisierung von Methanol, dadurch gekennzeichnet, daß die Homologisierung unter Verwendung des Katalysatorsystems enthaltend:

a) Kobalt und/oder (eine) Kobaltverbindung(en),
b) wenigstens ein Jodid aus der Gruppe: LiJ, NaJ, KJ, RbJ, CsJ, (N R 1 R 2 R 3 R 4 )+ J- , und/oder wenigstens eines dieser Jodide bildende Verbindungen, wobei R 1 , R 2 , R 3 und R4 H, Alkyl-und Arylgruppen, bevorzugt H, CH 3 , C 2 H 5 und C 6 H 5 sein können
c) Methyljodid und/oder Methyljodid bildende Verbindungen in Gegenwart von 1,4-Dioxan und/oder alkyliertem 1,4-Dioxan durchgeführt wird und daß die Homologisierung kontinuierlich unter Rückführung des Katalysatorsystems durchgeführt wird.
摘要翻译： 1.甲醇加氢甲酰化的方法，其特征在于反应在催化剂存在下进行，所述催化剂包括：a）钴和/或（a）钴化合物，b）至少一种该组的碘化物： LiJ，NaJ，KJ，RbJ，CsJ，（N R1R2 R3 R4）** + J ** - 和/或形成该基团的至少一种碘化物的化合物，其中R1，R2，R3和R4可以是 H，烷基和芳基，优选H，CH 3，C 2 H 5和C 6 H 5，c）在1,4-二恶烷和/或烷基化1,4-二恶烷存在下形成甲基碘和/或甲基碘化合物，加氢甲酰化是连续进行的，催化剂被循环使用。

119. 发明公开

EP0182872A4 A PROCESS FOR THE PREPARATION OF CYCLOBUTENE-SUBSTITUTED AROMATIC HYDROCARBONS. 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG ZYKLOBUTENSUBSTITUIERTER AROMATISCHER KOHLENWASSERSTOFFE。
公开(公告)号：EP0182872A4
公开(公告)日：1986-08-21
申请号：EP85902848
申请日：1985-05-20
申请人： DOW CHEMICAL CO
发明人： SO YING-HUNG
IPC分类号： C07C43/21 , C07B31/00 , C07B37/10 , C07C1/00 , C07C1/26 , C07C13/44 , C07C17/00 , C07C17/25 , C07C25/18 , C07C27/00 , C07C37/00 , C07C39/17 , C07C41/00 , C07C41/24 , C07C51/00 , C07C51/347 , C07C63/34 , C07C67/00 , C07C67/28 , C07C67/30 , C07C69/035 , C07C69/76 , C07C201/00 , C07C231/00 , C07C231/12 , C07C233/65 , C07C253/00 , C07C51/09
CPC分类号： C07C69/76
摘要： Process for the preparation of an aromatic hydrocarbon with a cyclobutene ring fused to the aromatic hydrocarbon which comprises, dissolving an ortho-alkyl halomethyl aromatic hydrocarbon in an inert solvent and pyrolyzing the solution of ortho-alkyl halomethyl aromatic hydrocarbon in the inert solvent under conditions such that the ortho-alkyl and the halomethyl substituents form a cyclobutene ring thereby forming an aromatic hydrocarbon having a fused cyclobutene ring. The ortho-alkyl group has the structural formula (R')2-CH-, wherein R' is separately in each occurance hydrogen or a C1-20 alkyl. The aromatic hydrocarbons with a cyclobutene ring fused to the aromatic hydrocarbon are useful in the preparation of monomers, which are then useful in the preparation of high performance polymers.
摘要翻译：制备具有与芳族烃稠合的环丁烯环的芳烃的方法，包括将邻烷基卤代甲基芳烃溶解在惰性溶剂中，并在惰性溶剂中将邻烷基卤甲基芳烃的溶液在惰性溶剂中热解邻位烷基和卤代甲基取代基形成环丁烯环，从而形成具有稠合的环丁烯环的芳烃。邻烷基具有结构式（R'）2 -CH-，其中R'分别在每个出现的氢或C1-20烷基中。具有与芳族烃稠合的环丁烯环的芳族烃可用于制备单体，其然后可用于制备高性能聚合物。

120. 发明公开

EP0070303A4 SYNTHESIS GAS SYSTEM. 失效
标题翻译：系统合成气生产。
公开(公告)号：EP0070303A4
公开(公告)日：1985-09-02
申请号：EP82900725
申请日：1982-01-19
申请人： SWEENEY MAXWELL P
发明人： SWEENEY MAXWELL P
IPC分类号： B01J8/06 , C01B3/36 , C07C1/02 , C07C27/00 , C07C29/15 , C07C29/151 , C07C29/157 , C07C29/50 , C07C31/04 , C07C67/00
CPC分类号： F28D19/045 , C01B3/36 , C07C29/1518 , C07C29/157 , C07C29/50 , Y02P20/125 , C07C31/04
摘要： Method and apparatus for the production of synthesis gas from hydrocarbonaceous gases, wherein a hydrocarbonaceous gas is preheated, reacted with oxygen in the presence of steam, and quenched utilizing a rotating matrix comprising glassy ceramic fibers. After reaction with oxygen, the gases may be passed over a catalyst to further convert said hydrocarbonaceous gas to synthesis gas. Such method and apparatus is especially useful in a process for the production of methanol, wherein carbon dioxide in the synthesis gases is absorbed using crude methanol and recycled, by stripping the CO u-rich crude methanol with gas which has passed over catalyst for the conversion of synthesis gas to methanol under conversion conditions, thereby recycling and ultimately recovering as methanol yield carbon present in both carbon dioxide and unconverted methane present in said gases. This process requires neither the expensive reforming furnace nor the expensive synthesis gas compressors conventionally required in steam reforming methods, and uses much less oxygen than in conventional partial oxidation processes. This process is usefully augmented by additional methanol production by means of method and apparatus for partial oxidation, thereby comprising an even more highly efficient, integrated process for the production of methanol, wherein all methane carbon utilized by the combined process is converted to methanol except for about 7% which is required as fuel for power in efficiently separating the oxygen required from air and compressing it to operating pressure.

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