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101. 发明公开

EP0918068A4 POLYPROPYLENE COMPOSITION, PROCESS FOR PREPARING THE SAME, AND POLYMERIZATION CATALYST THEREFOR 失效
标题翻译：聚丙烯组合物，METHOD FOR THEIR并确保获得适当的聚合催化剂
公开(公告)号：EP0918068A4
公开(公告)日：1999-11-03
申请号：EP97934722
申请日：1997-08-06
申请人： CHISSO CORP
发明人： OHNO KATSUHIKO , KIMURA MASAMI , HIROSE TAKETO , MORIMOTO YOSHITAKA , SAITO JUN
IPC分类号： C08F4/44 , C08F4/658 , C08L23/06 , C08L23/10 , C08L23/14 , C08F10/00
CPC分类号： C08L23/10 , C08L23/06 , C08L23/142 , C08L2314/02 , C08L2666/04
摘要： A polypropylene composition comprising 0.001 to 10 parts by weight of a polyethylene having an intrinsic viscosity [θE] of 0.01 to less than 15 dl/g as measured in tetralin at 135 °C and 100 parts by weight of a polyolefin comprising at least polypropylene, wherein the polyethylene is finely dispersed as particles with a number average particle diameter of, e.g., 1 to 5000 nm in the polyolefin comprising at least polypropylene. By virtue of the above constitution, the polypropylene composition has excellent transparency and rigidity, is free from the creation of a sweeper roll flow mark in the preparation of a film and substantially free from a neck-in phenomenon of a film, and has high productivity.

102. 发明公开

EP0683180A3 Catalyst for polymerizing an olefin and method for polymerizing the olefin. 失效
标题翻译：的催化剂用于所述烯烃聚合烯烃和过程的聚合。
公开(公告)号：EP0683180A3
公开(公告)日：1998-10-14
申请号：EP95107570
申请日：1995-05-17
申请人： MITSUBISHI CHEM CORP
发明人： SUGA YOSHINORI , MARUYAMA YASUO , ISOBE EIJI , UEHARA YUMITO , ISHIHAMA YOSHIYUKI , SAGAE TAKEHIRO
IPC分类号： C08F4/02 , C08F4/44 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65922 , Y10S526/904 , Y10S526/943
摘要： A catalyst for polymerizing an olefin, which comprises, as the essential components, (A) a metallocene-type transition metal compound and (B) at least one member selected from the group consisting of (1) an ion-exchanging layered compound other than a silicate and (2) an inorganic silicate, which is obtained by salt-treatment and/or acid-treatment and which has a water content of not higher than 3% by weight.

103. 发明公开

EP0841368A1 Synthesis of macrocyclic polymers having low hysteresis compounded properties 失效
标题翻译：具有低滞后大环聚合物的制备
公开(公告)号：EP0841368A1
公开(公告)日：1998-05-13
申请号：EP97117842.1
申请日：1997-10-15
申请人： Bridgestone Corporation
发明人： Hall, James E.
IPC分类号： C08L9/00 , B60C1/00 , C08F36/04 , C08F297/04 , C08F4/44
CPC分类号： C08F8/00 , C08F4/50 , C08F8/42 , C08F36/04 , C08F2800/20 , C08F2810/40 , Y10T152/10495 , C08F4/44 , C08F212/08
摘要： The present invention provides a method of anionic synthesis of stable macrocyclic polymers that are compounded to form vulcanizable elastomeric compounds exhibiting reduced hysteresis properties. Cyclic organometallic compounds containing divalent metal atoms of Groups IIA and IIB of the Periodic System are employed as initiators of anionic polymerization of conjugated diene, vinyl aromatic and/or triene monomers. Coupling of the living ends of the resulting macrocyclic polymers or copolymers with a coupling agent or a coupling agent that is also a functionalizing agent results in stable macrocyclic polymers with improved hysteresis properties.

104. 发明公开

EP0841356A1 Synthesis of multiblock polymers using group IIA and IIB metal cyclic organometallic initiators 失效
标题翻译： Herstellung von Multiblockpolymeren unter Verwendung von cyclischen Organometallinitiatoren des Gruppe IIA und IIB
公开(公告)号：EP0841356A1
公开(公告)日：1998-05-13
申请号：EP97117841.3
申请日：1997-10-15
申请人： Bridgestone Corporation
发明人： Hall, James E.
IPC分类号： C08F297/02 , C08F4/44 , C08F297/04
CPC分类号： C08F297/04
摘要： The invention is a practical process for anionically synthesizing multiblock polymers containing a plurality of blocks formed from polar and/or non-polar monomers by using a cyclic organometallic compound initiator that comprises a divalent metal atom and an organic moiety contained in a ring, preferably a cycloorganomagnesium initiator. Activation of the ring metallic atom results in anionic polymerization of the monomers by addition into the initiator ring at the bonds between the metallic atom and its two adjacent carbon atoms, the metallic atom acting as a bridge between the two living ends of the propagating chain. The active chain ends can be coupled or terminated.
摘要翻译：制备三嵌段聚合物的方法包括：（a）使至少一种阴离子可聚合单体的第一单体电荷与包含二价金属阳离子和含有环的有机基团的环状有机金属化合物的引发剂反应，形成具有 2端反应末端; （b）通过将不同于上述单体的至少一种阴离子可聚合单体的第二单体电荷与第一嵌段反应形成三嵌段聚合物，以在第一嵌段的每个末端反应性末端上形成第二嵌段。优选地，二价金属阳离子是铍，镉，钡，锶，镁，镉，锌或汞。单体是极性或非极性的。优选的极性单体是5-25℃甲基丙烯酸烷基酯，2-8C环氧烷烃，丙烯腈，内酰胺，4-25℃丙烯酸烷基酯，环硅氧烷，乙烯基吡啶，上述的混合物和共聚物。优选的非极性单体是乙烯，4-40C链二烯，8-20C芳基烯烃，乙烯基多核芳烃，6-18C三烯和混合物。优选的单体是1,3-丁二烯（第一）和苯乙烯（第二）。该反应在包含选自锂，钠，钾，铷，铯和混合物的金属和非质子溶剂的有机金属化合物的存在下进行。

