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    • 104. 发明公开
    • VERFAHREN ZUR HERSTELLUNG VON 1-PHENYLPYRAZOLIN-3-CARBONSÄURE-DERIVATEN
    • 用于生产1-苯基吡唑啉-3-羧酸衍生物
    • EP1012143A1
    • 2000-06-28
    • EP98940248.2
    • 1998-08-06
    • Aventis CropScience GmbH
    • SCHLEGEL, Günter
    • C07D231/06
    • C07D231/06
    • The present invention relates to a method for preparing 1-phenylpyrrazolin-3-carboxylic acid derivatives of the general formula (III), wherein said method comprises reacting hydrazones of the general formula (I) with olefins of the general formula (II) using a base as a catalyst. In the above-mentioned formulae, Ph is an optionally substituted phenyl, R1 is hydrogen or alkyl, R?2 and R3¿ are independently hydrogen, halogen, cyano, an optionally substituted organic residue or R?2 and R3¿ form together with the carbon atom bearing them a saturated or partially saturated cyclic compound comprising 5 or 6 atoms. X is amino, hydroxy, alkoxy, cycloalkoxy, alkylamino, dialkylamino, alkyloxyalkyloxy, trialkylsilyloxy or trialkylsilylmethyloxy and Y is chlorine or bromine. This reaction is carried out in a two-phase system comprising an organic phase and an aqueous phase using a sterically hindered amine and an optional other base. The 1-phenylpyrrazolin-3-carboxylic acid derivatives of the present invention can be used as phyto-protective agents, i.e. as agents for protecting useful crops in agriculture or silviculture against undesired effects due to the application of herbicides.
    • 110. 发明公开
    • HERBIZIDE MITTEL
    • EP1303188A2
    • 2003-04-23
    • EP01936436.3
    • 2001-06-06
    • Aventis CropScience GmbH
    • WÜRTZ, JochenKOCUR, JeanKRAUSE, Hans-PeterMARTINEZ DE UNA, JulioHAASE, DetlevBICKERS, UdoSCHNABEL, Gerhard
    • A01N47/36A01N25/30
    • A01N25/30A01N47/36A01N25/32A01N2300/00
    • The invention relates to a herbicidal agent containing the following: A) one or more sulfonylureas of general formula (I) wherein R1 is C2-C4-alkoxy or CO-Ra, wherein Ra is equal to OH, C¿1?-C6-alkoxy or NR?bRc¿, wherein R?b and Rc¿ independently of each other, are the same or different and are H or C¿1?-C6-alkyl, R?2¿ is halogen or (A)¿n-NR?dRe, wherein n is equal to zero or 1, A is a group CRfRg, wherein R?f and Rg¿, independently of each other, are the same or different and are H or C1-C6-alkyl, Rd is equal to H or C¿1?-C6-alkyl and R?e¿ is H, C¿1?-C6-alkyl or an acyl radical, and wherein R?d and Re¿ can also form a heterocyclical ring; and R2 can also be H if R1 is equal to C¿2?-C4-alkoxy; R?3¿ is H or C¿1?-C6-alkyl; m is equal to zero or 1; x and Y, independently of each other, are the same or different and are C1-C6-alkyl, C1-C6-alkoxy or C1-C6-alkylthio, each of the three aforementioned radicals being unsubstituted or substituted with one or more radicals from the following group: halogen, C1-C4-alkoxy and C1-C4-alkylthio, or C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-alkenyloxy or C3-C6-alkynyloxy, preferably C1-C4-alkyl or C1-C4--alkoxy; and Z is equal to CH or N; and/or their salts; and B) one or more tensides containing at least 10 alkylene oxide units as a structural element.
    • 本发明涉及一种除草剂,其含有以下成分:A)一种或多种通式(I)的磺酰脲,其中R 1是C 2 -C 4 - 烷氧基或CO-R a,其中R a等于OH,C 1 -C 6 - 烷氧基或NR b R c',其中R b和R c彼此独立地相同或不同,并且是H或C 1 -C 6烷基,R 2'是卤素或(A) 其中n等于零或1,A是基团CRfRg,其中Rf和Rg彼此独立地相同或不同并且是H或C 1 -C 6烷基,R d相同 H或C 1 -C 6 - 烷基,R 5为H,C 1 -C 6 - 烷基或酰基,且其中R 7d和R 10也可形成杂环; 如果R 1等于C 2 -C 4 - 烷氧基,则R 2也可以是H; R 3是H或C 1 -C 6烷基; m等于零或1; x和Y彼此独立地相同或不同并且是C 1 -C 6烷基,C 1 -C 6烷氧基或C 1 -C 6烷硫基,三个前述基团各自未被取代或被一个或多个 卤素,C 1 -C 4烷氧基和C 1 -C 4烷硫基,或C 3 -C 6环烷基,C 2 -C 6烯基,C 2 -C 6炔基,C 3 -C 6烯氧基或C 3 -C 6炔氧基, C1-C4-烷基或C1-C4-烷氧基; Z等于CH或N; 和/或其盐; 和B)含有至少10个氧化烯单元作为结构单元的一种或多种表面活性剂。