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    • 96. 发明公开
    • ADHESIVE FILM AND METHOD OF MAKING A GRAPHIC
    • EP4177320A1
    • 2023-05-10
    • EP21206241.8
    • 2021-11-03
    • 3M Innovative Properties Company
    • Kolowrot, DirkLoescher, ClausArnolds, OliverD'Hollander, Stijn Alfons MarioOpstal, TomDehn, Ronald A.
    • C09J7/38B44C1/00
    • The present disclosure relates to an adhesive film comprising a polyvinyl chloride film having opposite first and second major sides, the first major side having an adhesive layer protected by a release liner, wherein the adhesive layer comprises a pressure sensitive adhesive, and wherein the pressure sensitive adhesive is made from a curable precursor comprising an acrylic copolymer and a crosslinker, and wherein the glass transition temperature of the acrylic copolymer is at least -30 °C, as calculated using the Fox Equation, and wherein the acrylic copolymer is made by copolymerization of a monomer composition, the monomer composition comprising
      (a) a C 1 -C 14 (meth)acrylic acid ester monomer,
      (b) an acid functional, ethylenically unsaturated polar monomer, and
      (c) a non-acid functional, ethylenically unsaturated polar monomer,
      and wherein the amount of the C 1 -C 14 (meth)acrylic acid ester monomer (a) is from 70 to 98 percent by weight, based on the total weight of the monomer composition, and wherein the amount of the acid functional, ethylenically unsaturated polar monomer (b) is from 1 to 15 percent by weight, based on the total weight of the monomer composition, and wherein the amount of the non-acid functional, ethylenically unsaturated polar monomer (c) is from 1 to 15 percent by weight, based on the total weight of the monomer composition.
      The present disclosure further relates to a method for producing a graphic on a substrate using said adhesive film.