105. 发明公开

EP0841347A1 Synthesis of macrocyclic polymers with group IIA and IIB metal cyclic organometallic initiators 失效
标题翻译：与环状Organometallinitiatoren大环聚合物的制备使用组IIA和IIB族的金属
公开(公告)号：EP0841347A1
公开(公告)日：1998-05-13
申请号：EP97117830.6
申请日：1997-10-15
申请人： Bridgestone Corporation
发明人： Hall, James E.
IPC分类号： C08F4/44 , C08F4/50 , C08F4/56 , C07F3/02 , C08G85/00 , C08F36/04 , C08F297/04
CPC分类号： C08G85/00 , C08F4/50 , C08F4/565 , C08F36/04 , C08F297/044 , C08F4/44
摘要： The invention is a practical process for anionically synthesizing commercially significant quantities of macrocyclic polymers from polar and/or non-polar monomers by using Group IIA and IIB metal cyclic organometallic initiators. Activation of the ring metal atom results in anionic polymerization of the monomers by addition into the initiator ring at the bonds between the atom and its two adjacent carbon atoms, the metal atom acting as a bridge between the two living ends of the propagating chain. Coupling of the cyclic polymer living ends by coupling agents produces macrocyclic polymers that are stable in air and moisture and that exhibit desirable properties, such as low viscosities at high molecular weights. Such macrocyclic polymers provide enhanced polymer processability during molding, extruding and the forming of films. Macrocyclic polymers terminated with coupling agents that also provide functional groups may be compounded to produce vulcanizable elastomeric compounds and articles that exhibit reduced hysteresis properties.

106. 发明公开

EP0306161A2 Energy-induced curable compositions 失效
标题翻译： Mit EnergiehärtbareZusammensetzungen。
公开(公告)号：EP0306161A2
公开(公告)日：1989-03-08
申请号：EP88307426.2
申请日：1988-08-11
申请人： MINNESOTA MINING AND MANUFACTURING COMPANY
发明人： Brown-Wensley, Katherine A. Minnesota Mining and , DeVoe, Robert J. Minnesota Mining and , Palazzotto, Michael C. Minnesota Mining and
IPC分类号： C08F4/44 , C08F2/50 , C08G65/12 , C08G59/68 , C08G18/16 , C08G18/22 , G03F7/00
CPC分类号： C08F2/50 , C08F4/44 , C08G18/161 , C08G18/22 , C08G18/637 , C08G59/68 , C08G65/12 , Y10S430/115 , Y10S430/122 , Y10S430/124
摘要： A polymerizable composition comprises a polymeric precursor selected from the group consisting of 1) at least one ethylenically-unsaturated monomer, 2) at least one epoxy monomer, and 3) polyurethane precursors, and a curing agent comprising an organometallic compound and an onium salt.
摘要翻译：可聚合组合物包含选自1）至少一种烯键式不饱和单体，2）至少一种环氧单体和3）聚氨酯前体的聚合物前体和包含有机金属化合物和鎓盐的固化剂。

107. 发明公开

EP0282437A2 Polymerization process 失效
标题翻译： Polymerisationsverfahren。
公开(公告)号：EP0282437A2
公开(公告)日：1988-09-14
申请号：EP88630046.6
申请日：1988-03-08
申请人： THE GOODYEAR TIRE & RUBBER COMPANY
发明人： Halasa, Adel Farhan , Robertson-Wilcox, Sylvia Eileen , Zanzig, David John , Arconti, Richard Joseph
IPC分类号： C08F36/04 , C08F4/44 , C08F4/48 , C08C19/44 , C08L9/00 , C08L21/00
CPC分类号： C08F36/04 , C08C19/44 , C08L21/00 , C08F4/48 , C08F4/44 , C08L2666/08
摘要： Metals from Groups I and II and organometallic compounds thereof can be used to catalyze the polymerization of diene monomers into polymers. The polymers formed in such polymerizations are terminated with the metal used to catalyze the polymerization and are sometimes referred to as living polymers. Very useful blends of such polymers can be made by utilizing the process of the present invention. More specifically, the present invention discloses a process for preparing a polydiene rubber blend comprising: (1) polymerizing at least one diene monomer utilizing at least one catalyst selected from the group consisting of Group I metals, Group II metals, organometallic compounds containing a Group I metal, and organometallic compounds containing a Group II metal, to a conversion which is within the range of 30% to 70% to produce low molecular weight polydiene chains; (2) joining from 20% to 70% of said low molecular weight polydiene chains with a suitable branching agent; and (3) allowing the polymerization to continue so as to produce said polydiene rubber blends.
摘要翻译：来自I和II族的金属及其有机金属化合物可用于催化二烯单体聚合成聚合物。在这种聚合中形成的聚合物用用于催化聚合的金属终止，有时称为活性聚合物。可以通过利用本发明的方法制备这种聚合物的非常有用的共混物。更具体地说，本发明公开了一种制备聚二烯橡胶共混物的方法，包括：（1）使用至少一种选自第I族金属，第II族金属，含有基团的有机金属化合物的催化剂聚合至少一种二烯单体 I金属和含有II族金属的有机金属化合物，转化率在30％至70％的范围内以产生低分子量聚二烯链; （2）用合适的支化剂从20％至70％的所述低分子量聚二烯链中连接; 和（3）使聚合继续进行以产生所述聚二烯橡胶共混物。

108. 发明授权

EP0085836B1 Verwendung polymerer Organo-Borverbindungen als Polymerisationsinitiatoren 失效
标题翻译：有机聚合物硼化合物作为聚合引发剂的使用
公开(公告)号：EP0085836B1
公开(公告)日：1988-07-20
申请号：EP83100210.0
申请日：1983-01-12
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： Ritter, Wolfgang, Dr.
IPC分类号： C08F8/42 , C08G85/00 , C08F4/44
CPC分类号： C08F8/42 , C08F4/52 , C08G85/004

109. 发明公开

EP0085836A2 Verwendung polymerer Organo-Borverbindungen als Polymerisationsinitiatoren 失效
标题翻译：使用聚合有机硼化合物作为聚合引发剂。
公开(公告)号：EP0085836A2
公开(公告)日：1983-08-17
申请号：EP83100210.0
申请日：1983-01-12
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： Ritter, Wolfgang, Dr.
IPC分类号： C08F8/42 , C08G85/00 , C08F4/44
CPC分类号： C08F8/42 , C08F4/52 , C08G85/004
摘要： Geschildert sind Organo-Borverbindungen mit hoher aerober Initiator-Wirking für eine Polymerisationsauslösung, gleichzeitig aber verbesserter Stabilität gegen Zutritt von Luftsauerstoff, in denen das Bor wenigstens überwiegend mittels Bor/Kohlensftoff- und gegebenenfalls Bor/Wasserstoff-Bindungen in das Molekül eingebunden vorliegt. Die Organo-Borverbindungen sind dadurch gekennzeichnet, daß die Bor enthaltenden Reste an eine gegen Zutritt von Luftsauerstoff wenigstens weitgehend unempfindliche organische Polymermatrix gebunden sind. Bevorzugt sind die borhaltigen Reste mit wenigstens einer Valenz des jeweiligen Boratoms unmittelbar an ein Kohlenstoffatom der Polymermatrix gebunden. Die zweckmäßigerweise als viskos-fließfähige bis feste, bevorzugt wenigstens weitgehend von Lösungsmitteln freien Massen enthalten insbesondere an die Polymermatrix gebundene Borwasserstoffreste und/ oder Organoborreste, die als Substituenten Alkyl-, Cycloalkyl- und/oder Arylreste aufweisen können.
摘要翻译：描述的是具有高的有氧引发剂wirking用于引发聚合反应，在相同的时间，但改进的耐大气氧，其中，所述硼是至少主要由硼/ Kohlensftoff-和任选的硼/氢键装置本并入分子有机硼化合物。的有机硼化合物的特征在于，所述含硼残基被结合到一个对大气中的氧气至少非常不敏感的有机聚合物基体的进入。具有特定硼原子中的至少一种化合价含硼基团优选直接键合到该聚合物基质中的碳原子。在有利的是最高固体和粘性的可流动，优选地至少基本上无溶剂的组合物包含，特别是结合Borwasserstoffreste和/或Organoborreste聚合物基质可以具有作为取代基的烷基，环烷基和/或芳基。

110. 发明授权

EP3848399B1 TRANSITION METAL COMPOUND AND METHOD FOR PRODUCING OLEFIN POLYMER 有权
公开(公告)号：EP3848399B1
公开(公告)日：2024-07-10
申请号：EP19856816.4
申请日：2019-09-02
IPC分类号： C07F17/00 , C08F4/6192 , C08F4/44 , C08F12/00 , C08F2/04 , C08F4/659 , C08F110/06
CPC分类号： C07F17/00 , C08F110/06 , C08F4/65908 , C08F2/04

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